Process for sweetening petroleum cuts without regular addition of
alkaline solution using a basic solid catalyst
    6.
    发明授权
    Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst 失效
    使用碱性固体催化剂不经常地加入碱性溶液来甜化石油馏分的方法

    公开(公告)号:US5591323A

    公开(公告)日:1997-01-07

    申请号:US474766

    申请日:1995-06-07

    摘要: A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by being contacted with a porous catalyst, in the presence of air said process being characterised in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of an alkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milligrams of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.

    摘要翻译: 一种用于甜化含有硫醇的石油馏分的方法,其中所述石油馏分通过与多孔催化剂接触而经受氧化条件,在空气存在下,所述方法的特征在于所述催化剂至少包含10至98重量% 一个矿物固相由Si / Al原子比小于或等于5,1-60重量%的活性炭,0.02-2重量%的至少一种金属螯合物和0-20重量%的碱性硅铝酸盐构成, 的至少一种有机或矿物结合剂,具有根据2896 ASTM标准确定的碱度,每克20mg的钾碱和10m 2 g -1的总BET表面积,并且在其孔结构内部含有永久性水性 相为干燥催化剂的0.1-40重量%。