公开(公告)号：US07977272B2

公开(公告)日：2011-07-12

申请号：US11793237

申请日：2005-11-17

申请人： Andrew John Miller ,  George Ernest Morris

发明人： Andrew John Miller ,  George Ernest Morris

IPC分类号： B01J27/185 ,  B01J27/053 ,  B01J27/13

CPC分类号： B01J31/0227 ,  B01J27/188 ,  B01J31/0224 ,  B01J31/0231 ,  B01J31/20 ,  B01J2231/34 ,  B01J2531/822 ,  C07C51/12 ,  C07C53/08

摘要： Catalyst system for the production of acetic acid comprising a rhodium carbonylation catalyst, methyl iodide and at least one heteropolyacid promoter.

摘要翻译： 用于生产包含铑羰基化催化剂，甲基碘和至少一种杂多酸促进剂的乙酸的催化剂体系。

公开(公告)号：US20080269519A1

公开(公告)日：2008-10-30

申请号：US11793237

申请日：2005-11-17

申请人： Andrew John Miller ,  George Ernest Morris

发明人： Andrew John Miller ,  George Ernest Morris

IPC分类号： C07C51/12 ,  B01J31/02

CPC分类号： B01J31/0227 ,  B01J27/188 ,  B01J31/0224 ,  B01J31/0231 ,  B01J31/20 ,  B01J2231/34 ,  B01J2531/822 ,  C07C51/12 ,  C07C53/08

摘要： A process and catalyst for the production of acetic acid by the carbonylation of methanol and/or a reactive derivative thereof wherein the catalyst system comprises a rhodium carbonylation catalyst, methyl iodide, a non-hydrohalogenoic acid promoter and optionally a co-promoter capable of generating ionic iodide.

摘要翻译： 用于通过甲醇和/或其反应性衍生物的羰基化生产乙酸的方法和催化剂，其中催化剂体系包含铑羰基化催化剂，甲基碘，非氢卤酸启动子和任选的能够产生 离子碘化物。

公开(公告)号：US08158815B2

公开(公告)日：2012-04-17

申请号：US12735123

申请日：2008-12-16

申请人： Evert Jan Ditzel ,  David John Law ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

发明人： Evert Jan Ditzel ,  David John Law ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

IPC分类号： C07C67/36 ,  C07C51/12 ,  C07C53/08

CPC分类号： B01J29/90 ,  B01J29/20 ,  B01J38/14 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.

摘要翻译： 一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生 使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压下接触，并且其中分子氧气体的分压使得催化剂的温度为 维持在225至325℃的范围内

公开(公告)号：US5932764A

公开(公告)日：1999-08-03

申请号：US984996

申请日：1997-12-04

申请人： George Ernest Morris ,  John Glenn Sunley

发明人： George Ernest Morris ,  John Glenn Sunley

IPC分类号： B01J23/46 ,  C07B61/00 ,  C07C51/12 ,  C07C53/08 ,  C07C53/126 ,  C07C51/14

CPC分类号： C07C51/12

摘要： A process for the production of a carboxylic acid having n+1 carbon atoms comprises (a) carbonylating with carbon monoxide in a first reaction zone at elevated temperature and pressure an alkyl alcohol having n carbon atoms and/or a reactive derivative thereof to produce a carboxylic acid having n+1 carbon atoms in a liquid reaction composition comprising carboxylic acid product, an iridium catalyst, an alkyl halide co-catalyst, water, an ester of the carboxylic acid product and the alkyl alcohol, and optionally one or more promoters, (b) withdrawing from the first reaction zone at least a portion of the liquid reaction composition together with dissolved and/or entrained carbon monoxide, and passing at least a portion of the withdrawn liquid reaction composition and carbon monoxide to a second reaction zone, ((c)reacting at least 1% of the dissolved and/or entrained carbon monoxide in the withdrawn reaction composition by further carbonylation at elevated temperature and pressure in the second reaction zone to produce further carboxylic acid product.

