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公开(公告)号:US11674014B2
公开(公告)日:2023-06-13
申请号:US16925747
申请日:2020-07-10
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Donald R. Allen , Wenji Quan , Bruno R. Pereira , Shigenobu Miura
IPC: C08K5/1545
CPC classification number: C08K5/1545
Abstract: Described herein are blends of starch or starch-based materials with polymeric materials, where the starch or starch-based material is intimately blended with the polymeric material, so as to exhibit very small particles sizes (e.g., less than 2 μm, or less than 1 μm) for the starch or starch-based material in the matrix of the polymeric material. Such intimate dispersion of very small particles provides for far more of the particles dispersed more evenly throughout the matrix of the polymeric material, which may enhance various performance characteristics of the blended composite material. Methods of producing articles from such blends exhibiting such small particles and excellent dispersion are also disclosed.
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公开(公告)号:US11046840B2
公开(公告)日:2021-06-29
申请号:US15691588
申请日:2017-08-30
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
Abstract: Described herein are methods for rendering biodegradable a plastic material that is not itself biodegradable, by blending the plastic material with a carbohydrate-based polymeric material that is formed from one or more starches, and a plasticizer (e.g., glycerin). The carbohydrate-based polymeric material is less crystalline than the starting starch materials, e.g., being substantially amorphous, and having a crystallinity of no more than 20%. Third party testing shows blends of such materials render the entire blend biodegradable, believed to be due to the low crystalline substantially amorphous carbohydrate-based polymeric material breaking the hygroscopic barrier associated with the non-biodegradable plastic material, so that when blended together, both the plastic material and the carbohydrate-based polymeric material are biodegradable.
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3.
公开(公告)号:US10919203B2
公开(公告)日:2021-02-16
申请号:US15481823
申请日:2017-04-07
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
IPC: B29C48/00 , C08J5/18 , B29C55/00 , B29C55/02 , B65D65/46 , B65D85/00 , B29C48/08 , C08L3/02 , B29K23/00 , B29L7/00 , B29L31/00
Abstract: Described herein are strength characteristics and biodegradation of articles produced using one or more petrochemical-based polymers and one or more carbohydrate-based polymers. A compatibilizer can optionally be included in the article. In some cases, the article can include a film or bag.
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4.
公开(公告)号:US20170218184A1
公开(公告)日:2017-08-03
申请号:US15481823
申请日:2017-04-07
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
CPC classification number: B29C48/022 , B29C48/0018 , B29C48/08 , B29C55/005 , B29C55/02 , B29K2003/00 , B29K2023/0625 , B29K2995/006 , B29L2007/008 , B29L2031/7129 , B65D65/466 , B65D85/70 , C08J5/18 , C08J2303/08 , C08J2323/06 , C08J2403/08 , C08J2423/06 , C08L3/02 , C08L2207/066 , C08L23/08 , C08L51/06
Abstract: Described herein are strength characteristics and biodegradation of articles produced using one or more petrochemical-based polymers and one or more carbohydrate-based polymers. A compatibilizer can optionally be included in the article. In some cases, the article can include a film or bag.
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公开(公告)号:US20170002185A1
公开(公告)日:2017-01-05
申请号:US14853780
申请日:2015-09-14
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan
CPC classification number: B29C48/865 , B29C48/022 , B29C48/10 , B29C48/18 , B29C48/185 , B29C48/21 , B29C48/832 , B29C48/875 , B29K2023/04 , B29K2995/006 , B29L2007/008 , B29L2031/7128 , B32B9/02 , B32B9/04 , C08J5/18 , C08J2323/08 , C08J2403/02 , C08L3/02 , C08L23/0815 , C08L3/00 , C08L51/06
Abstract: Described herein are strength characteristics and biodegradation of articles produced using one or more petrochemical-based polymers and one or more carbohydrate-based polymers. A compatibilizer can optionally be included in the article. In some cases, the article can include a film or bag.
Abstract translation: 这里描述的是使用一种或多种石油化学基聚合物和一种或多种基于碳水化合物的聚合物制备的制品的强度特性和生物降解。 增容剂可以任选地包括在制品中。 在某些情况下,文章可以包括一个电影或一个袋子。
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公开(公告)号:US20240150559A1
公开(公告)日:2024-05-09
申请号:US18492611
申请日:2023-10-23
Applicant: BiologiQ, Inc.
