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    Tire rubber composition comprising a coupling agent having a polythiosulfenamide function
    2.
    发明申请
    Tire rubber composition comprising a coupling agent having a polythiosulfenamide function 有权
    轮胎橡胶组合物，其包含具有聚亚硫酰胺功能的偶联剂

    公开(公告)号：US20050032949A1

    公开(公告)日：2005-02-10

    申请号：US10870999

    申请日：2004-06-21

    申请人： Carlos Araujo Da Silva ,  Christiane Blanchard ,  Gerard Mignani ,  Salvatore Pagano ,  Jean-Claude Tardivat

    发明人： Carlos Araujo Da Silva ,  Christiane Blanchard ,  Gerard Mignani ,  Salvatore Pagano ,  Jean-Claude Tardivat

    IPC分类号： B60C1/00 ,  B60C15/06 ,  C08J3/20 ,  C08K3/00 ,  C08K5/548 ,  C08L21/00 ,  C08K3/34 ,  C08K5/24

    CPC分类号： B60C15/06 ,  B60C1/00 ,  B60C1/0008 ,  B60C1/0016 ,  B60C1/0025 ,  C08K5/548 ,  C08L21/00

    摘要： An elastomeric composition usable for the manufacture of tires, based on at least (i) a diene elastomer, (ii) an inorganic filler as reinforcing filler and (iii), as (inorganic filler/diene elastomer) coupling agent, a organosilicon compound which is at least bifunctional and can be grafted on to the elastomer by means of a sulfur group having a polythiosulfenamide function, of formula: ≡Si-A-Sx—NR1R2,  (I) in which: A is a divalent bond group, whether straight-chain or branched, which makes it possible to join the polythiosulfenamide group to a silicon atom of the organosilicon compound; x is an integer or fractional number of from 2 to 4; R1 represents hydrogen or a monovalent hydrocarbon group; R2 represents a monovalent hydrocarbon group selected from among C3-C8 alkyls, whether straight-chain or branched, C5-C10 cycloalkyls, C6-C18 aryls and (C6-C18)aryl-(C1-C8)alkyls; R1 and R2 possibly forming together and with the nitrogen atom to which they are bonded a single hydrocarbon ring. Tires and tire treads comprising a composition of this type.

    摘要翻译： 可用于制造轮胎的弹性体组合物，至少基于（i）二烯弹性体，（ii）作为增强填料的无机填料和（iii）作为（无机填料/二烯弹性体）偶联剂的有机硅化合物， 至少是双官能的，并且可以通过具有式：Si-A-Sx-NR 1 R 2，（I）的具有聚亚硫酰胺官能团的硫基接枝到弹性体上，其中：A是 无论是直链还是支链的二价键基团，这使得可以将多亚硫酰胺基团连接到有机硅化合物的硅原子; x是2到4的整数或小数; R 1表示氢或一价烃基; R 2表示选自C 3 -C 8烷基，无论是直链还是支链，C5-C10环烷基，C6-C18芳基和（C6-C18）芳基 - （C1-C8）烷基的一价烃基; R 1和R 2可以一起形成，并与它们所键合的氮原子形成单个烃环。 包括这种类型的组合物的轮胎和轮胎胎面。

    Process for preparing functionalized polyorganosiloxane resins by redistribution in the presence of triflic acid and/or of at least one derivative thereof and of a nonbasic inert filler
    4.
    发明申请
    Process for preparing functionalized polyorganosiloxane resins by redistribution in the presence of triflic acid and/or of at least one derivative thereof and of a nonbasic inert filler 审中-公开
    在三氟酸和/或其至少一种衍生物和非碱性惰性填料的存在下再分配制备官能化聚有机硅氧烷树脂的方法

    公开(公告)号：US20080255292A1

    公开(公告)日：2008-10-16

    申请号：US12142318

    申请日：2008-06-19

    申请人： Fernande Boisson ,  Lucile Gambut ,  Gerard Mignani

    发明人： Fernande Boisson ,  Lucile Gambut ,  Gerard Mignani

    IPC分类号： C08L83/06 ,  C08K3/34

    CPC分类号： C08G77/10 ,  C08G77/08

    摘要： The invention provides a method for preparing functionalized polyorganosiloxane resins (POS) comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), wherein in said units R is C1-C10 alkyl or C8-C12 aryl and Y is a functional group (such as Si—H), by redistributing POS resins, using POSf bearing functional groups M′ and/or D′ and/or in the presence of an acid catalyst such as triflic acid or one of its derivatives and a non-basic inert filler: carbon black, diatomaceous earth, zeolite or acid or neutral oxide (Al2O3, Na2O, TiO2, MgO, silica). The invention also provides said catalyst system.

