Aqueous polyurethane resin dispersion, processes for its preparation,
and its use in aqueous coating compositions
    2.
    发明授权
    Aqueous polyurethane resin dispersion, processes for its preparation, and its use in aqueous coating compositions 失效
    水性聚氨酯树脂分散体,其制备方法及其在水性涂料组合物中的应用

    公开(公告)号:US5552496A

    公开(公告)日:1996-09-03

    申请号:US394553

    申请日:1995-02-27

    摘要: An aqueous coating composition which is self-drying or is crosslinked by external agents, processes and dispersions for its preparation and its use. The coating composition comprises:I) 40 to 100% by weight of a film-former in the form of an aqueous dispersion of one or more polyurethane resins having a number-average molecular mass (Mn) of from 2500 to 1,000,000 and a content of ionic groups, groups which can be converted to ionic groups, and/or hydrophilic groups of from 5 to 200 meq per 100 g of solid resin, and at least one CH-acid group per molecule and a OH-number of 0 to 100, wherein some or all of the Ch-acid groups can be reacted with one ore more compounds which are able to react with at least two CH-acid groups for chain-lengthening, andII) 60 to 0% by weight of one or more crosslinkers based on compounds which can react with at least two CH-acidic groups, based on formaldehyde condensation resins and/or polyisocyanates containing free or blocked isocyanate groups,the percentages by weight of I) and II) relating to the resin solids content and adding up to 100% by weight, and optionally pigments, fillers, organic solvents and/or conventional coating additives.

    摘要翻译: 一种水性涂料组合物,其自干燥或通过外用剂,其制备方法和分散体及其用途进行交联。 涂料组合物包括:I)40-100重量%的数均分子量(Mn)为2500至1,000,000的一种或多种聚氨酯树脂的水分散体形式的成膜剂,其含量为 离子基团,可以转化为离子基团的基团和/或每100克固体树脂为5至200meq的亲水基团,每分子至少一个CH酸基团和0-100个OH-基团, 其中一些或全部的Ch酸基团可以与一个或多个能够与至少两个CH-酸基团反应以进行链延长的化合物反应,和II)60至0重量%的一种或多种交联剂 基于可以与至少两个CH-酸性基团反应的化合物,基于甲醛缩合树脂和/或含有游离或封闭的异氰酸酯基团的多异氰酸酯,I)和II)的重量百分比与树脂固体含量相关并加起来 至100重量%,以及任选的颜料,填料,有机溶剂 和/或常规涂料添加剂。

    Aqueous coating media and their use in single-layer and multi-layer
coating processes
    3.
    发明授权
    Aqueous coating media and their use in single-layer and multi-layer coating processes 失效
    水性涂​​料介质及其在单层和多层涂层工艺中的应用

    公开(公告)号:US5886085A

    公开(公告)日:1999-03-23

    申请号:US849310

    申请日:1997-06-10

    摘要: Coating media and their use in processes for producing single-layer and multi-layer coatings are described. The coating media contain an aqueous mixture comprisingI. 99-70% by weight of a mixture ofA) 50-100% by weight of one or more binder vehicles which at least in part contain ionic groups,B) 0-50% by weight of one or more crosslinking agents, which at least in part may contain ionic groups, for binder vehicle A), wherein the ionic groups which are present have the same charge as those of component A), andII. 1-30% by weight of one or more binder vehicles (component C), which are miscible both with the binder vehicles of component A) at the storage temperature and with each other at the curing temperature of the coating media and which contain ionic groups, the charge of which is opposite to the charge of the ionic groups of component I), wherein the percentages by weight are given with respect to the weight of resin solids in each case and wherein the proportions of components I) and II) are matched to each other so that 0.5 to 70% of the number of charges of the ionic groups of I) are neutralised by the charges of the ionic groups of II), andIII. customary lacquer additives and/or pigments and/or extenders, and optionally one or more customary lacquer solvents.

