摘要:
The invention relates to a composite component that has improved bonding properties and includes a substrate (i) made of a thermoplastic polymer blend composition, and a coating (ii); in a layer located 5 to 10 μm below the boundary surface between the substrate (i) and the coating (ii), the substrate (i) has a dispersed, non-lamellar phase structure. The invention also relates to a method for manufacturing the composite component.
摘要:
The invention relates to a compounding method for producing impact-modified polycarbonate compositions using components acting as an alkali or using alkaline constituent-containing components. By using the method according to the invention, the harmful influence of the components acting as an alkali on the properties of polycarbonate molding compositions or the surface of molded bodies produced therefrom is counteracted. The method has the steps (i), (ii), and optionally (iii), wherein (i) in a first step A) 10 to 98 wt. % of at least one polymer selected from the group of aromatic polycarbonates and aromatic polyester carbonates, B) 0.001 to 0.3 wt. % of at least one organic Brønsted acid, i.e. a carbon and hydrogen-containing Brønsted acid, C) 0.0001 to 0.008 wt. % of at least one inorganic Brønsted acidic phosphorus compound, i.e. a Brønsted acidic phosphorus compound which does not contain carbon, D) 1 to 90 wt. % of at least one rubber-containing vinyl(co)polymerisate, E) 0 to 90 wt. % of at least one polyester, and F) 0 to 30 wt. % of at least one additive, the ratio of the weight percentages of the components B to C used in method step (i) ranging from 2 to 100, are heated by supplying thermal and/or mechanical energy, whereby at least the components A) and D) are melted and all of the components used are mixed together, dissolved into one another, or dispersed into one another, and in an additional step (ii), the melt (ii) resulting from method step (i) is resolidified by cooling and (iii) optionally granulated. The method steps (ii) and (iii) can be carried out in any order. The invention also relates to compositions produced according to the method, to the use thereof for producing molded bodies, to the molded bodies themselves, and to the use of the mixtures of B and C for stabilizing impact-modified polycarbonate compositions.
摘要:
Compositions and composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components.
摘要:
The present invention relates to dimensionally stable compositions comprising A) 50 to 70 parts by weight of at least one aromatic polycarbonate, B) 16 to 30 parts by weight of at least one polyalkylene terephthalate, C) 4 to 30 parts by weight of at least one mineral filler based on talc, D) 0.1-8.0 parts by weight of additives, with component D comprising at least one mould release agent and at least one stabilizer and with the sum of the parts by weight of components A-D making 100. The present invention further relates to the use of the thermoplastic moulding compounds for producing dimensionally stable preforms and mouldings, and also to the preforms and mouldings obtainable from the thermoplastic moulding compounds. The preforms and mouldings find preferred application in motor vehicle construction, more preferably as exterior components.
摘要:
The invention relates to a composition for production of a thermoplastic moulding compound, wherein the composition comprises or consists of the following constituents: A) 30% to 90% by weight of at least one polymer selected from the group consisting of aromatic polycarbonate, aromatic polyester carbonate and aromatic polyester, B) 5% to 65% by weight of rubber-modified vinyl (co)polymer prepared by the bulk polymerization method which is free of epoxy groups, C) 0.5% to 10% by weight of a block or graph polymer containing structural elements deriving from styrene and at least one epoxy-containing vinyl monomer, D) 0% to 20% by weight of one or more further additives, wherein component C has a weight ratio of structural elements deriving from styrene to those deriving from epoxy-containing vinyl monomer of 100:1 to 1:1, and to a process for producing a moulding compound from the composition, to the use of the composition or the moulding compound for production of mouldings, and to the mouldings themselves.
摘要:
The invention relates to compositions containing A) at least one polymer selected from the group of aromatic polycarbonates and aromatic polyester carbonates and B) at least one Brønsted-acidic compound selected from the group consisting of compounds of general formulae (I) and (II) (R1)y1-N—[R2-COOH]x1 (I) [HOOC—R2]x2(R1)y2N—(R3)-N(R1)y3[R2-COOH]x3 (II) wherein R1 represents optionally functionalized or heteroatom-substituted alkyl, aryl or cycloalkyl, R2 represents C1- to C8-alkylene or C2- to C8-alkylidene, R3 represents —(CH2)n—, —(CH2)n[O(CH2)n]m— or —(CH2)n[NR4(CH2)n]m—, n is an integer, m is an integer, R4 represents optionally functionalized or heteroatom-substituted alkyl, aryl or cycloalkyl, x1 is an integer between 1 and 3, x2 and x3 are respectively 1 or 2, and y1 is given by the formula y1=3−x1, y2 by the formula y2=2−x2, y3 by the formula y3=2−x3, and wherein in compounds having a plurality of radicals R1 and/or R2 these may independently of one another represent different or identical radicals having the abovementioned definitions, and also to a process for producing compositions using components A, B and optionally further components, wherein at least one of the employed components is alkaline or contains alkaline constituents, to compositions obtained by this process and to the use of the compositions for producing molded articles and to the molded articles themselves.
摘要:
Compositions comprising A) at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate, B) at least one polyester, wherein the polyester is derived from succinic acid and optionally further dicarboxylic acids and aliphatic, cycloaliphatic, araliphatic diols or aromatic diols, C) at least one cyclic phosphazene of structure (IV) wherein R is in each case identical or different and represents an amine radical, in each case optionally halogenated C1- to C8-alkyl, C1- to C8-alkoxy in each case optionally alkyl- and/or halogen-substituted C5- to C6-cycloalkyl, in each case optionally alkyl- and/or halogen- and/or hydroxyl-substituted C6- to C20-aryloxy, in each case optionally alkyl- and/or halogen- and/or bromine-substituted C7- to C12-aralkyl, a halogen radical or an OH radical, k is a whole number from 1 to 10 D) optionally graft polymer, E) optionally vinyl (co)polymer and/or polyalkylene terephthalate, F) optionally additives and also the use of these flame-retarded polycarbonate/polyester compositions for producing molded articles and the molded articles themselves, wherein the polyester in the composition can be obtained or prepared preferably from renewable raw materials.
摘要:
The present invention relates to compositions and composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components.
摘要:
The present invention relates to compositions and composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components.