Inventor: Kanth V. Josyula , Wenji Quan , Fehime Vatansever Ozaltun , Kurtis R. Clark , David J. Fairbanks , Leopoldo V. Cancio , Kenneth L. Kramer
IPC: C08L3/02 , C08K5/06 , C08K5/092 , C08K5/1545
CPC classification number: C08L3/02 , C08K5/06 , C08K5/092 , C08K5/1545
Abstract: Thermoplastic starch-based materials formed as a reactive extrusion product from one or more starches, plasticizers, with the addition of a diacid, diglycidyl ether, silicone and/or a glyceride additive added during gelatinization of the starch and plasticizer, before blending of such starch-based polymeric material with any other polymer (e.g., polyester biopolymers, polyolefins, polyamides, etc.). Silicones, where added, may alternatively be added after formation of the thermoplastic starch, e.g., as part of a masterbatch, when blending with another polymer. Addition of silicone reduces glycerin migration and smoke generation, particularly when processing such compositions to form nonwovens. Addition of glycerides (e.g., triglycerides) can increase hydrophobicity of the resulting starch-based polymeric material. Addition of the diacid can reduce molecular weight, while diglycidyl ether addition can build such molecular weight back up, resulting in a narrower molecular weight distribution, and improved processability of the resulting starch-based polymeric material, particularly for nonwoven applications.
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7.
公开(公告)号:US11359088B2
公开(公告)日:2022-06-14
申请号:US16925952
申请日:2020-07-10
Applicant: BiologiQ, Inc.
Inventor: Donald R. Allen , Wenji Quan , Bradford LaPray
Abstract: Composite blends of PBAT (or another similar polyester) with PLA and a carbohydrate-based polymeric material. While PLA is not compostable under home composting conditions (e.g., temperature of 28° C.) on its own, when blended in the manner described herein, it is compositable under such conditions. The addition of the PLA increases the rigidity of the composite blend, as PBAT on its own is so flexible as to be problematic for use in carryout bags, and the like. An exemplary blend may include 30-55% by weight of the carbohydrate-based polymeric material, up to 20%, or up to 15% by weight of PLA, with the balance of polymeric content being PBAT (e.g., 30-60% PBAT). Other components (e.g., an inorganic filler, such as calcium carbonate) may also be included in the blend.
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公开(公告)号:US11111363B2
公开(公告)日:2021-09-07
申请号:US15836555
申请日:2017-12-08
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
Abstract: Described herein are strength characteristics and biodegradation of articles produced using one or more “green” sustainable polymers and one or more carbohydrate-based polymers. A compatibilizer can optionally be included in the article. In some cases, the article can include a film, a bag, a bottle, a cap or lid therefore, a sheet, a box or other container, a plate, a cup, utensils, or the like.
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公开(公告)号:US11840623B2
公开(公告)日:2023-12-12
申请号:US17358619
申请日:2021-06-25
Applicant: BIOLOGIQ, INC.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
CPC classification number: C08L23/06 , C08L3/02 , C08L83/04 , C08L2201/06 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2207/066 , C08L3/02 , C08L23/08 , C08L51/06
Abstract: Described herein are methods for rendering biodegradable a plastic material that is not itself biodegradable, by blending the plastic material with a carbohydrate-based polymeric material that is formed from one or more starches, and a plasticizer (e.g., glycerin). The carbohydrate-based polymeric material is less crystalline than the starting starch materials, e.g., being substantially amorphous, and having a crystallinity of no more than 20%. Third party testing shows blends of such materials render the entire blend biodegradable, believed to be due to the low crystalline substantially amorphous carbohydrate-based polymeric material breaking the hygroscopic barrier associated with the non-biodegradable plastic material, so that when blended together, both the plastic material and the carbohydrate-based polymeric material are biodegradable.
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公开(公告)号:US20210363335A1
公开(公告)日:2021-11-25
申请号:US17393110
申请日:2021-08-03
Applicant: BiologiQ, Inc.
Inventor: Bradford LaPray , Wenji Quan , Donald R. Allen
Abstract: Described herein are strength characteristics and biodegradation of articles produced using one or more “green” sustainable polymers and one or more carbohydrate-based polymers. A compatibilizer can optionally be included in the article. In some cases, the article can include a film, a bag, a bottle, a cap or lid therefore, a sheet, a box or other container, a plate, a cup, utensils, or the like.
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