    摘要翻译： 本发明提供了一种制备官能化聚有机硅氧烷树脂（POS）的方法，所述聚有机硅氧烷树脂（POS）包含单元M：（R 3 SiO 2 1/2），Q：（SiO 4/2 ）和M'：（Y a a R 3-a SiO 1/2）和任选的D：（R SUB 和/或D'：（RYSiO 2/2/2）和T：（RS 3 O 3/2/2） SUB）和/或T'：（YSiO 3/2/2），其中在所述单元中R是C 1 -C 10烷基或 C 8 -C 12芳基，Y是官能团（如Si-H），通过重新分配POS树脂，使用具有POS的官能团M'和/或D 和/或在酸催化剂如三氟甲烷或其衍生物之一和非碱性惰性填料：碳黑，硅藻土，沸石或酸或中性氧化物（Al 2 O 3）存在下， O 3，Na 2 O，TiO 2，MgO，二氧化硅）。 本发明还提供了所述催化剂体系。

    Method for preparing polyorganosiloxanes (pos) by polycondensation/redistribution of oligosiloxanes in the presence of a strong base and strong bases used
    5.
    发明申请
    Method for preparing polyorganosiloxanes (pos) by polycondensation/redistribution of oligosiloxanes in the presence of a strong base and strong bases used 审中-公开
    在强碱和强碱的存在下，通过缩聚/再分布低聚硅氧烷制备聚有机硅氧烷（pos）的方法

    公开(公告)号：US20050080215A1

    公开(公告)日：2005-04-14

    申请号：US10497756

    申请日：2002-12-13

    申请人： Antoire Baceiredo ,  Guy Bertrand ,  Alla Lemeune ,  Gerard Mignani

    发明人： Antoire Baceiredo ,  Guy Bertrand ,  Alla Lemeune ,  Gerard Mignani

    IPC分类号： C07F9/535 ,  C07F9/54 ,  C08G77/08 ,  C08G77/06

    CPC分类号： C07F9/5463 ,  C07F9/5352 ,  C07F9/54 ,  C08G77/08

    摘要： The invention concerns the synthesis of silicone by anionic polymerisation of cyclic organosiloxane oligomers in the presence of a slightly nucleophilic strong base. The invention aims at providing novel strong base catalysts, more efficient in terms of solubility in the silicones, with hydrolysis stability strength and polymerising capacity. To achieve this, the invention provides for the use of ylides derived from aminophosphonium such as for example that of formula: [Me3N)3P—CHMe2]+, MeO or derived from phosphoranylidenes such as that of formula: [Me3P—HC=Pme3]+, t-BuO. The invention also concerns strong base catalysts as novel products.

    摘要翻译： 本发明涉及通过在轻微亲核的强碱存在下通过环状有机硅氧烷低聚物的阴离子聚合来合成硅氧烷。 本发明旨在提供新的强碱催化剂，在硅氧烷中的溶解度方面更有效，具有水解稳定性强度和聚合能力。 为了实现这一点，本发明提供了使用衍生自氨基鏻的内鎓盐，例如式：[Me 3 N）3 P-CHMe 2] +，MeO或衍生自如下式的亚正膦的衍生物：[Me 3 P-HC = Pme 3] +，t-BuO。 本发明还涉及作为新产品的强碱催化剂。

    Organic material active in nonlinear optics
    9.
    发明授权
    Organic material active in nonlinear optics 失效
    非线性光学有机材料

    公开(公告)号：US5075409A

    公开(公告)日：1991-12-24

    申请号：US520202

    申请日：1990-05-03

    申请人： Pascal Barthelemy ,  Remi Meyrueix ,  Gerard Mignani

    发明人： Pascal Barthelemy ,  Remi Meyrueix ,  Gerard Mignani

    IPC分类号： G02F1/35 ,  C08G18/32 ,  C08G18/38 ,  C08G18/67 ,  C08G18/73 ,  C08G18/76 ,  C08G18/77 ,  C08G18/79 ,  G02F1/355 ,  G02F1/361

    CPC分类号： C08G18/7678 ,  C08G18/3836 ,  C08G18/3838 ,  C08G18/384 ,  C08G18/678 ,  C08G18/679 ,  C08G18/73 ,  C08G18/771 ,  C08G18/792 ,  G02F1/3617 ,  Y10T428/31551

