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公开(公告)号:US20190144585A1
公开(公告)日:2019-05-16
申请号:US16098010
申请日:2017-05-03
Applicant: BASF SE
Inventor: Tanja ROST , Roelof BALK , Immanuel WILLERICH , Sebastian ENCK , Joost LESWIN , Wolfgang GASCHLER , Martin Robert SCHEUBLE
IPC: C08F220/18 , C08F220/06 , C08F212/08 , C08F2/22 , C08K3/22 , C09D133/02 , C09D133/12
Abstract: Disclosed herein is a process for preparing an aqueous polymer latex by polymerising a monomer composition M by a radical emulsion polymerisation, where at least 95% of the monomer composition M is metered during a period P to the polymerisation reaction under polymerisation conditions, such that during at least one period P(n) within the period P, the relative amount of monomers M2, which are metered to the polymerisation reaction during the periods P(n), to the total amount of the monomer composition M, which is metered to the polymerisation reaction during said period P(n), is at least 1% by weight higher than the relative amount of monomers M2, which are metered to the polymerisation reaction outside of each of said periods P(n), to the total amount of the monomer composition M, which is metered to the polymerisation reaction outside of each of said periods P(n).
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公开(公告)号:US20170275407A1
公开(公告)日:2017-09-28
申请号:US15512303
申请日:2015-09-18
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER
IPC: C08F265/06 , C09D5/00 , C09D151/00
CPC classification number: C08F265/06 , C08F2/26 , C09D5/00 , C09D151/003 , C08F220/28 , C08F2220/286 , C08F220/38 , C08F2220/382 , C08F230/02
Abstract: The present invention relates to a polymer dispersion obtainable by at least one two-stage emulsion polymerization, by 1) preparing a polymer A by a radical polymerization from a 1st composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier, 2) admixing the polymer A prepared at 1) with a base, 3) in the presence of the polymer A treated at 2), preparing a polymer B by radical polymerization from a 2nd composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier. The present invention also relates to a process for preparing the polymer dispersion of the invention, to coating materials in the form of an aqueous composition comprising the polymer dispersion of the invention, and to the use of the polymer dispersion of the invention for coating compositions or paints and varnishes.
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3.
公开(公告)号:US20140107249A1
公开(公告)日:2014-04-17
申请号:US14134481
申请日:2013-12-19
Applicant: BASF SE
Inventor: Roelof BALK , Rolf DERSCH , Sebastian ROLLER , Bernhard SCHULER
IPC: C09D5/02
CPC classification number: C09D5/022 , C08F2/24 , C08F2/46 , C08F220/18 , C08F220/40 , C08F2220/1825 , C09D4/00 , C09D133/066 , C08F212/08 , C08F220/06 , C08F220/56 , C08F2220/283
Abstract: The present invention provides aqueous emulsion polymers comprising (A) monomers A (B) at least one (meth)acrylate with olefinically unsaturated side groups (monomers B), and (C) at least one photoinitiator, and also the use thereof in coating materials, more particularly in exterior architectural paints.
Abstract translation: 本发明提供包含(A)单体A(B)至少一种具有烯属不饱和侧基(单体B)的(甲基)丙烯酸酯和(C)至少一种光引发剂的水性乳液聚合物,以及其在涂料中的用途 ,更具体地在外部建筑涂料中。
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公开(公告)号:US20220325125A1
公开(公告)日:2022-10-13
申请号:US17265224
申请日:2019-07-22
Applicant: BASF SE
Inventor: Bastiaan LOHMEIJER , Roelof BALK , Robert WRAZIDLO
IPC: C09D133/12 , C08F2/22 , C09D5/02 , C09D125/14
Abstract: The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers M having a polymer content of at least 55 wt. % and a polymodal particle size distribution of the polymer particles of the polymer dispersion. The invention also relates to aqueous polymer dispersions obtained from this process as well as aqueous liquid compositions comprising at least one aqueous polymer dispersion and the use of such aqueous liquid compositions as binder.
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公开(公告)号:US20180305471A1
公开(公告)日:2018-10-25
申请号:US15523800
申请日:2015-11-03
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER
IPC: C08F2/26 , C08F220/14 , C08F265/06 , C08F6/20
CPC classification number: C08F2/26 , C08F2/001 , C08F6/20 , C08F220/14 , C08F265/06 , C09D151/003
Abstract: The present invention relates to a method for producing an aqueous polymer dispersion by radical-initiated aqueous emulsion polymerization of ethylenically unsaturated monomers, and to polymer dispersions obtainable according to said method. The invention also relates to the use of the said polymer dispersions, in particular for the production of coating products for wood.
