公开(公告)号：US07718730B2

公开(公告)日：2010-05-18

申请号：US10742484

申请日：2003-12-19

申请人： Richard R. Roesler ,  Kurt C. Frisch ,  Craig E. Jansen ,  Dinesh Pethiyagoda ,  Kevan E. Hudson

发明人： Richard R. Roesler ,  Kurt C. Frisch ,  Craig E. Jansen ,  Dinesh Pethiyagoda ,  Kevan E. Hudson

IPC分类号： B05D3/02 ,  B32B5/02 ,  B32B7/12 ,  B32B27/00 ,  B32B27/04 ,  B32B27/12 ,  B32B27/40 ,  C08G18/00 ,  C08G18/08 ,  C08G18/28 ,  C08G77/04 ,  C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  C08L83/00 ,  C08L83/04 ,  C09J4/00 ,  C09J7/02 ,  C09J101/00 ,  C09J201/00 ,  D06M15/643

CPC分类号： C08G18/289 ,  C08G18/10 ,  C08G2190/00 ,  C09J175/04 ,  Y10S524/906 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31573 ,  Y10T428/31587 ,  Y10T428/31591 ,  Y10T428/31605 ,  Y10T442/2492 ,  Y10T442/2762 ,  Y10T442/277 ,  Y10T442/2861 ,  Y10T442/2918

摘要： A two-component adhesive, sealant, or coating composition containing (i) a first component containing a portion of an alkoxysilane-functional urethane and water; and (ii) a second component containing the remaining portion of the alkoxysilane-functional urethane and a catalyst. The alkoxysilane-functional urethane includes the reaction product of (a) the reaction product of a hydroxy functional compound and a polyisocyanate, that contains isocyanate groups; with (b) an amine functional aspartate. The composition is used in a method of bonding a first substrate to a second substrate. The method includes (a) combining component i) and component ii) to form a mixture, applying a coating of the mixture to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate. The method is used make an assembly.

摘要翻译： 一种双组分粘合剂，密封剂或涂料组合物，其包含（i）含有部分烷氧基硅烷官能的氨基甲酸酯和水的第一组分; 和（ii）含有烷氧基硅烷官能氨基甲酸酯的剩余部分的第二成分和催化剂。 烷氧基硅烷官能化氨基甲酸酯包括（a）含有异氰酸酯基的羟基官能化合物和多异氰酸酯的反应产物的反应产物; 与（b）胺功能性天冬氨酸。 该组合物用于将第一衬底粘合到第二衬底的方法中。 该方法包括（a）将组分i）和组分ii）组合以形成混合物，将混合物的涂层施加到第一衬底或第二衬底的至少一个表面，并使第一衬底的表面与表面 的第二基板。 该方法用于组装。

公开(公告)号：US07060750B2

公开(公告)日：2006-06-13

申请号：US10834143

申请日：2004-04-28

申请人： Craig E. Jansen ,  Kurt C. Frisch ,  Richard R. Roesler ,  Dinesh Pethiyagoda ,  Kevan E. Hudson

发明人： Craig E. Jansen ,  Kurt C. Frisch ,  Richard R. Roesler ,  Dinesh Pethiyagoda ,  Kevan E. Hudson

IPC分类号： C08G18/48

CPC分类号： C08G18/3893 ,  C08G18/10 ,  C08G18/283 ,  C08G18/4866 ,  C08G2190/00

摘要： An adhesive, sealant or coating composition that includes: a) 20 to 80% by weight, based on the weight of a), b), and c) of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, b) 20 to 80% by weight, based on the weight of a), b), and c) of a polyether urethane containing one reactive silane group and one or more polyether segments, and c) 1 to 60% by weight, based on the weight of a), b), and c) of a pigment having a BET surface area of from 15 to 100 m2/g and an oil absorption of from 40 to 110 cc/100 g; where the sum of a), b), and c) does not exceed 100% by weight. The composition can be used to bond and/or coat substrates.

摘要翻译： 一种粘合剂，密封剂或涂料组合物，其包括：a）基于a），b）和c）的重量为20至80重量％的含有两个或更多个反应性硅烷基团和一个或多个聚醚部分的聚醚型聚氨酯 ，b）基于a），b）和c）的重量为20至80重量％的含有一个反应性硅烷基团和一个或多个聚醚链段的聚醚型氨基甲酸酯，以及c）1至60重量％ 基于a），b）和c）的重量，并且c）具有15-100m 2 / g的BET表面积和40至110cc / 100的吸油量的颜料 G; a），b）和c）的总和不超过100重量％。 该组合物可用于粘合和/或涂覆底物。

公开(公告)号：US07115696B2

公开(公告)日：2006-10-03

申请号：US10690751

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G77/24

CPC分类号： C09J175/08 ,  C08G18/10 ,  C08G18/283 ,  C08G18/4866 ,  C08G2190/00 ,  C08G18/289

摘要： A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, where the polyether segments have a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and the sum of Mn of all of the polyether segments per molecule averages 6000 to 20,000, and the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula and b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000.

