ETHYLENE-BASED POLYMERS AND PROCESSES TO MAKE THE SAME
    5.
    发明申请
    ETHYLENE-BASED POLYMERS AND PROCESSES TO MAKE THE SAME 有权
    基于乙烯的聚合物及其制备方法

    公开(公告)号:US20140135462A1

    公开(公告)日:2014-05-15

    申请号:US14127802

    申请日:2012-06-21

    IPC分类号: C08F4/52 C08F4/38

    摘要: The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene in the presence of at least one free-radical agent, and in the presence of a “metal alkyl-containing compound” selected from the group consisting of the following: i) at least one “Group II metal alkyl-containing compound,” ii) at least one “Group III metal alkyl-containing compound,” or iii) a combination of i) and ii). The invention also provides a composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization, and wherein the ethylene-based polymer has the following property: y>0.28567x−0.00032, wherein y=vinyl/1000 C, as determined by 1H NMR, and x=mol % polymerized ?-olefin, as determined by 13C NMR. The invention also provides a composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization, and wherein the ethylene-based polymer has the following properties: A) a vinyl content greater than, or equal to, 0.3 vinyl per 1000 C (total carbons), and B) a polymerized alpha-olefin level less than, or equal to, 1.00 mole percent, based on the total moles of polymerized monomers.

    摘要翻译: 本发明提供一种形成乙烯基聚合物的方法,所述方法包括在至少一种自由基试剂存在下使乙烯聚合,并在“含金属烷基化合物”存在下,选自 以下:i)至少一种“II族金属烷基化合物”,ii)至少一种“III族金属烷基化合物”,或iii)i)和ii)的组合。 本发明还提供一种包含至少一种由自由基聚合制备的乙烯基聚合物的组合物,其中乙烯类聚合物具有以下性质:y> 0.28567x-0.00032,其中y =乙烯基/ 1000℃, 通过1 H NMR测定,x = mol%聚合的α-烯烃,通过13 C NMR测定。 本发明还提供一种组合物,其包含由自由基聚合制备的至少一种基于乙烯的聚合物,并且其中所述乙烯类聚合物具有以下性质:A)乙烯基含量大于或等于0.3乙烯基/ 1000℃(总碳),和B)聚合的α-烯烃含量小于或等于1.00摩尔%,基于聚合单体的总摩尔数。

    Ethylene-based polymers with improved melt strength and processes for the same
    9.
    发明授权
    Ethylene-based polymers with improved melt strength and processes for the same 有权
    具有改善熔体强度的乙烯基聚合物及其制备方法

    公开(公告)号:US09388260B2

    公开(公告)日:2016-07-12

    申请号:US14367849

    申请日:2012-12-10

    摘要: The invention provides an ethylene-based polymer formed from at least the following: ethylene and a monomeric chain transfer agent (monomeric CTA) selected from Structure 1: wherein L is selected from a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon; R1 is selected from hydrogen, a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon; R2 is selected from hydrogen, a saturated hydrocarbon or a substituted saturated hydrocarbon; R3 is selected from hydrogen, a saturated hydrocarbon or a substituted saturated hydrocarbon; and R4 is selected from a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon.

    摘要翻译: 本发明提供由以下至少一种形成的乙烯类聚合物:乙烯和选自结构1的单体链转移剂(单体CTA):其中L选自饱和烃,取代的饱和烃,不饱和烃或 取代的不饱和烃; R1选自氢,饱和烃,取代的饱和烃,不饱和烃或取代的不饱和烃; R2选自氢,饱和烃或取代的饱和烃; R3选自氢,饱和烃或取代的饱和烃; 并且R 4选自饱和烃,取代的饱和烃,不饱和烃或取代的不饱和烃。