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公开(公告)号：US4789564A
公开(公告)日：1988-12-06
申请号：US32377
申请日：1987-03-31
IPC分类号： C04B41/49 , C04B41/84 , C07F7/02 , C07F7/10 , C09K3/18 , D06M15/643 , D21H17/13 , D21H21/16 , D21H23/44 , B05D3/02 , C23C16/00
CPC分类号： C04B41/84 , C04B41/4944 , C09K3/18 , D06M15/6436 , D21H17/13 , D21H21/16 , D21H23/44
摘要： Surfaces containing hydroxyl groups are rendered water-repellent through exposure to hydridoaminosilanes of the general formulaH.sub.x Si(NRH).sub.y (NR.sub.2.sup.1).sub.3-yIn particular, tris(dimethylamino)silane and its derivatives have been found to make substrates with hydroxyl-containing surfaces hydrophobic without adversely effecting the physical properties of the substrate being treated and without the necessity of and pre- or post-treatment steps (i.e. moisturizing, neutralizing, etc.).
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公开(公告)号：US4675424A
公开(公告)日：1987-06-23
申请号：US841545
申请日：1986-03-19
IPC分类号： C04B35/589 , C07F7/10 , C08G77/48 , C08G77/62
CPC分类号： C08G77/62 , C04B35/589 , C07F7/10
摘要： A method of preparing silazane polymers, with 3 or more repeating units, of the general formula--((CH.sub.3).sub.2 N).sub.e Si(R).sub.a (R'HN).sub.f H.sub.c (NR').sub.g --and a (CH.sub.3).sub.2 NH byproduct group where R is hydrogen, an alkyl group having 1-6 carbon atoms or an aryl group having 6-12 carbon atoms, a=0, or 1, b=2-4, C=0-2, d=0 or 1, e=0-2, f=0-2, g=1-3 and a+c+e+f+g=4 for the polymer units; and R' is hydrogen or methyl, whereby the silazane polymer is substantially free of halide impurities, and wherein this method comprises:transaminating an aminosilane of the general formula (R).sub.a ((CH.sub.3).sub.2 N).sub.b H.sub.c S; where R is defined as above and a+b+c=4 with an amine of the general formula (CH.sub.3).sub.d NH.sub.3-d whereby d is defined as above and the amine has a molecular weight lower than 45 all in the presence of an acid catalyst or the ammonium salt of the acid and thereafter condensing to form the polymer.
摘要翻译： 制备具有3个以上重复单元的具有通式 - （（CH 3）2 N）e Si（R）a（R'HN）fHc（NR'）g - 和（CH 3）2 NH副产物基团）的硅氮烷聚合物的方法 其中R是氢，具有1-6个碳原子的烷基或具有6-12个碳原子的芳基，a = 0或1，b = 2-4，C = 0-2，d = 0或1， 对于聚合物单元，e = 0-2，f = 0-2，g = 1-3和a + c + e + f + g = 4; 并且R'是氢或甲基，由此硅氮烷聚合物基本上不含卤化物杂质，并且其中该方法包括：将通式（R）a（（CH 3）2 N）b H c S的氨基硅烷转氨酸; 其中R如上所定义，a + b + c = 4与通式（CH3）dNH3-d的胺反应，其中d如上定义，胺在酸存在下全部分子量低于45 催化剂或酸的铵盐，然后冷凝形成聚合物。
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公开(公告)号：US4400526A
公开(公告)日：1983-08-23
申请号：US430373
申请日：1982-09-30
CPC分类号： C07F7/1896 , C07F7/025
摘要： A hydrogen bearing silyl carbamate of the general formula:HSiR.sub.n (O.sub.2 CNR'R").sub.3-nis synthesized from hydrogen bearing aminosilane and gaseous carbon dioxide. The resulting hydrogen bearing silyl carbamate is novel in the single hydrogen attached to the silyl carbamate and represents a major new compound for creating novel compositions of matter.
