公开(公告)号：US20030180215A1

公开(公告)日：2003-09-25

申请号：US10299879

申请日：2002-11-19

Applicant: Conoco, Inc.

Inventor： Tianyan Niu ,  Daxiang Wang ,  David M. Minahan ,  Harold A. Wright ,  Gloria I. Straguzzi

IPC: C01B003/26 ,  B01J023/10

CPC classification number: C01B3/40 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/40 ,  B01J23/58 ,  B01J23/63 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0205 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1005 ,  C01B2203/1011 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1241 ,  Y02P20/52

Abstract: Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500null C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.

Abstract translation: 公开了控制的孔结构催化剂，其有效催化将甲烷部分氧化成CO和H 2，并且有利地能够引发反应而不需要额外的点火源。 优选的催化剂包括负载在具有一定表面积，孔体积，孔径和金属分散特性的氧化铝或改性氧化铝载体上的铑和钐，其允许在低于500℃的温度和少量或不使用的温度下使反应点燃 的点火剂。 还描述了一种部分氧化轻烃以形成合成气的方法，以及提高该方法的低温点火的方法。

公开(公告)号：US20030045423A1

公开(公告)日：2003-03-06

申请号：US10162056

申请日：2002-06-04

Applicant: Conoco Inc.

Inventor： Hasan Dindi ,  William H. Manogue ,  Norman Herron ,  Tianyan Niu ,  Daxiang Wang ,  David M. Minahan

IPC: C01B003/26

CPC classification number: C01B3/40 ,  B01J23/002 ,  B01J23/56 ,  B01J23/63 ,  B01J23/894 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0236 ,  B01J2523/00 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1017 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/3706 ,  B01J2523/822 ,  B01J2523/3787

Abstract: A family of supported hexagonal phase mixed metal oxide catalysts are disclosed that have the general formula M2.5LnRh6O13 (expressed as atomic ratios), wherein M refers to Group II elements such as Mg, Ca, Ba, Sr and Be or a Group VIII transition metal that can exist in a null2 oxidation state, such as Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Nb, Pd, Cd and Ta. Ln refers to the rare earth lanthanide group of elements, such as La, Yb, Sm and Ce. This family of catalysts demonstrate unexpected activity for efficiently catalyzing the net partial oxidation of methane in a short contact time reactor, with high selectivities for H2 product.

Abstract translation: 公开了具有通式M2.5LnRh6O13（表示为原子比）的负载六方相混合金属氧化物催化剂族，其中M是指II族元素如Mg，Ca，Ba，Sr和Be或VIII族过渡 可以存在于+2氧化态的金属，例如Ti，V，Mn，Fe，Co，Ni，Cu，Zn，Nb，Pd，Cd和Ta。 Ln是指稀土镧系元素，如La，Yb，Sm和Ce。 这种催化剂系列显示出意想不到的活性，用于在短接触时间反应器中有效催化甲烷的净部分氧化，对于H 2产物具有高选择性。

公开(公告)号：US20030165424A1

公开(公告)日：2003-09-04

申请号：US10339109

申请日：2003-01-09

Applicant: Conoco Inc.

Inventor： Sriram Ramani ,  Joe D. Allison ,  David M. Minahan ,  Harold A. Wright

IPC: C01B003/38

CPC classification number: B01J37/08 ,  B01J23/76 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J23/85 ,  B01J23/889 ,  B01J23/8892 ,  B01J23/894 ,  B01J23/8946 ,  B01J23/8986 ,  B01J23/8993 ,  B01J37/0205 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1029 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52

Abstract: A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.

Abstract translation: 公开了用于轻烃的催化部分氧化以在超大气压下产生合成气的方法和催化剂。 用于该方法的优选催化剂包括镍 - 镁氧化物固溶体和至少一种选自Cr，Mn，Mo，W，Sn，Re，Rh，Ru，Ir，Pt，La，Ce，Sm，Yb， Lu，Bi，Sb，In和P及其氧化物。