    摘要翻译: PCT No.PCT / EP95 / 04967 Sec。 371日期:1997年6月10日 102(e)日期1997年6月10日PCT 1995年12月15日PCT PCT。 WO96 / 18693 PCT出版物 日期1996年6月20日涂料介质及其在生产单层和多层涂料工艺中的应用。 涂层介质包含含有99-70%(重量)A至50-100%重量的一种或多种粘合剂载体的混合物的水性混合物,其至少部分含有离子基团,B)0-50% 一种或多种至少部分可以含有离子基团的交联剂对于粘合剂载体A)的重量,其中存在的离子基团具有与组分A)和II相同的电荷。 1-30重量%的一种或多种粘合剂载体(组分C),它们可与组分A的粘合剂载体混合)在储存温度下并且在涂布介质的固化温度下彼此混合并且含有离子基团 ,其电荷与组分I)的离子基团的电荷相反,其中以每种情况下相对于树脂固体的重量给出重量百分比,并且其中组分I)和II)的比例匹配 使得I)的离子性基团的电荷数的0.5〜70%被II)和III的离子性基团的电荷中和。 常规的漆添加剂和/或颜料和/或增量剂,以及任选的一种或多种常规的漆溶剂。

    Process for producing decorative multiple-layer coatings
    4.
    发明授权
    Process for producing decorative multiple-layer coatings 失效
    生产装饰性多层涂料的方法

    公开(公告)号:US5681622A

    公开(公告)日:1997-10-28

    申请号:US564343

    申请日:1996-02-13

    摘要: A process and a coating medium for producing a decorative multilayer coating on a substrate, wherein a base lacquer coat is applied and is overpainted with a transparent lacquer coat, wherein an aqueous, self-crosslinking base lacquer is used, which contains, as a binder vehicle, an aqueous polyurethane resin dispersion based on a polyurethane resin having a number average molecular weight (Mn) of 2500 to 120,000, a content of 10 to 400 mmole of lateral and/or terminal hydroxyl and/or R'O groups bonded to silicon, where R'=a C.sub.1 to C.sub.8 alkyl or C(O)R''', and R'''=a C.sub.1 to C.sub.10 alkyl, per 100 g solid resin, a hydroxyl number of 0 to 150, wherein hydroxyl groups bonded to silicon are not included in the calculation of the OH number, and a content of ionic groups, groups convertible into ionic groups and/or hydrophilic groups of 5 to 200 mEqu per 100 g solid resin.

    摘要翻译: PCT No.PCT / EP95 / 01410 Sec。 371日期1996年2月13日 102(e)日期1996年2月13日PCT提交1995年4月14日PCT公布。 公开号WO95 / 28428 日期1995年10月26日一种用于在基材上生产装饰性多层涂层的方法和涂布介质,其中施加基漆漆并用透明漆涂层涂覆,其中使用水性自交联基漆,其中 含有作为粘合剂载体的基于数均分子量(Mn)为2500〜120,000的聚氨酯树脂的水性聚氨酯树脂分散体,含有10〜400mmole的侧面和/或末端羟基和/或R' O基团,其中R'= C 1至C 8烷基或C(O)R“',并且R”'= C 1至C 10烷基,每100克固体树脂,羟基数为0至150,其中 结合硅的羟基不包括在OH数的计算中,离子基团的基团,可转换成离子基团和/或亲水基团的基团为每100克固体树脂为5至200mEqu。

    Method for producing multilayer coatings
    7.
    发明授权
    Method for producing multilayer coatings 失效
    生产多层涂料的方法

    公开(公告)号:US5721018A

    公开(公告)日:1998-02-24

    申请号:US639874

    申请日:1996-04-26

    摘要: A process for preparing a multi-layer coating on an electrically nonconductive surface of a substrate, which comprises (A) applying over the surface an aqueous dispersion having a pH of from 5 to 8 when not containing a metallic pigment, the dispersion containing of from 15% to 20% wt. based on the dispersion of a base coat resin without metallic pigments then having a nonvolatile content of from about 30% to about 50% wt. based on the base coat resin of (i) from 75% to 98% wt. based on base coat resin solids of one or more partially or completely acid neutralized cationic, polyurethane, and polyurethane-urea resins, having a OH number of up to 450, and an amine number of from 20 to 200, and (ii) from 2% to 25% wt. based on base coat resin solids of one or more of an amine-formaldehyde condensation resin alone or in admixture with a blocked polyiisocyanate in either case having at least two groups per molecule being reactive with one or more of amino, OH.sup.-, urethane, and urea groups in (i), the aqueous dispersion further containing one or more of a pigment, a filler, and a lacquer additive, and up to 15% wt. based on the dispersion of an organic solvent for said resin, the ratio of pigment and filler to the resin solids being 0.05-1.2:1, and (B) then applying a clear anionic lacquer coat in a solution in water or in an organic solvent of a clear lacquer powder, said base coat and said clear lacquer coat being cured together at a temperature below 160.degree. C.

