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    Telechelic olefin metathesis polymers from renewable feedstocks
    4.
    发明授权
    Telechelic olefin metathesis polymers from renewable feedstocks 有权
    来自可再生原料的远视烯烃易位聚合物

    公开(公告)号：US08324334B2

    公开(公告)日：2012-12-04

    申请号：US13060058

    申请日：2009-08-21

    申请人： Simon C. Jones ,  Farshad J. Motamedi ,  Li-Sheng Wang ,  Brian Edgecombe ,  Michael A. Giardello

    发明人： Simon C. Jones ,  Farshad J. Motamedi ,  Li-Sheng Wang ,  Brian Edgecombe ,  Michael A. Giardello

    IPC分类号： C08G61/08 ,  C08F4/80

    CPC分类号： C08G61/08 ,  C08G2261/3322 ,  C08G2261/418

    摘要： Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.

    摘要翻译： 公开了烯烃易位聚合反应，更具体地说，环烯烃与烯烃化合物如来自种子油等的开环易位聚合反应形成遥爪聚合物。 在一个方面，提供了一种用于进行催化开环易位聚合反应的方法，包括在钌亚烷基烯烃复分解催化剂存在下使至少一种烯烃化合物与至少一种环烯烃接触，所述条件有效地允许环 开环环烯烃的易位聚合，由此所形成的环烯烃聚合物用烯烃化合物终止。 本发明可用于催化，有机合成，聚合物化学和工业化学领域。

    ADHESION PROMOTERS AND GEL-MODIFIERS FOR OLEFIN METATHESIS COMPOSITIONS
    7.
    发明申请
    ADHESION PROMOTERS AND GEL-MODIFIERS FOR OLEFIN METATHESIS COMPOSITIONS 审中-公开
    粘合剂组合物的粘合促进剂和凝胶改性剂

    公开(公告)号：US20140329017A1

    公开(公告)日：2014-11-06

    申请号：US14125837

    申请日：2012-06-17

    申请人： Li-Sheng Wang ,  Anthony R. Stephen ,  Paul W. Booth ,  Tessa Schulze ,  Michael A. Giardello ,  Mark S. Trimmer ,  Christopher J. Cruce ,  Farshad J. Motamedi ,  Brian Edgecombe

    发明人： Li-Sheng Wang ,  Anthony R. Stephen ,  Paul W. Booth ,  Tessa Schulze ,  Michael A. Giardello ,  Mark S. Trimmer ,  Christopher J. Cruce ,  Farshad J. Motamedi ,  Brian Edgecombe

    IPC分类号： C03C25/30

    CPC分类号： C03C25/30 ,  C08F32/02 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K5/0025 ,  C08K5/14 ,  C08K5/29 ,  C08K2201/014 ,  C08L65/00

    摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

    摘要翻译： 本发明涉及用于改善树脂组合物与基材的粘合性，预处理基材以改善树脂组合物与基材的粘合性和/或控制树脂组合物凝胶形成的组合物和方法。 更具体地，本发明涉及使用在树脂组合物中含有异质基团的粘合促进剂来改善开环易位聚合（ROMP）组合物与基材的粘合性的组合物和方法。 本发明还涉及通过用含有异氰酸酯基团的粘合促进剂预处理底物材料来改善树脂组合物对基材的粘附性的方法。 本发明还涉及一种提供凝胶改性的ROMP组合物的方法，其中将氢过氧化物加入到ROMP可聚合树脂组合物中以控制聚合树脂的凝胶形成。 进一步公开了改进的ROMP组合物，其包含环烯烃，ROMP复分解催化剂，粘合促进剂和加入的氢过氧化物凝胶改性剂。 通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

    Telechelic Olefin Metathesis Polymers from Renewable Feedstocks
    8.
    发明申请
    Telechelic Olefin Metathesis Polymers from Renewable Feedstocks 有权
    来自可再生原料的非线性烯烃复分解聚合物

    公开(公告)号：US20110294971A1

    公开(公告)日：2011-12-01

    申请号：US13060058

    申请日：2009-08-21

    申请人： Simon C. Jones ,  Farshad J. Motamedi ,  Li-Sheng Wang ,  Brian Edgecombe ,  Michael A. Giardello

    发明人： Simon C. Jones ,  Farshad J. Motamedi ,  Li-Sheng Wang ,  Brian Edgecombe ,  Michael A. Giardello

    IPC分类号： C08F216/04 ,  C08F232/06 ,  C08F232/04 ,  C08F4/80 ,  C08F222/20 ,  C08F220/68 ,  C08F216/10

    CPC分类号： C08G61/08 ,  C08G2261/3322 ,  C08G2261/418

    摘要： Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.

    摘要翻译： 公开了烯烃易位聚合反应，更具体地说，环烯烃与烯烃化合物如来自种子油等的开环易位聚合反应形成遥爪聚合物。 在一个方面，提供了一种用于进行催化开环易位聚合反应的方法，包括在钌亚烷基烯烃复分解催化剂存在下使至少一种烯烃化合物与至少一种环烯烃接触，所述条件有效地允许环 开环环烯烃的易位聚合，由此所形成的环烯烃聚合物用烯烃化合物终止。 本发明可用于催化，有机合成，聚合物化学和工业化学领域。

    Clays pre-activated with intercalated polymerization initiation sites
    10.
    发明申请
    Clays pre-activated with intercalated polymerization initiation sites 审中-公开
    粘土通过嵌入的聚合引发位点预活化

    公开(公告)号：US20060211803A1

    公开(公告)日：2006-09-21

    申请号：US11081334

    申请日：2005-03-16

    申请人： Nicholas Rodak ,  Brian Edgecombe ,  Noah Macy

    发明人： Nicholas Rodak ,  Brian Edgecombe ,  Noah Macy

    IPC分类号： C08K9/04

    CPC分类号： C08K9/04 ,  C01B33/44 ,  C01P2002/22 ,  C01P2002/72 ,  C01P2002/86 ,  C01P2002/88

    摘要： A modified clay may be made by contacting a clay with an unsaturated cationic compound and an alkoxyamine, or an adduct thereof. The resulting pre-activated clay, which contains a cationic alkoxyamine bound to the clay, may be further treated with a monomer to provide a polymer that is bound to the clay, thereby forming a nanocomposite material. The nanocomposite material may in turn be blended with another polymer prepared from the same or a different monomer.

    摘要翻译： 改性粘土可以通过使粘土与不饱和阳离子化合物和烷氧基胺或其加合物接触来制备。 所得到的预活化粘土含有与粘土结合的阳离子烷氧基胺，可进一步用单体处理，以提供与粘土结合的聚合物，由此形成纳米复合材料。 纳米复合材料又可以与由相同或不同单体制备的另一种聚合物共混。