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公开(公告)号：US20080234510A1
公开(公告)日：2008-09-25
申请号：US11628953
申请日：2005-06-09
摘要： The invention relates to a method of obtaining polyoxygenated organic compounds. The inventive method is characterized in that it comprises the oxidation reaction of a diether, preferably an acetal, with an oxygen source, in the presence of: one or more radical initiating agents, one or more additives that generate a basic reaction medium, and one or more catalysts.
摘要翻译： 本发明涉及获得聚氧化有机化合物的方法。 本发明的方法的特征在于，它包括二醚，优选缩醛与氧源的氧化反应，存在下：一种或多种自由基引发剂，一种或多种产生碱性反应介质的添加剂和一种 或更多的催化剂。
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2.发明授权公开(公告)号：US06191323B1
公开(公告)日：2001-02-20
申请号：US09557300
申请日：2000-04-25
申请人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
发明人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
IPC分类号： C07C2914
CPC分类号： C07C29/14 , B01J29/04 , B01J29/89 , C07C29/143 , C07C2601/14 , Y10S423/27 , C07C35/12 , C07C35/08
摘要： A process for the reduction of ketones or aldehydes to alcohols has been developed. The process involves contacting the ketone or aldehyde with a primary or secondary alcohol and a catalyst at reduction conditions. The catalyst is a molecular sieve having the empirical formula: (MwSnxTiySi1-x-y-zGez)O2 where M is a trivalent metal such as aluminum or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译： 已经开发了将酮或醛还原成醇的方法。 该方法包括在还原条件下使酮或醛与伯醇或仲醇和催化剂接触。 催化剂是具有以下经验式的分子筛：其中M是三价金属如铝或硼。 这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。
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3.发明申请METHOD AND CATALYSTS FOR THE EPOXIDATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF OXYGEN 审中-公开氧气存在下氧化烯烃的方法和催化剂公开(公告)号：US20090234145A1
公开(公告)日：2009-09-17
申请号：US11911836
申请日：2006-04-06
IPC分类号： C07D301/04
CPC分类号： B01J29/0325 , B01J21/063 , B01J23/66 , B01J29/89 , B01J31/0274 , B01J35/006 , B01J2229/18 , B01J2229/32 , C07D301/10 , C07D303/04
摘要： The invention relates to a method for the epoxidation of an olefinic compound, which is characterised in that it comprises an oxidation reaction of at least one olefinic compound containing one or more double bonds C═C with oxygen in the presence of one or more reaction initiating agents, at least one catalyst containing at least one metal that is selected from a noble metal, a transition metal and mixtures of same, and at least one hydrocarbon that is selected from one or more branched alkanes, one or more alkyl cyclic or cyclic hydrocarbons, one or more alkyl aromatic or aromatic compounds and mixtures of same.
摘要翻译： 本发明涉及一种烯烃化合物的环氧化方法，其特征在于它包含在一种或多种反应引发剂存在下至少一种含有一个或多个双键CC与氧的烯属化合物的氧化反应， 至少一种含有至少一种选自贵金属，过渡金属及其混合物的金属的催化剂和至少一种选自一种或多种支链烷烃，一种或多种烷基环状或环状烃的烃，一种 或更多烷基芳族或芳族化合物及其混合物。
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4.发明申请METHOD FOR EXTRACTING BIOCHEMICAL PRODUCTS OBTAINED FROM A PROCESS OF HYDROTHERMAL CARBONIZATION OF BIOMASS 有权从生物质热水碳酸化过程中提取生物化学产品的方法公开(公告)号：US20140142353A1
公开(公告)日：2014-05-22
申请号：US14114818
申请日：2011-12-22
申请人： Martin Hitzl , Michael Renz , Avelino Corma Canos
发明人： Martin Hitzl , Michael Renz , Avelino Corma Canos
IPC分类号： C10G1/00
CPC分类号： C10G1/002 , C10G1/008 , C10G1/02 , C10G2300/1011 , C10L9/086 , C10L2290/54 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.
