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    Production of olefin oligomer lubricants
    3.
    发明授权
    Production of olefin oligomer lubricants 失效
    生产烯烃低聚物润滑剂

    公开(公告)号：US5105051A

    公开(公告)日：1992-04-14

    申请号：US693254

    申请日：1991-04-29

    申请人： Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

    发明人： Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

    IPC分类号： B01J29/04 ,  B01J39/10 ,  C07C2/12 ,  C08F10/14 ,  C10M107/02 ,  C10M143/00

    CPC分类号： C10M143/00 ,  B01J29/04 ,  B01J39/10 ,  C07C2/12 ,  C08F10/14 ,  C10M107/02 ,  C07C2523/26 ,  C07C2529/78 ,  C10M2205/00 ,  C10M2205/028 ,  C10N2220/02

    摘要： A process for oligomerizing alpha olefins to produce hydrocarbon oligomers useful as lubricants and lubricant additives uses a catalyst comprising a supported reduced group VIB metal, preferably chromium, in the form of its oxide. The support is a mesoporous, inorganic, crystalline solid of unique structure, of novel pore geometry. The preferred forms of these mesoporous materials are characterized by substantially uniform hexagonal honeycomb microstructure, with uniform pores having a cell diameter greater than 13 .ANG., preferably in the mesoporous range of about 20-100 .ANG.. The use of the catalysts made with the mesoporous support materials enables products of greater viscosity to be made as compared to the products from catalysts using amorphous supports. The catalyst is usually used under oligomerization conditions at a temperature of about 90.degree. to 250.degree. C. to produce liquid hydrocarbon oligomers in the lubricant range which have a branch ratio of less than 0.19 and high values of viscosity index.

    摘要翻译： 用于使α-烯烃低聚以制备用作润滑剂和润滑剂添加剂的烃低聚物的方法使用包含其氧化物形式的负载的还原族VIB金属，优选铬的催化剂。 该支持体是具有独特结构，孔隙几何形状的介孔，无机，结晶固体。 这些介孔材料的优选形式的特征在于基本上均匀的六边形蜂窝微结构，具有孔直径大于13的均匀孔，优选在约20-100的介孔范围内。 与使用无定形载体的催化剂的产物相比，使用由介孔载体材料制成的催化剂能够制备更大粘度的产物。 催化剂通常在低温条件下在约90℃至250℃的温度下使用，以在润滑剂范围内产生分支比小于0.19且粘度指数高的液态烃低聚物。

    Olefin oligomerization catalyst
    4.
    发明授权
    Olefin oligomerization catalyst 失效
    烯烃低聚催化剂

    公开(公告)号：US5270273A

    公开(公告)日：1993-12-14

    申请号：US1133

    申请日：1993-01-06

    申请人： Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

    发明人： Bruce P. Pelrine ,  Kirk D. Schmitt ,  James C. Vartuli

    IPC分类号： B01J29/04 ,  B01J39/10 ,  C07C2/12 ,  C08F10/14 ,  C10M107/02 ,  C10M143/00 ,  B01J29/36

    CPC分类号： C10M143/00 ,  B01J29/04 ,  B01J39/10 ,  C07C2/12 ,  C08F10/14 ,  C10M107/02 ,  C07C2523/26 ,  C07C2529/78 ,  C10M2205/00 ,  C10M2205/028 ,  C10N2220/02

    摘要： A catalyst for oligomerizing alpha olefins to produce hydrocarbon oligomers useful as lubricants and lubricant additives comprises a supported reduced Group VIB metal, preferably chromium, in the form of its oxide. The support is a mesoporous, inorganic, crystalline solid of unique structure, of novel pore geometry. The preferred forms of these mesoporous materials are characterized by substantially uniform hexagonal honeycomb microstructure, with uniform pores having a cell diameter greater than 13 .ANG., preferably in the mesoporous range of about 20-100 .ANG.. The use of the catalysts made with the mesoporous support materials enables products of greater viscosity to be made as compared to the products from catalysts using amorphous supports. The catalyst is usually used under oligomerization conditions at a temperature of about 90.degree. to 250.degree. C. to produce liquid hydrocarbon oligomers in the lubricant range which have a branch ratio of less than 0.19 and high values of viscosity index.

    摘要翻译： 用于低聚α-烯烃以制备用作润滑剂和润滑剂添加剂的烃低聚物的催化剂包括其氧化物形式的负载的还原的VIB族金属，优选为铬。 该支持体是具有独特结构，孔隙几何形状的介孔，无机，结晶固体。 这些介孔材料的优选形式的特征在于基本上均匀的六边形蜂窝微结构，具有孔直径大于13的均匀孔，优选地在约20-100的介孔范围内。 与使用无定形载体的催化剂的产物相比，使用由介孔载体材料制成的催化剂能够制备更大粘度的产物。 催化剂通常在低温条件下在约90℃至250℃的温度下使用，以在润滑剂范围内产生分支比小于0.19且粘度指数高的液态烃低聚物。