    摘要： Marterials which are active in nonlinear optics, having a repeating unit of the following formula I: ##STR1## in which R.sub.1 and R.sub.2, are either identical or different, and denote a linear or branched methylenic chain, preferably containing from 2 to 6 carbon atoms; R.sub.3 is an aliphatic, aromatic or arylaliphatic hydrocarbon radical; R.sub.4 and R.sub.5, which are identical or different, denote a nitrogen atom or a CH radical, or alternatively R.sub.4 and R.sub.5 are both carbon with the R.sub.4 -R.sub.5 bond being a double or a triple bond; and Z.sub.1 and Z.sub.2, which are identical or different, denote an aromatic group wherein Z.sub.1 optionally contains one or more substituents R.sub.7 and wherein Z.sub.2 optionally contains one or more substituents R.sub.7 in addition to group A, each substituent R.sub.7 may be lower alkyl, halogen, amido, amino, sulfoxide, hydroxyl radical, alkoxy and trifluoromethyl; and A denotes an electron-acceptor group, with Z.sub.2 having one or more groups A.

    摘要翻译： 具有下列式I的重复单元的非线性光学活性物质：其中R 1和R 2相同或不同，并且表示直链或支链亚甲基链，优选含有2〜 6个碳原子; R3是脂族，芳族或芳基脂族烃基; R4和R5相同或不同，表示氮原子或CH基团，或者R4和R5都是碳，R4-R5键是双键或三键; 和Z 1和Z 2相同或不同，表示芳族基团，其中Z1任选地含有一个或多个取代基R 7，并且其中Z 2除了基团A任选含有一个或多个取代基R 7，每个取代基R 7可以是低级烷基，卤素， 酰氨基，氨基，亚砜，羟基，烷氧基和三氟甲基; 并且A表示电子受体基团，Z 2具有一个或多个基团A.

    Boron/nitrogen preceramic polymers and boron nitride ceramic materials produced therefrom
    10.
    发明授权
    Boron/nitrogen preceramic polymers and boron nitride ceramic materials produced therefrom 失效
    BORON / NITROGEN PRECERAMIC POLYMERS和BORON NITRIDE CERAMIC MATERIALS PRODUCER THEREFROM

    公开(公告)号：US5071935A

    公开(公告)日：1991-12-10

    申请号：US418193

    申请日：1989-10-06

    申请人： Pierre Ardaud ,  Gerard Mignani

    发明人： Pierre Ardaud ,  Gerard Mignani

    IPC分类号： C04B35/583 ,  C01B21/064 ,  C08G79/00 ,  C08G79/08 ,  D01F9/10

    CPC分类号： C08G79/08

    摘要： Organometallic boron/nitrogen polymers, precursors of boron nitride, include recurring structural units of the formulae (I) and (II): ##STR1## wherein X is N-R.sup.3, Y is NR.sup.1 R.sup.2 and Z is N-R, in which R, R.sup.1, R.sup.2 and R.sup.3, which may be identical or different, are each a hydrogen atom, an optionally substituted hydrocarbon radical, or an organosilyl or hydrogenoorganosilyl radical and are prepared by reacting (a) at least one cyclic compound (compound A) containing recurring structural units of the formula (1): ##STR2## wherein A is a halogen atom and R is a hydrogen atom, an optionally substituted hydrocarbon radical, or an organosilyl or hydrogenoorganosilyl radical, with (b) at least one compound including at least one boron atom to which two halogen atoms are directly bonded (compound B), and (c) at least one compound containing at least one NH.sub.2 group compound C); the resulting organometallic polymers are facilely pyrolyzed into boron nitride ceramic materials.

    摘要翻译： 有机金属硼/氮聚合物，氮化硼的前体包括式（I）和（II）的重复结构单元：其中X是N-R 3，Y是NR 1 R 2，和 Z是NR，其中R，R 1，R 2和R 3可以相同或不同，各自为氢原子，任选取代的烃基或有机甲硅烷基或氢有机甲硅烷基，并且通过使（a）至少一种 含有式（1）的重复结构单元的环状化合物（化合物A）：其中A是卤素原子，R是氢原子，任选取代的烃基或有机甲硅烷基或氢有机甲硅烷基，其中 （b）至少一种包含至少一个与两个卤原子直接键合的硼原子的化合物（化合物B），和（c）至少一种含有至少一个NH 2基团化合物C）的化合物; 所得到的有机金属聚合物易于热解成氮化硼陶瓷材料。