摘要翻译： 由含氢氨基硅烷和气态二氧化碳合成具有通式：HSiRn（O 2 CNR'R“）3-n的含氢甲硅烷基氨基甲酸酯。 所产生的含氢甲硅烷基氨基甲酸酯在连接到甲硅烷基氨基甲酸酯的单氢中是新颖的，并且代表用于产生物质的新组合物的主要新化合物。
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公开(公告)号：US4395564A
公开(公告)日：1983-07-26
申请号：US397815
申请日：1982-07-13
申请人： Bernard Kanner , Steven P. Hopper
发明人： Bernard Kanner , Steven P. Hopper
摘要： A process whereby silanes of the general formula:HSi(NRR').sub.x (R").sub.3-xwherein R, R' and R" are independently an aliphatic or aromatic, substituted or unsubstituted, saturated or unsaturated hydrocarbon radical having from one to eight carbon atoms, inclusive and R and R' may also be hydrogen and where R" may also be alkoxy and where x has a value from one to three are reacted in the presence of a catalyst with alcohols in the stoichiometry of approximately one equivalent of alcohol per mole of silicon-nitrogen bond to give unexpectedly high yields of alkoxyhydridosilanes. In the reaction the silyl amine groups have been replaced by alkoxide groups without significant loss of the silicon-hydrogen group. Similar reactions in the absence of a catalyst give undesirably low yields of the corresponding alkoxy silanes and, in most cases, substantial loss of silyl hydrogen groups.
摘要翻译： 一种方法，其中通式为：HSi（NRR'）x（R“）3-x的硅烷，其中R，R'和R”独立地是脂族或芳族取代或未取代的饱和或不饱和烃基， 1至8个碳原子，包括R 1和R 2'，R和R'也可以是氢，并且其中R“也可以是烷氧基，并且其中x具有1至3的值在催化剂存在下与大约化学计量的醇反应 每摩尔硅 - 氮键相当于1当量醇，从而产生了意想不到的高产率的烷氧基硅烷。 在反应中，甲硅烷基胺基已被烷氧基组所取代，硅氢基团没有明显的损失。 在不存在催化剂的情况下，类似的反应给出了相应的烷氧基硅烷的不合需要的低产率，并且在大多数情况下甲硅烷基氢基团显着损失。
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公开(公告)号：US4496754A
公开(公告)日：1985-01-29
申请号：US454178
申请日：1982-12-28
CPC分类号： C07F7/045 , C07F7/1896
摘要： Silyl carbamates are produced by the reaction under suitable reaction conditions of silanes bearing at least one silicon-hydrogen bond of the formula: R.sub.4-x SiH.sub.x with an ammonium carbamate of the formula: R'R"NH.sub.2.sup..sym. R'R"NCO.sub.2.sup..crclbar.. This novel route is much simpler and more direct than those previously known and provides a new classes of silyl carbamates.
摘要翻译： 甲硅烷基氨基甲酸酯通过在具有下式的至少一个硅氢键的硅烷的合适反应条件下通过反应产生：具有下式的R 4 -XSiH x与下式的氨基甲酸铵：R'R''NH 2（+）R'R“ NCO 2（ - ）。 这种新颖的路线比先前已知的更简单和更直接，并且提供了一类新的甲硅烷基氨基甲酸酯。
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公开(公告)号：US4556725A
公开(公告)日：1985-12-03
申请号：US694307
申请日：1985-01-24
CPC分类号： C07F7/1896 , C07F7/025
摘要： Triacetoxysilanes are prepared by adding a tris(amino)silane to acetic anhydride and maintaining the reaction mix at a temperature no greater than about 50.degree. C.
