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公开(公告)号:US20240336772A1
公开(公告)日:2024-10-10
申请号:US18294679
申请日:2022-08-03
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Oliver WAGNER , Konrad ROSCHMANN
IPC: C08L51/00 , C08F2/00 , C08F2/26 , C08F2/38 , C08F220/06 , C08F220/14 , C08F220/18 , C08F220/56 , C08F226/06 , C08K5/5435 , C09D151/00
CPC classification number: C08L51/003 , C08F2/001 , C08F2/26 , C08F2/38 , C08F220/06 , C08F220/14 , C08F220/1804 , C08F220/1808 , C08F220/56 , C08F226/06 , C08K5/5435 , C09D151/006 , C08L2201/52 , C08L2207/53
Abstract: The present invention relates to a process for modifying an aqueous polymer latex of polymer particles that bear carboxyl groups comprising the mixing of the aqueous polymer latex with at least one silane compound of formula (1) at a temperature of at least 60° C.: (RO)3-nR1nSiR2X (1) wherein R is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C1-C10-alkoxy-C1-C10-alkyl, C2-C10-alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C2-C10- alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R2 is a covalent chemical bond or a C1-C20-alkylene, in which non-adjacent methylene units can be replaced by O-groups, n is 0, 1, 2 or 3, and X is a radical having 3 to 10 carbon atoms and bearing an oxirane group. The present invention also relates to modified aqueous polymer latexes obtainable by such process and to the use of these polymer latexes as binders or co-binders for industrial varnishes.
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公开(公告)号:US20250101248A1
公开(公告)日:2025-03-27
申请号:US18698054
申请日:2022-09-26
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Oliver WAGNER , Konrad ROSCHMANN
IPC: C09D15/00 , C08F8/28 , C08F220/18 , C09D5/02 , C09D133/06
Abstract: The present invention relates to use of an aqueous polymer composition containing a water-soluble or water-dispersible polymer P made of polymerized ethylenically unsaturated monomers M comprising. 30 to 90 wt.-%, based on the total weight of monomers M, of at least one monomer M1 selected from C1-C12-alkyl esters of monoethylenically unsaturated carboxylic acids, C6-C10-cycloalkyl esters of monoethylenically unsaturated carboxylic acids and monovinylaromatic hydrocarbon monomers, 5 to 30 wt.-%, based on the total weight of monomers M, of at least one monomer M2 selected from monoethylenically unsaturated monomers containing at least one acid group, and 5 to 40 wt.-%, based on the total weight of monomers M, of at least one monomer M3 different from M2 which has a reactive functional group being capable of being crosslinked, wherein the total weight of monomers M1, M2 and M3 corresponds to at least 90% of the total weight of monomers M; wherein the monomers M are selected such that the theoretical glass transition temperature according to Fox (Tgt) of the polymer P is at most 80° C.; and wherein the polymer P is dissolved or dispersed in an aqueous phase such that the acid groups of the polymer P are totally or partially neutralized; as a staining composition for porous materials. The present invention also relates to an aqueous polymer composition containing said water-soluble or water-dispersible polymer P made of polymerized ethylenically unsaturated monomers M and a crosslinking agent.
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公开(公告)号:US20160126548A1
公开(公告)日:2016-05-05
申请号:US14889577
申请日:2014-04-30
Applicant: BASF SE
Inventor: Simon SCHROEDLE , Oliver WAGNER , Kai DOERING , Aleksei VOLKOV
CPC classification number: H01M4/505 , C01G53/006 , C01G53/44 , C01P2004/61 , C01P2004/84 , C01P2006/11 , C01P2006/40 , H01M4/525
Abstract: Spherical particles comprising a lithiated mixed transition metal oxide comprising nickel, cobalt and manganese and optionally at least one further transition metal, each in cationic form, wherein the carbonate content, calculated as Li2CO3, is in the range from 0.01 to 0.3% by weight, based on overall particles, and the proportion of nickel, plotted against the radius of the particles in question, in the outer region of the particles is at least 10 mol % below the proportion in the core, and the manganese content, plotted against the radius of the particles in question, in the outer region of the particles is at least 10 mol % above the proportion in the core, and where mol % are based on the total transition metal content.
Abstract translation: 包含镍,钴和锰的锂化混合过渡金属氧化物和任选至少一种阳离子形式的另外的过渡金属的球形颗粒,其中以Li 2 CO 3计算的碳酸盐含量为0.01至0.3重量% 基于总体颗粒,并且在颗粒的外部区域中相对于所述颗粒的半径绘制的镍的比例比芯中的比例低至少10摩尔%,并且锰含量相对于半径 的颗粒的外部区域比核心中的比例高至少10摩尔%,其中摩尔%基于总过渡金属含量。
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