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公开(公告)号：US4068720A
公开(公告)日：1978-01-17
申请号：US643985
申请日：1975-12-24
CPC分类号： E21B43/24 , C09K8/76 , C09K8/90 , Y10S507/903
摘要： Gelled acidic compositions suitable for either matrix acidizing or fracture-acidizing of subterranean formations, and methods of using said compositions in acidizing operations, are provided. Said compositions comprise water, a water-soluble cellulose ether, an acid, a water soluble compound of a polyvalent metal wherein the metal can be reduced to a lower polyvalent valence state and cause gelation of the water containing said cellulose ether and said acid, and a reducing agent capable of reducing said metal and causing said gelation.
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公开(公告)号：US4169797A
公开(公告)日：1979-10-02
申请号：US846060
申请日：1977-10-27
CPC分类号： E21B43/24 , C09K8/74 , C09K8/76 , Y10S507/903 , Y10S507/923 , Y10S507/933
摘要： Gelled acidic compositions suitable for either matrix-acidizing or fracture-acidizing of subterranean formations, and methods of using said compositions in acidizing operation, are provided. Said compositions comprise water, a water-soluble cellulose ether, an acid, a water-soluble compound of a polyvalent metal wherein the metal can be reduced to a lower polyvalent valence state and cause gelation of the water containing said cellulose ether and said acid, and a reducing agent capable of reducing said metal and causing said gelation.
摘要翻译： 提供适用于地下地层的基质酸化或断裂酸化的凝胶状酸性组合物，以及在酸化操作中使用所述组合物的方法。 所述组合物包含水，水溶性纤维素醚，酸，多价金属的水溶性化合物，其中金属可以还原成较低的多价态并引起含有所述纤维素醚和所述酸的水的凝胶化， 以及能够还原所述金属并导致所述凝胶化的还原剂。
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公开(公告)号：US4068714A
公开(公告)日：1978-01-17
申请号：US643986
申请日：1975-12-24
申请人： James E. Hessert , Brent J. Bertus
发明人： James E. Hessert , Brent J. Bertus
CPC分类号： C09K8/905 , C09K8/76 , Y10S507/903 , Y10S507/923 , Y10S507/933
摘要： Gelled acidic compositions suitable for either matrix acidizing or fracture-acidizing of subterranean formations, and methods of using said compositions in acidizing operations, are provided. Said compositions comprise water, a water-dispersible biopolysaccharide, an acid, a water soluble compound of a polyvalent metal wherein the metal can be reduced to a lower polyvalent valence state and cause gelation of the water containing said biopolysaccharide and said acid, and a reducing agent capable of reducing said metal and causing said gelation.
摘要翻译： 提供了适用于地下地层的基质酸化或断裂酸化的凝胶状酸性组合物，以及在酸化操作中使用所述组合物的方法。 所述组合物包含水，水分散性生物多糖，酸，多价金属的水溶性化合物，其中所述金属可以还原成较低的多价态并引起含有所述生物多糖和所述酸的水的凝胶化， 能够还原所述金属并导致所述凝胶化的还原剂。
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公开(公告)号：US4146486A
公开(公告)日：1979-03-27
申请号：US846063
申请日：1977-10-27
申请人： James E. Hessert , Brent J. Bertus
发明人： James E. Hessert , Brent J. Bertus
CPC分类号： C09K8/905 , C09K8/76 , Y10S507/903 , Y10S507/923 , Y10S507/933
摘要： Gelled acidic compositions suitable for either matrix-acidizing or fracture-acidizing of subterranean formations, and methods of using said compositions in acidizing operations, are provided. Said compositions comprise water, a water-dispersible biopolysaccharide, an acid, a water-soluble compound of a polyvalent metal wherein the metal can be reduced to a lower polyvalent valence state and cause gelation of the water containing said biopolysaccharide and said acid, and a reducing agent capable of reducing said metal and causing said gelation.
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公开(公告)号：US5024750A
公开(公告)日：1991-06-18
申请号：US457411
申请日：1989-12-26
CPC分类号： C10G69/04 , C10G67/0463
摘要： Heavy hydrocarbon oil, containing asphaltene, sulfur and metal contaminants, is hydrotreated in the presence of a hydrotreating catalyst having a small pore diameter in an initial process step to remove sulfur and metal contaminants. Removal of additional metal and sulfur contaminants is then accomplished in a second process step by solvent deasphalting, wherein the size of the pore diameter of the hydrotreating catalyst utilized in the initial hydrotreating step affects the metals rejection in the subsequent solvent deasphalting step. In a third process step the deasphalted oil is catalytically cracked substantially in the absence of added hydrogen to provide lower boiling hydrocarbon products.
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公开(公告)号：US4775461A
公开(公告)日：1988-10-04
申请号：US146524
申请日：1988-01-21
CPC分类号： C10G11/05 , B01J29/049 , B01J29/06 , B01J29/084 , C10G11/04 , B01J2229/36 , B01J2229/42
摘要： A process for catalytic cracking using a catalyst obtained by preparing pillared interlayered clay materials comprises the steps of contacting a smectite containing material, preferably bentonite, with a solution comprising at least one of ammonium and alkali metal carboxylates and alkali metal carbonates and bicarbonates, plus preferably also alkali metal dithionite; separating the thus-contacted material from the solution; treating the separated material with a solution comprising a polymeric cationic hydroxy metal complex, preferably of aluminum (more preferably, polymeric hydroxy aluminum chloride); separating and finally heating the thus-treated smectite material. The pillared interlayered clay material of this invention can be intimately admixed with zeolite. The pillared interlayered clay material of this invention, with or without zeolite, can be used as catalyst for cracking hydrocarbon-containing oils.