摘要翻译： 通过向乙酸酐中加入三（氨基）硅烷并将反应混合物保持在不高于约50℃的温度下制备三乙酰氧基硅烷。
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7.发明授权Process for the preparation of oximatohydridosilanes and aminoxyhydridosilanes 失效制备肟基羟基硅烷和氨基羟基硅烷的方法
公开(公告)号：US4384131A
公开(公告)日：1983-05-17
申请号：US397814
申请日：1982-07-13
申请人： Bernard Kanner , Steven P. Hopper
发明人： Bernard Kanner , Steven P. Hopper
CPC分类号： C07F7/025
摘要： A process whereby silanes of the general formulaHSi(NRR.sup.I).sub.x (R.sup.II).sub.3-xare reacted in the presence of a catalyst with oximes or hydroxylamines in the stoichiometry of approximately one equivalent of oxime or hydroxylamine per mole of silicon-nitrogen linkage to give unexpectedly high yields of substituted silanes.
摘要翻译： 使通式为HSi（NRRI）x（RII）3-x的硅烷在催化剂存在下与肟或羟基胺反应的方法，其化学计量为每摩尔硅 - 氮键大约1当量肟或羟胺的化学计量， 取代硅烷出人意料地高产率。
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公开(公告)号：US4783516A
公开(公告)日：1988-11-08
申请号：US554291
申请日：1983-11-22
IPC分类号： C04B35/571 , C08G77/60 , C08G77/06
CPC分类号： C08G77/60 , C04B35/571
摘要： This invention is concerned with novel polysilanes containing olefinic groups which are prepared by reactions of halogen-containing organosilane monomers or mixtures thereof with sodium metal in an appropriate solvent or mixture of solvents. Such polysilane polymers are soluble and thermoplastic, and can be directly converted to silicon carbide compositions by pyrolysis at atmospheric pressure.
摘要翻译： 本发明涉及通过含卤素的有机硅烷单体或其混合物在合适的溶剂或溶剂混合物中与金属钠的反应制备的含有烯烃基团的新型聚硅烷。 这种聚硅烷聚合物是可溶的和热塑性的，并且可以通过在大气压下热解直接转化成碳化硅组合物。
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9.发明授权Method for preparing methacryloxy and acryloxy containing organosilanes and organosilicones 失效制备含甲基丙烯酰氧基和丙烯酰氧基的有机硅烷和有机硅氧烷的方法
公开(公告)号：US4709067A
公开(公告)日：1987-11-24
申请号：US865009
申请日：1986-05-20
申请人： Nan S. Chu , Bernard Kanner
发明人： Nan S. Chu , Bernard Kanner
CPC分类号： C08G77/38 , C07F7/1876
摘要： This invention relates to an improved process for preparing, purifying and/or storing methacryloxy or acryloxy containing organosilicon compounds without the undesirable polymerization normally associated with the methacrylate bonds. In an alternative embodiment, the process is even further improved with the addition of certain stabilizers, and in particular diketone or ketoester stabilizers.
摘要翻译： 本发明涉及一种改进的制备，纯化和/或储存含有甲基丙烯酰氧基或丙烯酰氧基的有机硅化合物的方法，而没有通常与甲基丙烯酸酯键相关的不期望的聚合。 在替代实施方案中，通过加入某些稳定剂，特别是二酮或酮酯稳定剂，该方法甚至进一步改善。
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公开(公告)号：US4668812A
公开(公告)日：1987-05-26
申请号：US815003
申请日：1985-12-31
申请人： Jennifer M. Quirk , Bernard Kanner
发明人： Jennifer M. Quirk , Bernard Kanner
IPC分类号： B01J23/00 , B01J23/46 , B01J31/00 , B01J31/20 , B01J31/24 , C07B61/00 , C07F7/08 , C07F7/10 , C07F7/18 , C08G77/22 , C08G77/32
CPC分类号： C07F7/10 , C07F7/0801 , C07F7/0881 , C07F7/1876
摘要： A novel synthesis for silanes and siloxanes containing olefinic bonds wherein an aminosilane, siloxane alkoxysilane or alkylalkoxysilane and an olefin undergo a dehydrocondensation in the presence of a rhodium or ruthenium catalyst.
摘要翻译： 含有烯键的硅烷和硅氧烷的新合成，其中氨基硅烷，硅氧烷烷氧基硅烷或烷基烷氧基硅烷和烯烃在铑或钌催化剂存在下进行脱氢。
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