公开(公告)号：US06809170B2

公开(公告)日：2004-10-26

申请号：US10690953

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Karsten Danielmeier ,  Dinesh Pethiyagoda ,  Gerhard Ruttmann

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Karsten Danielmeier ,  Dinesh Pethiyagoda ,  Gerhard Ruttmann

IPC分类号： C08G7726

CPC分类号： C08G18/4866 ,  C08G18/0885 ,  C08G18/283 ,  C08G18/289 ,  C08G18/4825 ,  C08G2190/00

摘要： Preparation of moisture-curable, alkoxysilane-functional polyether urethanes by reacting at an NCO:OH equivalent ratio of 1.5:1 to 2.5:1 a) a hydroxyl component containing i) 20 to 100 wt. %, of a polyether diol and other polyether segments, where the polyether segments have Mn of at least 3000 and degree of unsaturation of less than 0.04 meq/g, where the sum of Mn of polyether segments per molecule averages 6000 to 20,000, and ii) 0 to 80 wt. % of a polyether monool and other polyether segments having Mn of 1000 to 15,000, with b) an isocyanate component containing i) 20 to 100 wt. % of a diisocyanate, and ii) 0 to 80 wt. % of a monoisocyanate, forming an isocyanate-containing reaction product reacted at an equivalent ratio of 0.8:1 to 1.1:1 with c) a compound containing an isocyanate-reactive group and reactive silane groups where at least 10 mole % is a compound of formula

公开(公告)号：US06844413B2

公开(公告)日：2005-01-18

申请号：US10690956

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/38 ,  C08G18/48 ,  C09D175/04 ,  C09J175/04 ,  C08G77/26

CPC分类号： C08G18/3893 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/283 ,  C08G18/289 ,  C08G18/3821 ,  C08G18/4866 ,  C08G2190/00 ,  C09J175/04

摘要： A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, where the polyether segments have a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and the sum of Mn of all of the polyether segments per molecule averages 6000 to 20,000, and the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula H2N—Y—Si—(X)3  (I) b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000, where the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula

摘要翻译： 含有20〜90重量％的含有两个以上反应性硅烷基团和一个以上聚醚链段的聚醚型聚氨酯的水分固化性烷氧基硅烷官能团聚氨酯，其中聚醚链段的数均分子量（Mn） 至少3000，不饱和度小于0.04毫当量/ g，每个分子中所有聚醚链段的Mn的总和平均为6000至20,000，反应性硅烷基团通过异氰酸酯基团与 一种化合物）10-80重量％的含有一个反应性硅烷基团的聚醚聚氨酯和一个或多个Mn为1000-15,000的聚醚链段，其中反应性硅烷基团通过异氰酸酯基团与 式的化合物

公开(公告)号：US06833423B2

公开(公告)日：2004-12-21

申请号：US10690954

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G7724

CPC分类号： C08G18/3893 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/283 ,  C08G18/3821 ,  C08G18/4866 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/04 ,  C09K3/1021 ,  C08G18/289

摘要： A moisture curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and polyether segments having a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, where the sum of Mn of the polyether segments averages 6000 to 20,000, and the reactive silane groups are incorporated by reaction of an isocyanate-reactive group with a compound of formula OCN—Y—Si—(X)3  (I) b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000, where the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula

摘要翻译： 含有a）20〜90重量％的含有两个以上反应性硅烷基团的聚醚型聚氨酯和数均分子量（Mn）为3000以上且不饱和度的聚醚链段的湿气固化型烷氧基硅烷官能团聚氨酯 小于0.04毫当量/克，其中聚醚片段的Mn的平均值为6000至20,000，并且反应性硅烷基团通过异氰酸酯反应性基团与公式的化合物的反应引入）10至80重量％ 含有一个反应性硅烷基团和一个或多个Mn为1000至15,000的聚醚链段的聚醚型聚氨酯，其中反应性硅烷基团通过异氰酸酯基与式

公开(公告)号：US06998459B2

公开(公告)日：2006-02-14

申请号：US10690931

申请日：2003-10-22

申请人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

发明人： Richard R. Roesler ,  Derek L. Crawford ,  Kurt C. Frisch ,  Dinesh Pethiyagoda ,  Karsten Danielmeier