摘要翻译： 使用通过制备柱状夹层粘土材料获得的催化剂进行催化裂化的方法包括以下步骤：将含绿土的材料，优选膨润土与包含铵和碱金属羧酸盐和碱金属碳酸盐和碳酸氢盐中的至少一种的溶液接触， 碱金属连二亚硫酸盐; 将如此接触的材料与溶液分离; 用包含聚合物阳离子羟基金属络合物，优选铝（更优选聚合羟基氯化铝）的溶液处理分离的材料; 分离并最终加热如此处理的蒙皂石材料。 本发明的柱状夹层粘土材料可与沸石紧密混合。 具有或不具有沸石的本发明的柱状层间粘土材料可用作裂解含烃油的催化剂。
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公开(公告)号：US4728629A
公开(公告)日：1988-03-01
申请号：US26233
申请日：1987-03-16
申请人： Brent J. Bertus , H. Wayne Mark , Dwight L. McKay
发明人： Brent J. Bertus , H. Wayne Mark , Dwight L. McKay
CPC分类号： C10G11/04 , B01J29/06 , B01J29/90 , B01J2229/34 , B01J2229/40
摘要： A composition comprising a cracking catalyst having had deposited thereon an aluminum containing treating agent.
摘要翻译： 一种组合物，其包含在其上沉积有铝的处理剂的裂化催化剂。
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公开(公告)号：US4719191A
公开(公告)日：1988-01-12
申请号：US908276
申请日：1986-09-17
CPC分类号： B01J29/049 , C10G11/05
摘要： Pillared interlayered clay products of increased stability and processes for preparing such clay products are provided. The pillared interlayered clays are prepared by reacting a smectite clay, such as montmorillonite, with an aqueous solution of a polymeric cationic hydroxy metal complex, such as aluminum chlorhydroxide and reacting the resulting product with a stability increasing compound selected from the group consisting of silicon, titanium, phosphorus and antimony halides and ethyl silicates.
摘要翻译： 提供了增加稳定性的柱状粘土粘土产品和制备这种粘土产品的方法。 柱状夹层粘土是通过将蒙脱石蒙皂石与聚合阳离子羟基金属络合物如氢氧化铝的水溶液反应制备的，并使所得产物与稳定性增加的化合物反应，所述化合物选自硅， 钛，磷和锑卤化物和硅酸乙酯。
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9.发明授权Hydrodemetallization of oils with catalysts comprising nickel phosphate and titanium phosphate 失效用包含磷酸镍和磷酸钛的催化剂对油进行加氢离子化
公开(公告)号：US4680105A
公开(公告)日：1987-07-14
申请号：US859980
申请日：1986-05-05
IPC分类号： B01J23/755 , B01J27/185 , C10G45/06 , C10G45/00
CPC分类号： B01J27/1853 , B01J23/755 , C10G45/06 , Y10S502/521
摘要： A new composition of matter comprises nickel phosphate and titanium phosphate, preferably prepared by coprecipitation. A process for removing metals from a hydrocarbon-containing feed stream, in particular a heavy oil, comprises hydrotreatment in the presence of a solid catalyst composition comprising nickel phosphate and titanium phosphate (preferably coprecipitated).
摘要翻译： 新的物质组合物包括磷酸镍和磷酸钛，优选通过共沉淀制备。 从含烃进料流，特别是重油中除去金属的方法包括在包含磷酸镍和磷酸钛（优选共沉淀）的固体催化剂组合物的存在下进行加氢处理。
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公开(公告)号：US4562167A
公开(公告)日：1985-12-31
申请号：US597880
申请日：1984-04-09
申请人： Brent J. Bertus , Dwight L. McKay
发明人： Brent J. Bertus , Dwight L. McKay
IPC分类号： B01J21/20 , B01J23/644 , B01J29/90 , C10G11/04 , B01J33/00
CPC分类号： B01J29/90 , B01J21/20 , B01J23/6445 , C10G11/04 , Y10S502/521
摘要： A novel cracking catalyst, a method of preparing same and an improved hydrocarbon cracking process are provided wherein adverse effects of metals such as nickel, vanadium, iron, copper and cobalt in the cracking catalyst are precluded or mitigated by contacting the cracking catalyst with (A) at least one of elemental antimony and compounds thereof and (B) at least one of element tin and compounds thereof whereby there is added to said catalyst a modifying amount of each of (A) and (B) with the weight ratio of antimony to tin being such as to provide passivation of the contaminating metals greater than the sum of the passivation effects of each of (A) and (B) individually. In general the ratio will be in the range of from 0.001:1 to 1000:1, and preferably will be in the range of 0.05:1 to 50:1.
摘要翻译： 提供了一种新的裂化催化剂，其制备方法和改进的烃裂解方法，其中裂化催化剂中的镍，钒，铁，铜和钴等金属的不利影响通过使裂化催化剂与（A ）元素锑及其化合物中的至少一种和（B）元素锡及其化合物中的至少一种，由此向所述催化剂中加入（A）和（B）各自的改性量，其中锑与 例如，提供污染金属的钝化比单独的（A）和（B）中的每一个的钝化效应的总和大。 通常该比例在0.001:1-1000:1的范围内，优选在0.05:1至50:1的范围内。
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