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    Method to create region specific exposure in a layer
    1.
    发明授权
    Method to create region specific exposure in a layer 有权
    在图层中创建区域特定曝光的方法

    公开(公告)号：US07977032B2

    公开(公告)日：2011-07-12

    申请号：US10906268

    申请日：2005-02-11

    申请人： Christos D. Dimitrakopoulos ,  Daniel C. Edelstein ,  Vincent J. McGahay ,  Satyanarayana V. Nitta ,  Kevin S. Petrarca ,  Shom Ponoth ,  Shahab Siddiqui

    发明人： Christos D. Dimitrakopoulos ,  Daniel C. Edelstein ,  Vincent J. McGahay ,  Satyanarayana V. Nitta ,  Kevin S. Petrarca ,  Shom Ponoth ,  Shahab Siddiqui

    IPC分类号： G03F7/20

    CPC分类号： G03F7/2022

    摘要： A method of selectively altering material properties of a substrate in one region while making a different alteration of material properties in an adjoining region is provided. The method includes selectively masking a first portion of the substrate during a first exposure and selectively masking a second portion of the substrate during a second exposure. Additionally, a mask may be formed having more than one thickness where each thickness will selectively reduce the amount of energy from a blanket exposure of the substrate thereby allowing a substrate to receive different levels of energy dosage in a single blanket exposure.

    摘要翻译： 提供了一种在邻接区域中对材料性质进行不同的改变的同时选择性地改变一个区域中的衬底的材料特性的方法。 该方法包括在第一曝光期间选择性地掩蔽衬底的第一部分，并且在第二次曝光期间选择性地掩蔽衬底的第二部分。 另外，可以形成具有多于一个厚度的掩模，其中每个厚度将选择性地减少来自衬底的覆盖曝光的能量的量，从而允许衬底在单次覆盖曝光中接收不同水平的能量。

    RECOVERY OF HYDROPHOBICITY OF LOW-K AND ULTRA LOW-K ORGANOSILICATE FILMS USED AS INTER METAL DIELECTRICS
    5.
    发明申请
    RECOVERY OF HYDROPHOBICITY OF LOW-K AND ULTRA LOW-K ORGANOSILICATE FILMS USED AS INTER METAL DIELECTRICS 审中-公开
    作为金属电介质的低K和超低K有机硅膜的疏水性恢复

    公开(公告)号：US20110003402A1

    公开(公告)日：2011-01-06

    申请号：US12749213

    申请日：2010-03-29

    申请人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    发明人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    IPC分类号： H01L21/30

    CPC分类号： H01L21/76826 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/31058 ,  H01L21/76807 ,  H01L21/76814 ,  H01L2924/0002 ,  H01L2924/00

    摘要： Often used to reduce the RC delay in integrated circuits are dielectric films of porous organosilicates which have a silica like backbone with alkyl or aryl groups (to add hydrophobicity to the materials and create free volume) attached directly to the Si atoms in the network. Si—R bonds rarely survive an exposure to plasmas or chemical treatments commonly used in processing; this is especially the case in materials with an open cell pore structure. When Si—R bonds are broken, the materials lose hydrophobicity, due to formation of hydrophilic silanols and low dielectric constant is compromised. A method by which the hydrophobicity of the materials is recovered using a novel class of silylation agents which may have the general formula (R2N)XSiR′Y where X and Y are integers from 1 to 3 and 3 to 1 respectively, and where R and R′ are selected from the group of hydrogen, alkyl, aryl, allyl and a vinyl moiety. Mechanical strength of porous organosilicates is also improved as a result of the silylation treatment.

    摘要翻译： 通常用于减少集成电路中的RC延迟的是多孔有机硅酸盐的介电膜，其具有二氧化硅像主链与烷基或芳基（以增加材料的疏水性并产生自由体积）直接连接到网络中的Si原子。 Si-R键在暴露于等离子体或通常用于加工的化学处理中很少存活; 这在具有开孔细孔结构的材料中尤其如此。 当Si-R键断裂时，材料由于形成亲水硅烷醇而损失疏水性，并且低介电常数受损。 使用新型甲硅烷基化剂回收材料的疏水性的方法，其可以具有通式（R2N）XSiR'Y，其中X和Y分别为1至3和3至1的整数，并且其中R和 R'选自氢，烷基，芳基，烯丙基和乙烯基部分。 由于甲硅烷基化处理，多孔有机硅酸盐的机械强度也得到改善。

