Autodeposition post-bath rinse process
    5.
    发明授权
    Autodeposition post-bath rinse process 有权
    自动沉积后浴漂洗过程

    公开(公告)号:US06410092B1

    公开(公告)日:2002-06-25

    申请号:US09557534

    申请日:2000-04-25

    IPC分类号: B05D310

    CPC分类号: B05D7/144

    摘要: The anticorrosive properties of a coating autodeposited on a metal substrate are improved by contacting the autodeposited coating with an aqueous solution of an alkaline earth metal compound such as calcium nitrate prior to curing.

    摘要翻译: 在固化之前,通过使自动沉积的涂层与碱土金属化合物如硝酸钙的水溶液接触,改善了自动沉积在金属基底上的涂层的防腐蚀性能。

    Composition for the alkaline passivation of zinc surfaces
    6.
    发明授权
    Composition for the alkaline passivation of zinc surfaces 有权
    锌表面的碱性钝化的组成

    公开(公告)号:US09228088B2

    公开(公告)日:2016-01-05

    申请号:US13566155

    申请日:2012-08-03

    摘要: The present invention relates to an aqueous alkaline composition (A) for alkaline passivation of metallic components comprising at least in part surfaces of zinc or zinc alloys, containing iron(III) ions, phosphate ions, and one or more complexing agents, where a free alkalinity ranges from 1 to 6 points, and the pH is at least 11. The aqueous compositions (A) can additionally contain nonionic surfactants, so that such compositions are suitable for use in a method in which both cleaning and alkaline passivation of the metallic component occur in one step. The present invention further relates to a method for alkaline passivation of metallic components by contacting them with composition (A), and further a method for surface treatment in automobile body production, in which the alkaline passivation step using composition (A) is followed by an acid passivation step using a composition (B).

    摘要翻译: 本发明涉及用于金属组分的碱性钝化的碱性水溶液组合物(A),其包含至少部分含有铁(III)离子,磷酸根离子和一种或多种络合剂的锌或锌合金表面,其中, 碱度范围为1至6个点,pH值至少为11.水性组合物(A)可另外含有非离子表面活性剂,因此这些组合物适用于金属组分的清洁和碱性钝化两者的方法 发生在一个步骤。 本发明还涉及一种通过使其与组合物(A)接触来进行金属组分的碱钝化的方法,还涉及一种使用组合物(A)的碱性钝化步骤之后是一种用于汽车车身制造中的表面处理方法, 酸钝化步骤使用组合物(B)。

    MULTI-STAGE PRE-TREATMENT METHOD FOR METAL COMPONENTS HAVING ZINC AND IRON SURFACES
    8.
    发明申请
    MULTI-STAGE PRE-TREATMENT METHOD FOR METAL COMPONENTS HAVING ZINC AND IRON SURFACES 有权
    具有锌和铁表面的金属部件的多级预处理方法

    公开(公告)号:US20120325110A1

    公开(公告)日:2012-12-27

    申请号:US13484848

    申请日:2012-05-31

    IPC分类号: C09D5/08

    CPC分类号: C23C22/78 C23C22/34

    摘要: The invention relates to an acidic, aqueous, chromium-free composition (A) for the anti-corrosive treatment of steel and/or galvanized steel surfaces comprising metal ions (M) selected from ions at least of the elements nickel, cobalt, molybdenum, iron or tin and a multi-stage method applying the composition (A) for the anti-corrosive pre-treatment of metal components which have steel and/or galvanized steel surfaces. The invention further relates to metal surfaces of zinc or iron having a passive layer system comprising at least 30 mg/m2 nickel and at least 10 mg/m2 zircon, titanium and/or hafnium and sulfur, wherein nickel is present in metallic form at up to at least 30 At. %, obtainable in a method according to the invention.

