摘要:
Improved reaction processes comprise reacting a mixture to form a product comprising a metal alkyl, metal oxide, or mixture thereof and then passing said product to a post-reactor heat exchanger. The improvement comprises one or more of the following: (1) reacting said metal alkyl compound with an acid to produce a soluble metal ester; or (2) adding an ionic surfactant; or (3) adding a mixture comprising an antioxidant to the product under conditions sufficient to avoid formation of significant amounts of insoluble metal or metal compounds derived from said metal alkyl compound; or (4) purging said post-reactor heat exchanger with an inert gas under conditions to remove metal oxide from the post-reactor heat exchanger.
摘要:
Improved reaction processes comprise reacting a mixture to form a product comprising a metal alkyl, metal oxide, or mixture thereof and then passing said product to a post-reactor heat exchanger. The improvement comprises one or more of the following: (1) reacting said metal alkyl compound with an acid to produce a soluble metal ester; or (2) adding an ionic surfactant; or (3) adding a mixture comprising an antioxidant to the product under conditions sufficient to avoid formation of significant amounts of insoluble metal or metal compounds derived from said metal alkyl compound; or (4) purging said post-reactor heat exchanger with an inert gas under conditions to remove metal oxide from the post-reactor heat exchanger.
摘要:
The invention provides a process to form an ethylene-based polymer composition, the process comprising at least the following: Step 1: polymerizing a first ethylene-based polymer in the presence of at least one molecular catalyst and a hydrocarbon chain transfer agent, and at a polymerization pressure of at least 14,000 psi; Step 2: polymerizing a second ethylene-based polymer.
摘要:
A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
摘要:
The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene in the presence of at least one free-radical agent, and in the presence of a “metal alkyl-containing compound” selected from the group consisting of the following: i) at least one “Group II metal alkyl-containing compound,” ii) at least one “Group III metal alkyl-containing compound,” or iii) a combination of i) and ii). The invention also provides a composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization, and wherein the ethylene-based polymer has the following property: y>0.28567x−0.00032, wherein y=vinyl/1000 C, as determined by 1H NMR, and x=mol % polymerized ?-olefin, as determined by 13C NMR. The invention also provides a composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization, and wherein the ethylene-based polymer has the following properties: A) a vinyl content greater than, or equal to, 0.3 vinyl per 1000 C (total carbons), and B) a polymerized alpha-olefin level less than, or equal to, 1.00 mole percent, based on the total moles of polymerized monomers.
摘要翻译:本发明提供一种形成乙烯基聚合物的方法,所述方法包括在至少一种自由基试剂存在下使乙烯聚合,并在“含金属烷基化合物”存在下,选自 以下:i)至少一种“II族金属烷基化合物”,ii)至少一种“III族金属烷基化合物”,或iii)i)和ii)的组合。 本发明还提供一种包含至少一种由自由基聚合制备的乙烯基聚合物的组合物,其中乙烯类聚合物具有以下性质:y> 0.28567x-0.00032,其中y =乙烯基/ 1000℃, 通过1 H NMR测定,x = mol%聚合的α-烯烃,通过13 C NMR测定。 本发明还提供一种组合物,其包含由自由基聚合制备的至少一种基于乙烯的聚合物,并且其中所述乙烯类聚合物具有以下性质:A)乙烯基含量大于或等于0.3乙烯基/ 1000℃(总碳),和B)聚合的α-烯烃含量小于或等于1.00摩尔%,基于聚合单体的总摩尔数。
摘要:
A process is taught, comprising polymerizing ethylene in the presence of a catalyst to form a crystalline ethylene-based polymer having a crystallinity of at least 50% as determined by DSC Crystallinity in a first reactor or a first part of a multi-part reactor and reacting the crystalline ethylene-based polymer with additional ethylene in the presence of a free-radical initiator to form an ethylenic polymer in at least one other reactor or a later part of a multi-part reactor.
摘要:
A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
摘要:
A process is taught, comprising polymerizing ethylene in the presence of a catalyst to form a crystalline ethylene-based polymer having a crystallinity of at least 50% as determined by DSC Crystallinity in a first reactor or a first part of a multi-part reactor and reacting the crystalline ethylene-based polymer with additional ethylene in the presence of a free-radical initiator to form an ethylenic polymer in at least one other reactor or a later part of a multi-part reactor.
摘要:
The invention provides an ethylene-based polymer formed from at least the following: ethylene and a monomeric chain transfer agent (monomeric CTA) selected from Structure 1: wherein L is selected from a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon; R1 is selected from hydrogen, a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon; R2 is selected from hydrogen, a saturated hydrocarbon or a substituted saturated hydrocarbon; R3 is selected from hydrogen, a saturated hydrocarbon or a substituted saturated hydrocarbon; and R4 is selected from a saturated hydrocarbon, a substituted saturated hydrocarbon, an unsaturated hydrocarbon, or a substituted unsaturated hydrocarbon.
摘要:
The invention provides a process to form an ethylene-based polymer composition, the process comprising at least the following: Step 1: polymerizing a first ethylene-based polymer in the presence of at least one molecular catalyst and a hydrocarbon chain transfer agent, and at a polymerization pressure of at least 14,000 psi; Step 2: polymerizing a second ethylene-based polymer.