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公开(公告)号:US20240336772A1
公开(公告)日:2024-10-10
申请号:US18294679
申请日:2022-08-03
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Oliver WAGNER , Konrad ROSCHMANN
IPC: C08L51/00 , C08F2/00 , C08F2/26 , C08F2/38 , C08F220/06 , C08F220/14 , C08F220/18 , C08F220/56 , C08F226/06 , C08K5/5435 , C09D151/00
CPC classification number: C08L51/003 , C08F2/001 , C08F2/26 , C08F2/38 , C08F220/06 , C08F220/14 , C08F220/1804 , C08F220/1808 , C08F220/56 , C08F226/06 , C08K5/5435 , C09D151/006 , C08L2201/52 , C08L2207/53
Abstract: The present invention relates to a process for modifying an aqueous polymer latex of polymer particles that bear carboxyl groups comprising the mixing of the aqueous polymer latex with at least one silane compound of formula (1) at a temperature of at least 60° C.: (RO)3-nR1nSiR2X (1) wherein R is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C1-C10-alkoxy-C1-C10-alkyl, C2-C10-alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C2-C10- alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R2 is a covalent chemical bond or a C1-C20-alkylene, in which non-adjacent methylene units can be replaced by O-groups, n is 0, 1, 2 or 3, and X is a radical having 3 to 10 carbon atoms and bearing an oxirane group. The present invention also relates to modified aqueous polymer latexes obtainable by such process and to the use of these polymer latexes as binders or co-binders for industrial varnishes.
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公开(公告)号:US20210269573A1
公开(公告)日:2021-09-02
申请号:US17257969
申请日:2019-07-04
Inventor: Massimo BANDIERA , Roelof BALK , Bastiaan LOHMEIJER , Maria Jesus BARANDIARAN
IPC: C08F265/06 , C09D151/00 , C08J3/07
Abstract: The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers, where the process has a first polymerization step as an aqueous radical emulsion polymerization of a first monomer composition M.a and a subsequent further polymerization step as an aqueous radical emulsion polymerization of a second monomer composition M.b,
where the monomers M comprise at least one monomer M0 which is selected from compounds of formula 1, wherein X is Cl, Br or OS(O)2R3, Y is H, Cl, Br, OS(O)2R4, C1-C10-alkyl, or C(═O)OR5, R1 is H or C1-C10-alkyl, R2 is H or C1-C10-alkyl, R3 is C1-C10-alkyl, R4 is C1-C10-alkyl, R5 is C1-C20-alkyl. The invention also relates to an aqueous polymer dispersion obtainable by such a process as well as the use of such dispersions.-
公开(公告)号:US20250101248A1
公开(公告)日:2025-03-27
申请号:US18698054
申请日:2022-09-26
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Oliver WAGNER , Konrad ROSCHMANN
IPC: C09D15/00 , C08F8/28 , C08F220/18 , C09D5/02 , C09D133/06
Abstract: The present invention relates to use of an aqueous polymer composition containing a water-soluble or water-dispersible polymer P made of polymerized ethylenically unsaturated monomers M comprising. 30 to 90 wt.-%, based on the total weight of monomers M, of at least one monomer M1 selected from C1-C12-alkyl esters of monoethylenically unsaturated carboxylic acids, C6-C10-cycloalkyl esters of monoethylenically unsaturated carboxylic acids and monovinylaromatic hydrocarbon monomers, 5 to 30 wt.-%, based on the total weight of monomers M, of at least one monomer M2 selected from monoethylenically unsaturated monomers containing at least one acid group, and 5 to 40 wt.-%, based on the total weight of monomers M, of at least one monomer M3 different from M2 which has a reactive functional group being capable of being crosslinked, wherein the total weight of monomers M1, M2 and M3 corresponds to at least 90% of the total weight of monomers M; wherein the monomers M are selected such that the theoretical glass transition temperature according to Fox (Tgt) of the polymer P is at most 80° C.; and wherein the polymer P is dissolved or dispersed in an aqueous phase such that the acid groups of the polymer P are totally or partially neutralized; as a staining composition for porous materials. The present invention also relates to an aqueous polymer composition containing said water-soluble or water-dispersible polymer P made of polymerized ethylenically unsaturated monomers M and a crosslinking agent.