    摘要翻译: 本发明涉及一种用于钢和/或镀锌钢表面的防腐蚀处理的酸性含水无铬组合物(A),其包括选自至少元素镍,钴,钼, 铁或锡以及将组合物(A)应用于具有钢和/或镀锌钢表面的金属组分的防腐蚀预处理的多阶段方法。 本发明还涉及锌或铁的金属表面,其具有包含至少30mg / m2镍和至少10mg / m2锆石,钛和/或铪和硫的钝化层系统,其中镍以金属形式存在 至少30 At。 %,可根据本发明的方法获得。

    Process for removing fine particulate soil from hard surfaces
    9.
    发明授权
    Process for removing fine particulate soil from hard surfaces 失效
    从硬表面除去细颗粒土的方法

    公开(公告)号:US07204890B2

    公开(公告)日:2007-04-17

    申请号:US10182480

    申请日:2001-01-19

    IPC分类号: B08B7/00

    摘要: Many prior art processes for cleaning predominantly organic hard surfaces have been found to be considerably less effective in removing very fine particles on such surfaces than are the best cleaners for metallic surfaces. However, it has been found, and forms the basis of this invention, that fine particles can be removed effectively from organic surfaces by an indirect process of first forming a thin solid coating over the surface and then removing the solid coating, into which the fine particles that formerly contaminated the surface to be cleaned have presumably become incorporated. Substantially hydrolyzed poly(vinyl acetate) has been found particularly useful for forming the thin solid coating when this coating is to be removed by treatment with an acidic aqueous solution; acrylate polymers are preferred if the solid coating is to be removed by an alkaline aqueous solution. In either instance, in order to obtain good wetting without damaging the surface to be cleaned, the material that forms the bulk of the solid coating is preferably applied to the surface to be cleaned in an aqueous solution or dispersion that also contains surfactant molecules that include imidazoline moieties. A method of quantifying the degree of removal of solid particles is also provided.

    摘要翻译: 已经发现用于清洁主要有机硬表面的许多现有技术方法在除去金属表面的最佳清洁剂之后,在除去这些表面上的非常细小的颗粒方面相当不太有效。 然而,已经发现并形成本发明的基础,可以通过间接方法从有机表面有效地除去细颗粒,所述间接方法首先在表面上形成薄的固体涂层,然后除去固体涂层,其中精细 以前被污染的待清洁表面的颗粒大概已被纳入。 已经发现基本上水解的聚(乙酸乙烯酯)在通过用酸性水溶液处理除去该涂层时可以形成薄的固体涂层; 丙烯酸酯聚合物是优选的,如果固体涂料要被碱性水溶液除去。 在任一情况下,为了获得良好的润湿性而不损坏要清洁的表面,形成固体涂层的主体的材料优选地应用于还含有表面活性剂分子的水溶液或分散体中的待清洁表面,所述表面活性剂分子包括 咪唑啉部分。 还提供了定量固体颗粒去除程度的方法。

    Method and apparatus for removing metal contamination from soil
    10.
    发明授权
    Method and apparatus for removing metal contamination from soil 失效
    从土壤中去除金属污染的方法和设备

    公开(公告)号:US5607060A

    公开(公告)日:1997-03-04

    申请号:US469607

    申请日:1995-06-06

    IPC分类号: B09C1/02 B03B7/00 C22B11/00

    CPC分类号: B09C1/02

    摘要: The invention is a process and an apparatus for removing metal contamination from soil. In the method, the soil is treated to produce soil with a small particle size. The particulate soil is then separated into a coarse fraction and a fine fraction. The coarse fraction and the fine fraction are contacted with a leach solution in separate contacting zones to remove the metal contamination from the soil, the metal is removed from the leach solution and the leach solution recycled to the leaching zones.

    摘要翻译: 本发明是一种从土壤中去除金属污染的工艺和设备。 在该方法中,土壤被处理以产生具有小粒径的土壤。 然后将颗粒状土壤分离成粗级分和精馏。 粗级分和细级分与独立接触区中的浸出溶液接触以除去来自土壤的金属污染物,将金属从浸出溶液中除去,并将浸出溶液再循环至浸出区。