摘要翻译： 制备具有n + 1个碳原子的羧酸的方法包括（a）在高温和高压下在第一反应区中用一氧化碳羰基化具有n个碳原子的烷基醇和/或其反应性衍生物以产生 在包含羧酸产物，铱催化剂，烷基卤助催化剂，水，羧酸产物的酯和烷基醇的液体反应组合物中具有n + 1个碳原子的羧酸，以及任选的一种或多种助催化剂， （b）将液体反应组合物的至少一部分与溶解和/或夹带的一氧化碳一起排出第一反应区，并将至少一部分抽出的液体反应组合物和一氧化碳通入第二反应区（ （c）通过在升高的温度和压力下进一步羰基化使至少1％的溶解和/或夹带的一氧化碳在撤回的反应组合物中反应 他的第二反应区产生更多的羧酸产物。

公开(公告)号：US08329606B2

公开(公告)日：2012-12-11

申请号：US12735122

申请日：2008-12-16

申请人： Edo Johann Becker ,  Evert Jan Ditzel ,  Harry Kaiser ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

发明人： Edo Johann Becker ,  Evert Jan Ditzel ,  Harry Kaiser ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

IPC分类号： B01J38/10 ,  C07C51/12

CPC分类号： B01J29/06 ,  B01J29/20 ,  B01J29/50 ,  B01J29/65 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/90 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： Process for the in-situ regeneration of a zeolite catalyst in a carbonylation process for the production of at least one of methyl acetate and acetic acid. The process is carried out by (a) contacting a carbonylatable reactant selected from methanol, dimethyl ether and dimethyl carbonate and carbon monoxide in a reactor with a zeolite catalyst and recovering a product stream containing at least one of methyl acetate and acetic acid from the reactor, (b) ceasing contact of the catalyst with the carbonylatable reactant, (c) regenerating the catalyst with a regenerating gas selected from hydrogen or a mixture of hydrogen and carbon monoxide at a temperature in the range 250 to 600 C, and (d) terminating the hydrogen regenerating step and resuming contact of the catalyst with the carbonylatable reactant and carbon monoxide.

摘要翻译： 用于在羰基化方法中原位再生沸石催化剂以生产乙酸甲酯和乙酸中的至少一种的方法。 该方法通过以下步骤进行：（a）在反应器中使沸石催化剂使选自甲醇，二甲醚和碳酸二甲酯的羰基化反应物与一氧化碳接触，并从反应器中回收含有至少一种乙酸甲酯和乙酸的产物流 （b）停止催化剂与可羰基化反应物的接触，（c）在选自氢气或氢气和一氧化碳的混合物中的再生气体在250至600℃的温度范围内再生催化剂，和（d） 终止氢再生步骤并恢复催化剂与可羰基化反应物和一氧化碳的接触。

公开(公告)号：US20100317888A1

公开(公告)日：2010-12-16

申请号：US12735123

申请日：2008-12-16

申请人： Evert Jan Ditzel ,  David John Law ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

发明人： Evert Jan Ditzel ,  David John Law ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephan Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

IPC分类号： C07C67/36 ,  C07C67/37 ,  C07C51/12

CPC分类号： B01J29/90 ,  B01J29/20 ,  B01J38/14 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.

摘要翻译： 一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生 使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压力下接触，并且其中分子氧气体的分压使得催化剂的温度为 维持在225至325℃的范围内

公开(公告)号：US20100311567A1

公开(公告)日：2010-12-09

申请号：US12735122

申请日：2008-12-16

申请人： Edo Johann Becker ,  Evert Jan Ditzel ,  Harry Kaiser ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephen Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

发明人： Edo Johann Becker ,  Evert Jan Ditzel ,  Harry Kaiser ,  George Ernest Morris ,  Mark Stephen Roberts ,  Stephen Andreas Schunk ,  Martin Smit ,  John Glenn Sunley

IPC分类号： B01J38/10

CPC分类号： B01J29/06 ,  B01J29/20 ,  B01J29/50 ,  B01J29/65 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/90 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： A process for the in-situ regeneration of a zeolite catalyst in a carbonylation process for the production of at least one of methyl acetate and acetic acid by contacting methanol, dimethyl ethyl or dimethyl carbonate with carbon monoxide in the presence of a zeolite catalyst, ceasing contact of the catalyst with the reactant, regenerating the catalyst with a regenerating gas selected from hydrogen or a mixture of hydrogen and carbon monoxide at a temperature in the range 250 to 600° C., terminating the hydrogen regenerating step and resuming contact of the catalyst with the reactant and carbon monoxide.