    Recovery of hydrophobicity of low-k and ultra low-k organosilicate films used as inter metal dielectrics
    6.
    发明授权
    Recovery of hydrophobicity of low-k and ultra low-k organosilicate films used as inter metal dielectrics 失效
    用作金属间电介质的低k和超低k有机硅酸盐膜的疏水性的恢复

    公开(公告)号：US07687913B2

    公开(公告)日：2010-03-30

    申请号：US11676447

    申请日：2007-02-19

    申请人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    发明人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    IPC分类号： H01L23/48 ,  H01L23/52 ,  H01L29/40

    CPC分类号： H01L21/76826 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/31058 ,  H01L21/76807 ,  H01L21/76814 ,  H01L2924/0002 ,  H01L2924/00

    摘要： Often used to reduce the RC delay in integrated circuits are dielectric films of porous organosilicates which have a silica like backbone with alkyl or aryl groups (to add hydrophobicity to the materials and create free volume) attached directly to the Si atoms in the network. Si—R bonds rarely survive an exposure to plasmas or chemical treatments commonly used in processing; this is especially the case in materials with an open cell pore structure. When Si—R bonds are broken, the materials lose hydrophobicity, due to formation of hydrophilic silanols and low dielectric constant is compromised. A method by which the hydrophobicity of the materials is recovered using a novel class of silylation agents which may have the general formula (R2N)XSiR′Y where X and Y are integers from 1 to 3 and 3 to 1 respectively, and where R and R′ are selected from the group of hydrogen, alkyl, aryl, allyl and a vinyl moiety. Mechanical strength of porous organosilicates is also improved as a result of the silylation treatment.

    摘要翻译： 通常用于减少集成电路中的RC延迟的是多孔有机硅酸盐的介电膜，其具有二氧化硅像主链与烷基或芳基（以增加材料的疏水性并产生自由体积）直接附着在网络中的Si原子。 Si-R键在暴露于等离子体或通常用于加工的化学处理中很少存活; 这在具有开孔细孔结构的材料中尤其如此。 当Si-R键断裂时，材料由于形成亲水硅烷醇而损失疏水性，并且低介电常数受损。 使用新型甲硅烷基化剂回收材料的疏水性的方法，其可以具有通式（R2N）XSiR'Y，其中X和Y分别为1至3和3至1的整数，并且其中R和 R'选自氢，烷基，芳基，烯丙基和乙烯基部分。 由于甲硅烷基化处理，多孔有机硅酸盐的机械强度也得到改善。

    Recovery of hydrophobicity of low-k and ultra low-k organosilicate films used as inter metal dielectrics
    7.
    发明授权
    Recovery of hydrophobicity of low-k and ultra low-k organosilicate films used as inter metal dielectrics 失效
    用作金属间电介质的低k和超低k有机硅酸盐膜的疏水性的恢复

    公开(公告)号：US07179758B2

    公开(公告)日：2007-02-20

    申请号：US10853771

    申请日：2004-05-25

    申请人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    发明人： Nirupama Chakrapani ,  Matthew E. Colburn ,  Christos D. Dimitrakopoulos ,  Dirk Pfeiffer ,  Sampath Purushothaman ,  Satyanarayana V. Nitta

    IPC分类号： H01L21/311 ,  H01L21/469 ,  H01L21/31 ,  H01L21/461 ,  H01L21/302

    CPC分类号： H01L21/76826 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/31058 ,  H01L21/76807 ,  H01L21/76814 ,  H01L2924/0002 ,  H01L2924/00

    摘要： Often used to reduce the RC delay in integrated circuits are dielectric films of porous organosilicates which have a silica like backbone with alkyl or aryl groups (to add hydrophobicity to the materials and create free volume) attached directly to the Si atoms in the network. Si—R bonds rarely survive an exposure to plasmas or chemical treatments commonly used in processing; this is especially the case in materials with an open cell pore structure. When Si—R bonds are broken, the materials lose hydrophobicity, due to formation of hydrophilic silanols and low dielectric constant is compromised. A method by which the hydrophobicity of the materials is recovered using a novel class of silylation agents which may have the general formula (R2N)XSiR′Y where X and Y are integers from 1 to 3 and 3 to 1 respectively, and where R and R′ are selected from the group of hydrogen, alkyl, aryl, allyl and a vinyl moiety. Mechanical strength of porous organosilicates is also improved as a result of the silylation treatment.