    摘要翻译: 一种在基材的非导电表面上制备多层涂层的方法,其包括(A)当不含金属颜料时,在表面上涂覆pH为5至8的水分散体,所述分散体含有 15%至20%重量 基于没有金属颜料的底涂层树脂的分散体,然后具有约30%至约50%wt的不挥发物含量。 基于(i)75%至98%wt的底涂层树脂。 基于一种或多种部分或完全酸中和的阳离子,聚氨酯和聚氨酯 - 脲树脂的底漆树脂固体,OH值高达450,胺数为20至200,和(ii)2 %至25%wt 基于一种或多种胺 - 甲醛缩合树脂中的一种或多种胺 - 甲醛缩合树脂的底漆树脂固体,或与封闭的多异氰酸酯混合,在每种分子中具有至少两个基团的氨基,OH-,氨基甲酸酯和/ (i)中的尿素基团,水分散体还含有颜料,填料和漆添加剂中的一种或多种,​​和至多15重量% 基于用于所述树脂的有机溶剂的分散,颜料和填料与树脂固体的比例为0.05-1.2:1,和(B)然后在水或有机溶剂中的溶液中施加透明阴离子漆涂层 的清漆漆,所述底漆和所述透明漆层在低于160℃的温度下一起固化。

    Method for multi-layered coating of substrates
    9.
    发明授权
    Method for multi-layered coating of substrates 失效
    多层基材涂层方法

    公开(公告)号:US06534130B1

    公开(公告)日:2003-03-18

    申请号:US09555176

    申请日:2000-08-21

    IPC分类号: C08F246

    摘要: A process for the preparation of a multi-layer coating wherein a colour- and/or special effect-imparting base lacquer coating compound is applied to a substrate optionally precoated with a primer and/or primer surfacer coating compound and/or further coating compounds and a clear lacquer layer is then applied to the colour- and/or special effect-imparting base lacquer layer, wherein the colour- and/or special effect-imparting base lacquer coating compound used is one which contains binders which can be cured by free-radical and/or cationic polymerisation under the action of high-energy radiation.

    摘要翻译: 一种制备多层涂层的方法,其中将着色和/或特殊效果的基漆涂料化合物施用于任选地用底漆和/或底漆二嵌段涂料化合物预涂的基材和/或其它涂料化合物和 然后将清漆层施加到着色和/或特殊效果赋予基漆层,其中所用的着色和/或特殊效果的基漆涂料化合物是含有可以通过游离 - 在高能辐射的作用下进行自由基和/或阳离子聚合。

    Method for coating motor vehicle bodies or parts thereof
    10.
    发明授权
    Method for coating motor vehicle bodies or parts thereof 失效
    机动车身或其部件的涂敷方法

    公开(公告)号:US06506458B1

    公开(公告)日:2003-01-14

    申请号:US09700651

    申请日:2001-04-06

    IPC分类号: C08F246

    CPC分类号: B05D3/0263 B05D7/53

    摘要: Method of lacquering a substrate by applying a clear-lacquer coating compound to a precoated substrate or a one-coat top lacquer coating compound to an optionally precoated substrate, followed by curing, the substrate being a motor-vehicle body or parts thereof, in which the substrate is subjected, after the application of the clear-lacquer coating compound or one-coat top lacquer coating compound, optionally to a drying phase and the curing is then performed by irradiation with NIR radiation having the wavelength from 760 to 1500 nm.

    摘要翻译: 通过向预涂底物或单涂层顶漆涂料施涂透漆涂料化合物至任选的预涂底物,然后固化,所述底物是机动车体或其部分,其中涂布基材的方法,其中 在使用透明漆涂层化合物或单涂层顶漆涂料化合物之后,任选地进行干燥阶段,然后通过用波长为760至1500nm的NIR辐射进行照射来进行固化。