IPC分类号： C08G77/26

CPC分类号： C09J175/08 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/283 ,  C08G18/289 ,  C08G18/3821 ,  C08G18/4825 ,  C08G18/718 ,  C08G18/755 ,  C08G18/778 ,  C08G2190/00

摘要： The present invention relates to a polyether urethane containing one reactive silane group and one or more polyether segments having a number average molecular weight of 1000 to 15,000, wherein the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound corresponding to the formula wherein X represents identical or different organic groups which are inert to isocyanate groups below 100° C., provided that at least two of these groups are alkoxy or acyloxy groups, Y represents a linear or branched alkylene group containing 1 to 8 carbon atoms and R1 represents an organic group which is inert to isocyanate groups at a temperature of 100° C. or less.

摘要翻译： 本发明涉及含有一个反应性硅烷基团和一个或多个数均分子量为1000至15,000的聚醚链段的聚醚型聚氨酯，其中反应性硅烷基团通过异氰酸酯基团与对应于 形成

公开(公告)号：US07144955B2

公开(公告)日：2006-12-05

申请号：US10694107

申请日：2003-10-27

申请人： Scott A. Grace ,  Michael J. Dvorchak ,  Richard R. Roesler ,  Dinesh Pethiyagoda ,  Michael K. Jeffries ,  Jan Weikard

发明人： Scott A. Grace ,  Michael J. Dvorchak ,  Richard R. Roesler ,  Dinesh Pethiyagoda ,  Michael K. Jeffries ,  Jan Weikard

IPC分类号： C08L75/12 ,  C08G18/73 ,  C08G18/75

CPC分类号： C08G18/792 ,  C08G18/4208 ,  C08G18/4238 ,  C08G18/672 ,  C08G18/807 ,  C08G18/8175 ,  C09D175/16 ,  C08G18/42

摘要： Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.

摘要翻译： 含有可热固化的封端多异氰酸酯（也含有不饱和键的溶剂型双重固化涂层）和制备这些涂层的方法。 不饱和键如丙烯酸酯基团可以通过自由基机制如UV固化而交联。

公开(公告)号：US06894138B1

公开(公告)日：2005-05-17

申请号：US10723489

申请日：2003-11-26

申请人： Richard R. Roesler ,  Patricia B. Jacobs ,  Dinesh Pethiyagoda ,  Tabitha H. Riggio ,  Marianne M. Salek ,  Emery Yuhas

发明人： Richard R. Roesler ,  Patricia B. Jacobs ,  Dinesh Pethiyagoda ,  Tabitha H. Riggio ,  Marianne M. Salek ,  Emery Yuhas

IPC分类号： C07D231/12 ,  C08G18/10 ,  C08G18/73 ,  C08G18/80

CPC分类号： C08G18/10 ,  C08G18/73 ,  C08G18/807

摘要： The present invention is directed to a blocked polyisocyanate based on nonane triisocyanate. More particularly, the invention is directed to a blocked polyisocyanate useful in solvent borne coating compositions and comprising the reaction product of: a) nonane triisocyanate; b) a pyrazole blocking agent; and c) a diol or polyol.

摘要翻译： 本发明涉及基于壬烷三异氰酸酯的封端多异氰酸酯。 更具体地说，本发明涉及可用于溶剂型涂料组合物的封端多异氰酸酯，其包含以下物质：a）壬烷三异氰酸酯; b）吡唑封闭剂; 和c）二醇或多元醇。

公开(公告)号：US20050090620A1

公开(公告)日：2005-04-28

申请号：US10694107

申请日：2003-10-27

申请人： Scott Grace ,  Michael Dvorchak ,  Richard Roesler ,  Dinesh Pethiyagoda ,  Michael Jeffries ,  Jan Weikard

发明人： Scott Grace ,  Michael Dvorchak ,  Richard Roesler ,  Dinesh Pethiyagoda ,  Michael Jeffries ,  Jan Weikard

IPC分类号： C08G18/42 ,  C08G18/67 ,  C08G18/76 ,  C08G18/79 ,  C08G18/80 ,  C08G18/81 ,  C09D175/16 ,  C08F4/00

CPC分类号： C08G18/792 ,  C08G18/4208 ,  C08G18/4238 ,  C08G18/672 ,  C08G18/807 ,  C08G18/8175 ,  C09D175/16 ,  C08G18/42

摘要： Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.

摘要翻译： 含有可热固化的封端多异氰酸酯（也含有不饱和键的溶剂型双重固化涂层）和制备这些涂层的方法。 不饱和键如丙烯酸酯基团可以通过自由基机制如UV固化而交联。