    摘要翻译： 通常用于减少集成电路中的RC延迟的是多孔有机硅酸盐的介电膜，其具有二氧化硅像主链与烷基或芳基（以增加材料的疏水性并产生自由体积）直接连接到网络中的Si原子。 Si-R键在暴露于等离子体或通常用于加工的化学处理中很少存活; 这在具有开孔细孔结构的材料中尤其如此。 当Si-R键断裂时，材料由于形成亲水硅烷醇而损失疏水性，并且低介电常数受损。 使用新型甲硅烷基化剂回收材料的疏水性的方法，其可以具有通式（R 2 N 2）X SiR'Y 其中X和Y分别为1至3和3至1的整数，并且其中R和R'选自氢，烷基，芳基，烯丙基和乙烯基部分。 由于甲硅烷基化处理，多孔有机硅酸盐的机械强度也得到改善。

    Reliable BEOL integration process with direct CMP of porous SiCOH dielectric
    8.
    发明授权
    Reliable BEOL integration process with direct CMP of porous SiCOH dielectric 有权
    可靠的BEOL集成工艺与多孔SiCOH电介质的直接CMP

    公开(公告)号：US07948083B2

    公开(公告)日：2011-05-24

    申请号：US11763135

    申请日：2007-06-14

    申请人： Christos D. Dimitrakopoulos ,  Stephen M. Gates ,  Vincent J. McGahay ,  Sanjay C. Mehta

    发明人： Christos D. Dimitrakopoulos ,  Stephen M. Gates ,  Vincent J. McGahay ,  Sanjay C. Mehta

    IPC分类号： H01L29/40

    CPC分类号： H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76834 ,  H01L21/76885 ,  H01L23/53295 ,  H01L2924/0002 ,  H01L2924/00

    摘要： The present invention relates to methods of improving the fabrication of interconnect structures of the single or dual damascene type, in which there is no problem of hard mask retention or of conductivity between the metal lines after fabrication. The methods of the present invention include at least steps of chemical mechanical polishing and UV exposure or chemical repair treatment which steps improve the reliability of the interconnect structure formed. The present invention also relates to an interconnect structure which include a porous ultra low k dielectric of the SiCOH type in which the surface layer thereof has been modified so as to form a gradient layer that has both a density gradient and a C content gradient.

    摘要翻译： 本发明涉及改进单镶嵌型或双镶嵌型互连结构的制造方法，其中在制造之后金属线之间没有硬掩模保持或导电性问题。 本发明的方法至少包括化学机械抛光和UV曝光或化学修复处理的步骤，这些步骤提高了形成的互连结构的可靠性。 本发明还涉及一种互连结构，其包括SiCOH型的多孔超低k电介质，其中其表面层被修饰以形成具有密度梯度和C含量梯度的梯度层。

    Reliable BEOL integration process with direct CMP of porous SiCOH dielectric
    9.
    发明授权
    Reliable BEOL integration process with direct CMP of porous SiCOH dielectric 失效
    可靠的BEOL集成工艺与多孔SiCOH电介质的直接CMP

    公开(公告)号：US07253105B2

    公开(公告)日：2007-08-07

    申请号：US11063152

    申请日：2005-02-22

    申请人： Christos D. Dimitrakopoulos ,  Stephen M. Gates ,  Vincent J. McGahay ,  Sanjay C. Mehta

    发明人： Christos D. Dimitrakopoulos ,  Stephen M. Gates ,  Vincent J. McGahay ,  Sanjay C. Mehta

    IPC分类号： H01L21/44

    CPC分类号： H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76834 ,  H01L21/76885 ,  H01L23/53295 ,  H01L2924/0002 ,  H01L2924/00

    摘要： The present invention relates to methods of improving the fabrication of interconnect structures of the single or dual damascene type, in which there is no problem of hard mask retention or of conductivity between the metal lines after fabrication. The methods of the present invention include at least steps of chemical mechanical polishing and UV exposure or chemical repair treatment which steps improve the reliability of the interconnect structure formed. The present invention also relates to an interconnect structure which include a porous ultra low k dielectric of the SiCOH type in which the surface layer thereof has been modified so as to form a gradient layer that has both a density gradient and a C content gradient.

    摘要翻译： 本发明涉及改进单镶嵌型或双镶嵌型互连结构的制造方法，其中在制造之后金属线之间没有硬掩模保持或导电性问题。 本发明的方法包括化学机械抛光和紫外线曝光或化学修复处理的至少步骤，这些步骤提高了形成的互连结构的可靠性。 本发明还涉及一种互连结构，其包括SiCOH型的多孔超低k电介质，其中其表面层被修饰以形成具有密度梯度和C含量梯度的梯度层。