公开(公告)号：US10053363B2

公开(公告)日：2018-08-21

申请号：US15124725

申请日：2015-03-06

Applicant: CHIYODA CORPORATION

Inventor： Tomoyuki Mikuriya ,  Kenichi Imagawa ,  Hironori Kawai ,  Yusuke Nakajima ,  Takenori Kanda

IPC: C01B3/26 ,  C01B3/22 ,  B01J7/00

CPC classification number: C01B3/26 ,  B01J7/00 ,  B01J8/0453 ,  B01J8/0457 ,  B01J8/0488 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/067 ,  B01J2208/00176 ,  B01J2208/00256 ,  B01J2208/025 ,  B01J2208/065 ,  C01B3/22 ,  C01B2203/0277 ,  C01B2203/0833 ,  C01B2203/1047 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1252 ,  C01B2203/142 ,  C01B2203/16 ,  C01B2203/1623

Abstract: To allow hydrogen to be supplied to a dehydrogenation reaction unit for dehydrogenating an organic hydride by using a highly simple structure so that the activity of the dehydrogenation catalyst of the dehydrogenation reaction unit is prevented from being rapidly reduced. The hydrogen production system (1) comprises a first dehydrogenation reaction unit (3) for producing hydrogen by a dehydrogenation reaction of an organic hydride in presence of a first catalyst, and a second dehydrogenation reaction unit (4) for receiving a product of the first dehydrogenation reaction unit, and producing hydrogen by a dehydrogenation reaction of the organic hydride remaining in the product in presence of a second catalyst, wherein an amount of the first catalyst used in the first dehydrogenation reaction unit is equal to or less than an amount of the second catalyst used in the second dehydrogenation reaction unit, and an amount of hydrogen produced in the first dehydrogenation reaction unit is less than an amount of hydrogen produced in the second dehydrogenation reaction unit.

公开(公告)号：US09919986B2

公开(公告)日：2018-03-20

申请号：US15116007

申请日：2015-01-29

Applicant: CHIYODA CORPORATION

Inventor： Kenichi Imagawa ,  Hironori Kawai ,  Masato Shiraga ,  Yusuke Nakajima

IPC: C07C5/10 ,  C01B3/26 ,  C01B3/00

CPC classification number: C07C5/10 ,  C01B3/0015 ,  C01B3/26 ,  C01B2203/0277 ,  C07C5/367 ,  C07C2101/12 ,  C07C2521/04 ,  C07C2521/12 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2601/12 ,  C07C2601/14 ,  Y02E60/328 ,  Y02P20/52 ,  C07C13/18 ,  C07C15/06

Abstract: The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system (2) for an aromatic compound comprises a hydrogenation reaction unit (11) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit (12) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit (13) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.

公开(公告)号：US20170166496A1

公开(公告)日：2017-06-15

申请号：US15116007

申请日：2015-01-29

Applicant: CHIYODA CORPORATION

Inventor： Kenichi Imagawa ,  Hironori Kawai ,  Masato Shiraga ,  Yusuke Nakajima

IPC: C07C5/10 ,  C01B3/26 ,  C01B3/00

CPC classification number: C07C5/10 ,  C01B3/0015 ,  C01B3/26 ,  C01B2203/0277 ,  C07C5/367 ,  C07C2101/12 ,  C07C2521/04 ,  C07C2521/12 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2601/12 ,  C07C2601/14 ,  Y02E60/328 ,  Y02P20/52 ,  C07C13/18 ,  C07C15/06

Abstract: The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system (2) for an aromatic compound comprises a hydrogenation reaction unit (11) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit (12) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit (13) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.

公开(公告)号：US10472235B2

公开(公告)日：2019-11-12

申请号：US15558246

申请日：2016-03-23

Applicant: CHIYODA CORPORATION ,  Japan Oil, Gas and Metals National Corporation

Inventor： Shigeru Kado ,  Kohei Urasaki ,  Kyoji Ishikawa ,  Hironori Kawai ,  Yusuke Nakajima

IPC: C01B3/26 ,  B01J23/63 ,  B01J35/04 ,  C01B32/40 ,  B01J12/00 ,  B01J19/24 ,  C07C9/04 ,  B01J37/08 ,  B01J23/56 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J8/02 ,  B01J8/04 ,  C01B3/38 ,  B01J35/00 ,  B01J23/46 ,  B01J32/00

Abstract: A method of manufacturing synthesis gas by catalytic partial oxidation can prevent formation of hot spots from taking place when driving mixture gas to pass through a catalyst-filled layer at high velocity. The method comprises converting mixture gas of source gas containing lower hydrocarbons and oxidative gas containing oxygen into synthesis gas containing hydrogen and carbon monoxide as main components thereof by causing mixture gas to flow through a fixed bed catalyst layer arranged in a reactor. The method of manufacturing synthesis gas by catalytic partial oxidation is conducted such that the mixture gas is made to flow to the catalyst layer under the condition that the Reynolds number does not exceed 20 at the inlet of the catalyst layer.

公开(公告)号：US20180093886A1

公开(公告)日：2018-04-05

申请号：US15558246

申请日：2016-03-23

Applicant: CHIYODA CORPORATION ,  Japan Oil, Gas and Metals National Corporation

Inventor： Shigeru Kado ,  Kohei Urasaki ,  Kyoji Ishikawa ,  Hironori Kawai ,  Yusuke Nakajima

IPC: C01B3/26 ,  C01B32/40 ,  C07C9/04 ,  B01J12/00 ,  B01J19/24

CPC classification number: C01B3/26 ,  B01J8/0207 ,  B01J8/0242 ,  B01J8/0411 ,  B01J12/00 ,  B01J12/007 ,  B01J19/244 ,  B01J19/248 ,  B01J19/2485 ,  B01J19/249 ,  B01J19/2495 ,  B01J23/464 ,  B01J23/56 ,  B01J23/63 ,  B01J32/00 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/082 ,  B01J37/088 ,  B01J2208/00672 ,  B01J2208/024 ,  B01J2208/025 ,  B01J2219/00263 ,  B01J2523/00 ,  C01B3/386 ,  C01B32/40 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1064 ,  C07C9/04 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/822

Abstract: A method of manufacturing synthesis gas by catalytic partial oxidation can prevent formation of hot spots from taking place when driving mixture gas to pass through a catalyst-filled layer at high velocity. The method comprises converting mixture gas of source gas containing lower hydrocarbons and oxidative gas containing oxygen into synthesis gas containing hydrogen and carbon monoxide as main components thereof by causing mixture gas to flow through a fixed bed catalyst layer arranged in a reactor. The method of manufacturing synthesis gas by catalytic partial oxidation is conducted such that the mixture gas is made to flow to the catalyst layer under the condition that the Reynolds number does not exceed 20 at the inlet of the catalyst layer.