摘要翻译： 本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器， 其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在 预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体 垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。 本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。
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5.发明授权Aldehyde conversion method using a molecular sieve and the use of the molecular sieve as a catalyst in said method 失效使用分子筛的醛转化方法和在所述方法中使用分子筛作为催化剂公开(公告)号：US07087779B2
公开(公告)日：2006-08-08
申请号：US10932564
申请日：2004-09-02
IPC分类号： C07D331/02 , C07D301/12 , C07C69/76
CPC分类号： C07C51/285 , B01J29/0308 , B01J29/035 , B01J29/04 , B01J29/7057 , C01B37/005 , C01B39/085 , C07C51/235 , C07C67/39 , C07C63/04 , C07C65/21 , C07C69/017 , C07C69/08 , C07C69/10
摘要： The invention relates to an aldehyde conversion method comprising putting an aldehyde into contact with oxygenated water and with a catalyst, under oxidation conditions, wherein the catalyst is a molecular sieve with pores of a diameter of at least 0.52 nm and has an empirical formula in a calcined and dehydrated form of (SnxTiySi1-x-y-zGez)O2 wherein x is a molar fraction of the tin and has a value between 0.001 and 0.1; y is a molar fraction of titanium and has a value from zero to 0.1; and z is the molar fraction molar of the germanium and has a value from zero to 0.08.
摘要翻译： 本发明涉及醛转化方法，其包括在氧化条件下将醛与含氧水和催化剂接触，其中催化剂是直径为至少0.52nm的孔的分子筛，并且具有经验式 煅烧和脱水形式的<？in-line-formula description =“In-line Formulas”end =“lead”？（Sn x x Ti x Si x Si α-in-line-formula description =“In-line Formulas”end =“tail”？>其中x（x，y） 是锡的摩尔分数，其值在0.001和0.1之间; y是钛的摩尔分数，其值为0至0.1; z是锗的摩尔分数摩尔，其值为零至0.08。
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公开(公告)号：US06344583B1
公开(公告)日：2002-02-05
申请号：US09557302
申请日：2000-04-25
IPC分类号： C07C6902
CPC分类号： C07D315/00 , C07D309/30
摘要： Applicants have developed a process for the oxidation of ketones to esters. The process involves contacting the ketone with hydrogen peroxide and a catalyst at oxidation conditions. The catalyst is a molecular sieve represented by the empirical formula: (MwSnxTiySi1−x−y−zGez)O2 where M is a trivalent metal such as aluminum or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译： 申请人已经开发了将酮氧化成酯的方法。 该方法包括在氧化条件下使酮与过氧化氢和催化剂接触。 催化剂是由经验式表示的分子筛：其中M是三价金属如铝或硼。 这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。
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7.发明授权公开(公告)号：US09556384B2
公开(公告)日：2017-01-31
申请号：US14114818
申请日：2011-12-22
申请人： Martin Hitzl , Michael Renz , Avelino Corma Canos
发明人： Martin Hitzl , Michael Renz , Avelino Corma Canos
CPC分类号： C10G1/002 , C10G1/008 , C10G1/02 , C10G2300/1011 , C10L9/086 , C10L2290/54 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.
摘要翻译： 本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器， 其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在 预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体 垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。 本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。
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8.发明授权公开(公告)号：US10005073B2
公开(公告)日：2018-06-26
申请号：US14005325
申请日：2012-03-15
申请人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
发明人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
CPC分类号： B01J29/40 , B01J37/0018 , B01J37/0036 , B01J2229/18 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2529/70 , Y02P20/52 , C07C11/02 , C07C11/06
摘要： The present invention relates to a process for preparing phosphorus containing zeolite type catalysts based on crystalline aluminosilicates, the catalysts of this process and the use of these catalysts for the conversion of methanol to olefins.
