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公开(公告)号：US20120135210A1
公开(公告)日：2012-05-31
申请号：US13365313
申请日：2012-02-03
申请人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US08137801B2
公开(公告)日：2012-03-20
申请号：US12304505
申请日：2007-06-06
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US20100232021A1
公开(公告)日：2010-09-16
申请号：US12304505
申请日：2007-06-06
申请人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US08343624B2
公开(公告)日：2013-01-01
申请号：US13365313
申请日：2012-02-03
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US20070286994A1
公开(公告)日：2007-12-13
申请号：US11427055
申请日：2006-06-28
申请人： Christopher B. Walker , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one emboidiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施例中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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6.发明授权Perfluoropolyether urethane additives having (meth)acryl groups and hard coats 有权具有（甲基）丙烯酸基团和硬涂层的全氟聚醚氨基甲酸酯添加剂公开(公告)号：US08147966B2
公开(公告)日：2012-04-03
申请号：US12718481
申请日：2010-03-05
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
IPC分类号： B32B27/40
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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7.发明申请PERFLUOROPOLYETHER URETHANE ADDITIVES HAVING (METH)ACRYL GROUPS AND HARD COATS 有权具有（甲基）丙烯酸树脂组合物和硬质涂料的全氟聚醚添加剂公开(公告)号：US20100160595A1
公开(公告)日：2010-06-24
申请号：US12718481
申请日：2010-03-05
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, JR.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, JR.
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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8.发明申请PERFLUOROPOLYETHER URETHANE ADDITIVES HAVING (METH)ACRYL GROUPS AND HARD COATS 有权具有（甲基）丙烯酸树脂组合物和硬质涂料的全氟聚醚添加剂公开(公告)号：US20120142883A1
公开(公告)日：2012-06-07
申请号：US13396669
申请日：2012-02-15
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, JR.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, JR.
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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9.发明授权Perfluoropolyether urethane additives having (meth)acryl groups and hard coats 有权具有（甲基）丙烯酸基团和硬涂层的全氟聚醚氨基甲酸酯添加剂公开(公告)号：US07718264B2
公开(公告)日：2010-05-18
申请号：US11277162
申请日：2006-03-22
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
IPC分类号： B32B17/40
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
摘要翻译： 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。
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公开(公告)号：US08476398B2
公开(公告)日：2013-07-02
申请号：US13396669
申请日：2012-02-15
申请人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
发明人： Thomas P. Klun , Naiyong Jing , Richard J. Pokorny , Zai-Ming Qiu , Mark J. Pellerite , William D. Coggio , Christopher B. Walker, Jr.
CPC分类号： C07C235/08 , C08G18/3802 , C08G18/3825 , C08G18/672 , C08G18/673 , C08G18/792 , C08G18/8175 , C09D175/16 , G02B1/105 , G02B1/14 , Y10T428/265 , Y10T428/3154 , Y10T428/31551 , C08G18/50
摘要： Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.
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