摘要:
A process for recovering sulfur in a sulfur recovery unit comprising the steps of reacting hydrogen sulfide and oxygen in the reaction furnace at a minimum reaction temperature to produce a reaction effluent; reducing the temperature of the reaction effluent from the minimum reaction temperature to a boiler section outlet temperature to produce a cooled effluent, the cooled effluent comprises hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants; reacting the hydrogen sulfide, sulfur dioxide, and sulfur-containing contaminants in the catalytic extension to produce a boiler catalytic effluent; reducing the boiler catalytic effluent temperature such that the elemental sulfur condenses to form liquid sulfur and a gases stream; reacting the hydrogen sulfide and sulfur-containing contaminants with the oxygen to produce an oxidizer outlet stream comprises sulfur dioxide; and separating the sulfur dioxide in the scrubbing unit to produce a recycle stream and an effluent gases, the recycle stream comprises sulfur dioxide.
摘要:
A method of producing sulphuric acid from a sour tail gas comprises (a) obtaining a sour tail gas stream comprising H2S or reduced sulphur species or a combination thereof from an oil and gas facility; (b) subjecting the sour tail gas stream to oxidation and obtaining an oxidized gas stream comprising SO2; and, (c) utilizing the oxidized gas stream to obtain sulphuric acid and a SO2 reduced tail gas stream. The method may further comprise subjecting the oxidized gas stream to a regenerable absorption process. The sulphuric acid may be used to produce fertilizer.
摘要:
The present invention relates to a process and a device for the combustion of sulphur and/or sulphur-containing compounds, via which a sufficient production of SO2-containing gases having a high SO2 concentration is made possible. The combustion preferably proceeds using a combustion gas which has an oxygen fraction at least as high as air, but preferably a higher fraction of oxygen. The process and the device should be suitable, in particular, for providing sulphur dioxide as a source for further production of sulphuric acid or highly concentrated SO3-containing gases. In addition, the device and the process should be suitable for oxidizing hydrogen-sulphide-containing gases, such as occur, for example, in the refinery industry, in high concentrations to SO2.
摘要:
The invention relates to a method for producing gaseous hydrogen and strong sulphuric acid (97-100 wt-%) simultaneously from sulphur dioxide gas and water. Sulphur dioxide gas stream is divided into two separate sub-streams, the first sub-stream is routed for water decomposition in a partial thermochemical cycle of the hydrogen and sulphuric acid production and the second sub-stream is fed to the oxidation of the sulphur dioxide to sulphur trioxide.
摘要:
A process for treating acid gas comprising hydrogen sulfide comprises introducing a first acid gas into a reducing furnace to produce a first oxidized gas stream, cooling the first oxidized gas stream in a first heat recovery system, introducing the cooled gas stream into an oxidizing furnace to produce a second oxidized gas stream and cooling the second oxidized gas stream in a second heat recovery system. The acid gas is preferably produced in a refinery after treatment of sour gas or sour water. Spent acid may be fed into oxidizing furnace as part of a sulfuric acid recovery process. The spent acid can be spent sulfuric acid from a sulfuric acid alkylation process.
摘要:
Methods of making silicon carbide comprise providing at least one organosilicon precursor material, hydrolyzing the organosilicon in a solution comprising water and an acid catalyst, providing a surfactant to the solution, forming a gel by adding a base to the solution, and heating the gel at a temperature and for a time sufficient to produce silicon carbide.
摘要:
A process for the processing of spent photographic baths of black and white processes, namely developing baths with a preponderant content of alkali sulphite, particularly sodium sulphite, and fixing baths with a preponderant content of thiosulphates, particularly ammonium thiosulphate and/or sodium thiosulphate is proposed and is characterized in that following the deposition of the silver contained in the baths, the spent fixing baths are brought to a pH of approximately 0.5 with concentrated HCl and the elementary sulphur resulting from the decomposition of the thiosulphates is separated, whilst the remaining sulphurous acid intermediate solution is mixed with the spent developing baths and adjusted to a pH of approximately 2 and the resulting, SO.sub.2 -supersaturated solution is heated and pure SO.sub.2 is drawn off in a vacuum. Finally, the residual solution is adjusted to a pH of approximately 10 with Ca(OH).sub.2 and the liberated ammonia is drawn off.
摘要:
There is provided a process for the catalytic production of hydrogen from the reaction of hydrogen sulfide and carbon monoxide with the elimination of the carbonyl sulfide and/or sulfur dioxide by-products. The carbonyl sulfide and the sulfur dioxide are combusted or reacted in one or more reaction steps with each other, oxygen and/or hydrogen sulfide to produce carbon dioxide, water, sulfur or sulfuric acid or a combination of these.
摘要:
A method and apparatus for desulfurizing a gas and regenerating a sorbent is disclosed. The sulfur-containing feed gas which can be an effluent gas from a coal gasification reactor, for example, is desulfurized with a particulated metallic oxide sorbent in a transport riser. The sulfided sorbent is than separated from a desulfurized effluent gas and regenerated by contact with an oxygen-containing gas in a transport riser. The regenerated sorbent is separated from an SO.sub.2 containing offgas and recycled to the desulfurization step. The degree of sorbent conversion in the desulfurization step is held at a low level and the sorbent regeneration rate is increased to avoid excessive temperature rise in the regeneration step. In such manner, sorbent cooling can be substantially eliminated. The regeneration riser preferably comprises a once-through lift riser to minimize the riser transport gas requirements to just oxidant gas or oxidant gas mixed with a reduced amount of diluent gas. A reduction in use of diluent gas give a relatively high offgas SO.sub.2 concentration of as much as 15 mole percent, suitable for sulfuric acid manufacture and/or reduction to sulfur.