公开(公告)号：US3362955A

公开(公告)日：1968-01-09

申请号：US52205366

申请日：1966-01-21

Applicant: CHEMIE LINZ AG

Inventor： FERDINAND WEINROTTER ,  WALTER MULLER ,  ALFRED SCHMIDT ,  WALTER BOHLER

IPC: C07D20060101

CPC classification number: C07D251/56

公开(公告)号：US3310559A

公开(公告)日：1967-03-21

申请号：US35506464

申请日：1964-03-26

Applicant: CHEMIE LINZ AG

Inventor： FERDINAND WEINROTTER ,  WALTER MULLER ,  ALFRED SCHMIDT ,  JOHANN SCHWEIGHOFER

IPC: C07D251/56

CPC classification number: C07D251/56

公开(公告)号：US3388533A

公开(公告)日：1968-06-18

申请号：US42471665

申请日：1965-01-11

Applicant: CHEMIE LINZ AG

Inventor： FERDINAND WEINROTTER ,  WALTER MULLER ,  ALFRED SCHMIDT ,  JOHANN SCHWEIGHOFER ,  WILFRIED KRULLA

IPC: A61K31/70 ,  B01D47/10 ,  B01J10/02 ,  B01J19/18 ,  B01J19/24 ,  C01C3/00 ,  C01C3/20

CPC classification number: C01C3/20 ,  A61K31/70 ,  B01D47/10 ,  B01J10/02 ,  B01J19/18 ,  B01J19/2435 ,  B01J2219/00159 ,  B01J2219/185 ,  C01C3/001

公开(公告)号：US3386892A

公开(公告)日：1968-06-04

申请号：US55944966

申请日：1966-06-22

Applicant: CHEMIE LINZ AG

Inventor： ALFRED SCHMIDT ,  WALTER MULLER ,  FERDINAND WEINROTTER

IPC: B41M5/48 ,  C01B33/10 ,  C07D471/04 ,  G03C1/49 ,  G03C1/52 ,  G03C1/64 ,  G03C1/705 ,  G03C5/56 ,  G03G5/153 ,  G03G9/09

CPC classification number: B41M5/48 ,  C01B33/103 ,  C07D471/04 ,  G03C1/49 ,  G03C1/52 ,  G03C1/64 ,  G03C1/705 ,  G03C5/56 ,  G03G5/153 ,  G03G9/0926 ,  Y10S159/19 ,  Y10S514/874

公开(公告)号：US3324168A

公开(公告)日：1967-06-06

申请号：US52883066

申请日：1966-02-21

Applicant: CHEMIE LINZ AG

Inventor： WALTER MULLER ,  FERDINAND WEINROTTER

IPC: C07C51/275 ,  C07C203/04

CPC classification number: C07C203/04 ,  C07C201/02

Abstract: The invention comprises nitrates of the formula wherein R1 is C4- 12 straight chain alkyl and X is hydrogen or straight-chain alkyl group and a more general method of preparation of compounds of the formula where R is a straight chain alkyl group of at least 3 carbon atoms comprising introducing a mixture of one or more straight chain a -olefins, having at least 5 carbon atoms, and molecular oxygen into liquid dinitrogen tetroxide at - 10 DEG to +40 DEG C., removing excess nitrous fumes at a temperature not exceeding 60 DEG C. and, if desired, esterifying the carboxyl group in a known manner. The oxygen and dinitrogen tetraoxide are used in at least equimolar amounts, based on olefin. The reaction may be effected in the presence of an oxidation catalyst, e.g. SeO2 or V2O5. The starting olefin may be used in the form of a commercial mixture containing saturated hydrocarbons which act as a diluent. The excess nitrous fumes are conveniently removed from the product using a thin film evaporator. Examples relate to the nitrate esters of methyl-a -hydroxyvalerate, methyl - a - hydroxyoenanthate, a -hydroxycaprylic acid, a -hydroxycapric acid, a -hydroxylauric acid, a -hydroxymyristic acid, a -hydroxypelargonic acid, a -hydroxystearic acid, a -hydroxyarachidic acid and a -hydroxy-nonadecane carboxylic acid.