摘要:
The invention relates to the use of a weakly acid cation exchange resin for chromatographic separation of carbohydrates. In the invention the hydrophilic/hydrophobic interaction of carbohydrates, sugars and sugar alcohols with the weakly acid cation exchange resin is utilized. The weakly acid cation exchange resin is used for separation of hydrophobic saccharides, such as deoxy, methyl and anhydrosugars and anhydrosugaralcohols from more hydrophilic saccharides.
摘要:
The invention relates to sulphonated polymer resins, particularly polymer resins with a sulphonated shell layer, and the preparation thereof. Resins according to the invention are prepared by sulphonating a polymer in a non-swollen state with substantially pure gaseous sulphur trioxide substantially in the shell layer of the polymer particles. The polymer to be sulphonated can be for example a styrene-DVB copolymer. The resins according to the invention can be used for example as chromatographic resins, ion-exchange resins and catalyst resins.
摘要:
The invention relates to a system and a process for fractionating a solution into two or more fractions. The system of the invention comprises at least two compartments having a diameter of at least about one meter and including a uniform packing of a polymer-based ion exchange resin with a bead size in the range of about 50 to about 250 μm. The mixing volume of the fluid fronts in the system of the invention is not more than 5% of the volume of the compartment.
摘要:
The invention relates to the recovery of deoxy sugars, such as fucose from biomass-derived solutions, such as spent liquors obtained from pulping processes. The invention is based on the use of chromatographic fractionation with specific column packing materials and combinations thereof. The deoxy sugar product obtained from the chromatographic fractionation may be further purified by crystallization. The invention also provides a novel crystalline fucose product and a novel process for the crystallization of fucose.
摘要:
The invention relates to a chromatographic separation process of recovering mannose with high purity. The invention is based on the use of a chromatographic separation resin including a resin which is at least partly in a Ba2+ form resin and a resin which is in other than Ba2+ form.
摘要:
The invention relates to a process of recovering galactose from a solution derived from plant-based biomass. In the process of the invention, the starting solution is subjected to one or more chromatographic fractionation steps, which may carried out with a strongly basic anion exchange resin and optionally with a strongly acid cation exchange resin, in any desired sequence, followed by recovering at least one fraction enriched in galactose. The galactose fraction thus obtained is further purified by crystallization to obtain crystalline galactose. The invention also relates to non-animal derived crystalline D-galactose.
摘要:
The present invention relates to a method of fractionating liquid mixtures or solutions, comprising the steps of subjecting a feed in the form of a liquid mixture or solution to a first chromatographic separation, thereby recovering at least a fraction (A) and a fraction (B) both containing a first component or product, subjecting a mixture or solution derived from or comprising said fraction (A) to a second chromatographic separation, thereby recovering at least a fraction (C) rich in said first component or product and subjecting a mixture or solution derived from or comprising said fraction (B) to a third chromatographic separation, thereby recovering at least a fraction (D) also rich in said first component or product, and whereby at least two fractions are recovered from the second and third chromatographic separations.
摘要:
The present invention relates to a method of separating sugars and sugar alcohols from each other. More particularly the present invention relates to the use of a weakly basic anion exchange resin in a chromatographic separation process. The advantage of the present invention compared with the prior art is that it is especially suitable for separating reducing sugars in acidic conditions as well as for example in weakly acidic conditions. The method using chromatographic separation comprises at least one step where a weakly basic anion exchange resin is used in a chromatographic column or in a part of a column.
摘要:
The present invention relates to a process for the production of xylitol. The process utilises ribulose for the preparation of xylitol and involves several different conversion reactions, such as reduction, epimerisation and/or isomerisation. The present invention also relates to the use of ribulose for the preparation of xylitol.
摘要:
The present invention relates to the production of xylitol. In particular, processes utilising L-xylose as an intermediate for xylitol production are described. The present invention also relates to process for the preparation or L-xylose, as an intermediate, by-product or end-product to be used per se.