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公开(公告)号：US08115001B2
公开(公告)日：2012-02-14
申请号：US11597808
申请日：2005-05-25
IPC分类号： C07D221/18
CPC分类号： C01B39/48 , B01J29/035 , B01J29/70 , C01B37/02 , C10G11/05 , C10G49/08 , C10G2300/1092 , C10G2300/1096 , C10G2400/30
摘要： The invention relates to a laminar microporous crystalline zeolite material known as ITQ-30 which, as when synthesized, has a chemical composition in the anhydrous state with the following molar relations: x (M1/n XO2):y YO2:SiO2:z R, wherein: x represents a value less than 0.1, which can be equal to zero; y has a value of less than 0.1, which can be equal to zero; z has a value of less than 0.1; M is selected from among H+, NH4+, one or more +n inorganic cations and combinations of same; X represents one or more +3 oxidation state chemical elements; Y represents one or more +4 oxidation state chemical elements; and R represents one or more organic compounds. The invention also relates to the method of preparing said zeolite, involving the use of one or more organic additives in a reaction mixture which is crystallized by means of heating, and to the use thereof in processes for the separation and transformation of organic compounds.
摘要翻译： 本发明涉及一种称为ITQ-30的层状微孔结晶沸石材料，其当合成时具有以下摩尔关系的无水状态的化学组成：x（M1 / n XO2）：y YO2：SiO2：zR ，其中：x表示小于0.1的值，其可以等于零; y的值小于0.1，可以等于零; z的值小于0.1; M选自H +，NH4 +，一种或多种+ n种无机阳离子及其组合; X表示一种或多种+3氧化态化学元素; Y表示一个或多个+4氧化态化学元素; R表示一种或多种有机化合物。 本发明还涉及制备所述沸石的方法，涉及在通过加热结晶的反应混合物中使用一种或多种有机添加剂，以及其用于分离和转化有机化合物的方法中的用途。
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公开(公告)号：US20110282099A1
公开(公告)日：2011-11-17
申请号：US13133410
申请日：2009-11-26
IPC分类号： C07C211/51
CPC分类号： C07C209/60 , C07C209/78 , C07C211/50
摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps ofa) condensing aniline and formaldehyde, providing a condensate, the molar ratio of aniline to formaldehyde being chosen in the range of 2 to 3.5;b) reacting, in a first catalytic reaction step, at a reaction temperature within the range of about 30° C. to about 100° C., said condensate over a solid catalyst being chosen from the group consisting of clays, silicates, silica-aluminas and ion exchange resins, whereby an intermediate mixture is provided, the intermediate mixture comprising amino benzyl amines;c) converting, in a subsequent catalytic reaction step, at a temperature within the range of about 70° C. to about 250° C., the reaction temperature in said subsequent catalytic reaction step is higher than the reaction temperature in said first catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst being chosen from the group consisting of zeolites, delaminated zeolites and ordered mesoporous materials, thereby providing said methylene-bridged polyphenyl polyamines.
摘要翻译： 根据本发明的由苯胺和甲醛提供亚甲基桥接的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合，提供缩合物，苯胺与甲醛的摩尔比选择在2至3.5的范围内; b）在第一催化反应步骤中，在约30℃至约100℃范围内的反应温度下使所述缩合物在固体催化剂上选自粘土，硅酸盐，二氧化硅 - 氧化铝和离子交换树脂，由此提供中间体混合物，所述中间体混合物包含氨基苄基胺; c）在随后的催化反应步骤中，在约70℃至约250℃的温度范围内转化，所述后续催化反应步骤中的反应温度高于所述第一催化反应中的反应温度 在随后的固体催化剂存在下将所述中间体混合物形成亚甲基桥连的聚苯胺，所述固体催化剂选自沸石，分层沸石和有序介孔材料，从而提供所述亚甲基桥连的聚苯基多胺。
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