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公开(公告)号:US20220235229A1
公开(公告)日:2022-07-28
申请号:US17608649
申请日:2020-05-07
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Robert WRAZIDLO
IPC: C09D5/02 , C08F220/18 , C08K3/22 , C09D133/06 , C09D7/61
Abstract: The present invention relates to aqueous polymer latexes of film-forming copolymers obtainable by aqueous emulsion polymerisation of monomers M, which comprise at least 80% by weight, based on the monomers M, of—at least one non-ionic monomer M1, which is selected from C1-C20-alkyl esters of acrylic acid, C5-C20-cycloalkyl esters of acrylic acid, C1-C20-alkyl esters of methacrylic acid, C5-C20-cycloalkyl esters of methacrylic acid and monovinyl aromatic monomers; —one or more monoethylenically unsaturated monomers M2, which are selected from monoethylenically unsaturated monocarboxylic acids having 3 to 6 carbon atoms and monoethylenically unsaturated dicarboxylic acids having 4 to 6 carbon atoms; and where the polymer latex contains an emulsifier combination comprising i. at least one first emulsifier (1), which is selected from salts, in particular from the alkali metal salts and the ammonium salts of sulfated ethoxylated C8-C20-alkanols having a degree of ethoxylation in the range from 5 to 20 and sulfated ethoxylated tristyrylphenols having a degree of ethoxylation in the range from 5 to 20, and ii. at least one second emulsifier (2), which is selected from the salts, in particular from the alkali metal salts and the ammonium salts of a sulfated ethoxylated C8-C20-alkanol having a degree of ethoxylation in the range from 21 to 50 and sulfated ethoxylated tristyrylphenols having a degree of ethoxylation in the range from 21 to 50. The present invention also relates to a process for producing such polymer latexes and to the use of these polymer latexes as binders in waterborne coating compositions which contain at least one inorganic tannin blocking compound and to the use of such coating compositions for coating tannin-containing substrates such as wood or woodbased materials.
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10.
公开(公告)号:US20190100613A1
公开(公告)日:2019-04-04
申请号:US16085807
申请日:2017-03-14
Applicant: BASF SE
Inventor: Roelof BALK , Bastiaan LOHMEIJER , Robert WRAZIDLO
IPC: C08F265/06 , C09D7/65 , C09D5/02 , C09D151/00 , C08K5/07 , C08F2/38 , C08F2/22
Abstract: The present invention provides very finely divided polymer dispersions obtainable by at least one two-stage emulsion polymerization, wherein 1) an acid-rich first polymer P1 is prepared by a radical polymerization from a 1st composition comprising A) at least one monomer selected from the group of (cyclo)alkyl (meth)acrylates, vinylaromatics having up to 20 carbon atoms, a radically polymerizable compound selected from the group of ethylenically unsaturated nitriles having up to 20 carbon atoms, vinyl esters of carboxylic acids containing up to 20 carbon atoms, vinyl halides having up to 10 carbon atoms, and vinyl ethers of alcohols containing 1 to 10 carbon atoms B) at least one α,β-ethylenically unsaturated carboxylic acid C) at least one crosslinking monomer with a keto or aldehyde group D) optionally at least one adhesion promoter E) optionally tert-butyl acrylate F) optionally further monomers M in the presence of a chain link transfer agent, 2) the polymer P1 prepared under 1) is admixed with a base, 3) a hydrophobic polymer P2 is prepared by radical polymerization, in the presence of the polymer P1 treated under 2), from a 2nd composition comprising A) at least one monomer selected from the group of (cyclo)alkyl (meth)acrylates, vinylaromatics having up to 20 carbon atoms, a radically polymerizable compound selected from the group of ethylenically unsaturated nitriles having up to 20 carbon atoms, vinyl esters of carboxylic acids containing up to 20 carbon atoms, vinyl halides having up to 10 carbon atoms, and vinyl ethers of alcohols containing 1 to 10 carbon atoms B) optionally at least one α,β-ethylenically unsaturated carboxylic acid C) at least one crosslinking monomer with a keto or aldehyde group D) optionally at least one adhesion promoter, and also E) optionally further monomers M, 4) and by optional addition, subsequent to the polymerization of P1 and P2, of a water-soluble at least trifunctional alkoxylated polyamine, more particularly an ethoxylated and/or propoxylated triamine.
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