摘要翻译： 一种用于在羰基化方法中原位再生沸石催化剂的方法，用于通过在沸石催化剂存在下使甲醇，二甲基乙基或碳酸二甲酯与一氧化碳接触来制备乙酸甲酯和乙酸中的至少一种，停止 催化剂与反应物的接触，用选自氢或氢和一氧化碳的混合物的再生气体在250-600℃的温度下再生催化剂，终止氢再生步骤并恢复催化剂的接触 与反应物和一氧化碳。

公开(公告)号：US07642392B2

公开(公告)日：2010-01-05

申请号：US10569441

申请日：2004-08-19

申请人： Richard Daniel Kay ,  George Ernest Morris ,  John Glenn Sunley

发明人： Richard Daniel Kay ,  George Ernest Morris ,  John Glenn Sunley

IPC分类号： C07C1/00

CPC分类号： C07C1/20 ,  C07C2527/125 ,  C07C2527/138 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G2400/02 ,  Y02P30/20

摘要： The present invention relates to a process for the production of branched chain hydrocarbons from methanol and/or dimethyl ether, which process comprises contacting, in a reactor, methanol and/or dimethyl ether with a catalyst comprising indium halide.

摘要翻译： 本发明涉及从甲醇和/或二甲醚生产支链烃的方法，该方法包括在反应器中使甲醇和/或二甲醚与包含卤化铟的催化剂接触。

公开(公告)号：US07915446B2

公开(公告)日：2011-03-29

申请号：US10563920

申请日：2004-06-23

申请人： Anthony Haynes ,  David John Law ,  Andrew Miller ,  George Ernest Morris ,  Marc John Payne ,  John Glenn Sunley

发明人： Anthony Haynes ,  David John Law ,  Andrew Miller ,  George Ernest Morris ,  Marc John Payne ,  John Glenn Sunley

IPC分类号： C07C51/16

CPC分类号： B01J23/468 ,  C07C51/12 ,  C07C53/08

摘要： A catalyst and process for the production of acetic acid by the carbonylation of methanol and/or a reactive derivative thereof. The catalyst system comprises an iridium carbonylation catalyst, methyl iodide co-catalyst, optionally at least one of ruthenium, osmium, rhenium, zinc, gallium, tungsten, cadmium, mercury and indium and at least one non-hydrohalogenoic acid promoter. The non-hydrohalogenoic acid may be an oxoacid, a superacid and/or a heteropolyacid.

摘要翻译： 用于通过甲醇和/或其反应性衍生物的羰基化生产乙酸的催化剂和方法。 催化剂体系包括铱羰基化催化剂，甲基碘助催化剂，钌，锇，铼，锌，镓，钨，镉，汞和铟中的至少一种和至少一种非氢卤酸促进剂。 非氢卤酸可以是含氧酸，超酸和/或杂多酸。

公开(公告)号：US06881325B2

公开(公告)日：2005-04-19

申请号：US09779287

申请日：2001-02-08

申请人： George Ernest Morris ,  Andrew Richard Lucy ,  William H. Gong ,  Monica Cristina Regalbuto ,  George A. Huff, Jr.

发明人： George Ernest Morris ,  Andrew Richard Lucy ,  William H. Gong ,  Monica Cristina Regalbuto ,  George A. Huff, Jr.

IPC分类号： C10G67/12 ,  C10G27/04

CPC分类号： C10G67/12

摘要： Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons, sulfur-containing and nitrogen-containing organic compounds. Oxidation feedstock is contacted with a soluble quaternary ammonium salt containing halogen, sulfate, or bisulfate anion, and an immiscible aqueous phase comprising a source of hydrogen peroxide, and at least one member of the group consisting of phosphomolybdic acid and phosphotungstic acid, in a liquid reaction mixture under conditions suitable for reaction of one or more of the sulfur-containing and/or nitrogen-containing organic compounds. Blending components containing less sulfur and/or less nitrogen than the oxidation feedstock are recovered from the reaction mixture. Advantageously, at least a portion of the immiscible acid-containing phase is recycled to the oxidation.

摘要翻译： 公开了经济方法，用于通过选择性氧化包含烃，含硫和含氮有机化合物的混合物的原料来生产用于运输燃料的炼油厂混合的组分。 氧化原料与含有卤素，硫酸盐或硫酸氢盐阴离子的可溶性季铵盐和包含过氧化氢源的不混溶水相和至少一种由磷钼酸和磷钨酸组成的组中的一种在液体中接触 反应混合物在适于一种或多种含硫和/或含氮有机化合物的反应条件下进行。 从反应混合物中回收含有比氧化原料少的硫和/或更少的氮的混合组分。 有利地，至少一部分不混溶的含酸相被再循环至氧化。