摘要:
Novel biodegradable polymers consisting of a biodegradable core bound to at least two carboxylic polyacid-based branches via a bond capable of being broken by hydrolysis or by oxidation are described. Biodegradable detergent compositions containing such polymers are also described.
摘要:
A hydrophilic polymer with improved biodegradability and particular usefulness in detergent compositions contains units derived by polymerization from at least one monomers A bearing a carboxylic acid function or an equivalent function, units derived by polymerization from at least one monomers B bearing an electron-rich group or a function capable of introducing an electron-rich group into the main chain, and, optionally, units derived by polymerization from at least one monomers C which is copolymerizable with A and B, but is different from A and B. Examples of suitable monomers as monomers A include maleic anhydride, acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid, and the salts thereof. Examples of suitable monomers as monomers B include butadiene, isoprene, chloroprene, dimethylbutadiene, cyclohexadiene, butadienecarboxylic acid, butadienedicarboxylic acid, acetylene, acetylenecarboxylic acid and acetylenedicarboxylic acid. Suitable monomers as monomers C include vinyl, acrylic and styrene monomers and derivatives thereof.
摘要:
A hydrophilic polymer with improved biodegradability and particular usefulness in detergent compositions contains units derived by polymerization from at least one monomers A bearing a carboxylic acid function or an equivalent function, units derived by polymerization from at least one monomers B bearing an electron-rich group or a function capable of introducing an electron-rich group into the main chain, and, optionally, units derived by polymerization from at least one monomers C which is copolymerizable with A and B, but is different from A and B. Examples of suitable monomers as monomers A include maleic anhydride, acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid, and the salts thereof. Examples of suitable monomers as monomers B include butadiene, isoprene, chloroprene, dimethylbutadiene, cyclohexadiene, butadienecarboxylic acid, butadienedicarboxylic acid, acetylene, acetylenecarboxylic acid and acetylenedicarboxylic acid. Suitable monomers as monomers C include vinyl, acrylic and styrene monomers and derivatives thereof.
摘要:
Process for the preparation of tert-dodecyl mercaptan by reaction of hydrogen sulfide with tri(n-butene) in the presence of a catalyst. tert-Dodecyl mercaptan thus prepared and its use as chain-transfer agent in radical (co)polymerization reactions.
摘要:
The present invention relates to core-shell polymers having a hydrophilic copolymer shell, and a high level of core material of from 75 to 95 weight percent. The hydrophilic shell provides better coverage of the core resulting in better powder properties such as anti-blocking. The hydrophilic shell also allows for a thinner shell and a larger elastomeric core. Core-shell polymers of the invention are especially useful as impact modifiers for plastic materials.
摘要:
Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
摘要:
A radical polymerization process for the in which a tert-dodecyl mercaptan prepared by reaction of hydrogen sulfide with tri(n-butene) in the presence of a catalyst as chain-transfer agent.
摘要:
The invention relates to a process allowing the preparation of a (dialkylphosphono)alkyl (meth)acrylate, corresponding to the formula: by reaction of an alkyl (meth)acrylate A of formula: with a dialkylphosphonated alcohol B of formula: in the presence of a catalyst comprising zirconium acetylacetonate.
摘要:
Process for improving the dispersibility and the filterability of scleroglucan powders, in which a surfactant is incorporated in the coagulated polymer. The powder obtained according to the process has a dispersibility and a filterability after drying of the coagulum which are greatly superior to those of a powder treated after drying with the same quantity of surfactant or of a powder in solution treated with this same quantity of surfactant.
摘要:
The invention relates to an impact modified thermoplastic resin comprising a polymeric impact modifier with a core-shell structure comprising 2-octylacrylate.