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    WATER-BASED SURFACE TREATMENT AGENT
    1.
    发明申请
    WATER-BASED SURFACE TREATMENT AGENT 审中-公开

    公开(公告)号：US20170342275A1

    公开(公告)日：2017-11-30

    申请号：US15604963

    申请日：2017-05-25

    申请人： DAIKIN INDUSTRIES, LTD. ,  DAIKIN AMERICA INC.

    发明人： J. Kasey BRIDGES ,  Ronald O. SKIDDS ,  Takashi ENOMOTO ,  Masahiro MIYAHARA

    IPC分类号： C09D5/16 ,  D06N3/04 ,  D06M15/263 ,  D06N3/00 ,  C08F220/18 ,  C09D133/08

    摘要： A surface treatment agent which is an aqueous emulsion containing: (a) a fluorine-free polymer including: (i) repeating units derived from a long-chain (meth)acrylate ester monomer represented by the formula: CH2═CA11-C(═O)—O-A12, wherein A11 is a hydrogen atom or a methyl group, and A12 is a linear or branched aliphatic hydrocarbon group having 10-30 carbon atoms; (b) a surface active agent including both of a nonionic surface active agent and an anionic surface active agent, wherein the amount of the anionic surface active agent is at least 22% by weight, based on the total of the nonionic surface active agent and the anionic surface active agent; and (c) a liquid medium comprising water.

    SURFACE TREATMENT AGENT
    2.
    发明申请
    SURFACE TREATMENT AGENT 审中-公开

    公开(公告)号：US20190077984A1

    公开(公告)日：2019-03-14

    申请号：US16085157

    申请日：2017-03-15

    申请人： DAIKIN INDUSTRIES, LTD.

    发明人： Rumi KAWABE ,  Masaki FUKUMORI ,  Ryosuke HARA ,  Masahiro MIYAHARA ,  Shinichi MINAMI ,  Ikuo YAMAMOTO

    IPC分类号： C09D151/06 ,  D06M15/248 ,  D06M15/263 ,  D06M13/165

    摘要： Provided is a surface treatment agent which does not use fluorine-containing monomers, particularly fluoroalkyl group-containing monomers. The surface treatment agent is a water-based emulsion which includes: a copolymer (1) which includes a first polymer formed from first monomers, and a second polymer formed from second monomers, wherein the second polymer is polymerized in the presence of the first polymer, the first monomers include a long-chain acrylate ester monomer (a) represented by the formula CH2═CA11-C(═O)—O-A12 (in the formula, A11 represents hydrogen, a monovalent organic group, or a halogen, and A12 represents a C18-30 straight-chain or branched hydrocarbon group), the first monomers do not include a halogenated olefin monomer (b), and the second monomers include the halogenated olefin monomer (b); a surfactant (2) including a nonionic surfactant; and a liquid medium (3) including water.

    DISPERSION
    3.
    发明申请
    DISPERSION 有权

    公开(公告)号：US20220411663A1

    公开(公告)日：2022-12-29

    申请号：US17902394

    申请日：2022-09-02

    申请人： DAIKIN INDUSTRIES, LTD.

    发明人： Ikuo YAMAMOTO ,  Masahiro MIYAHARA ,  Shinichi MINAMI

    IPC分类号： C09D185/00

    摘要： A dispersion containing a fluorine-containing polymer and a liquid medium. The fluorine-containing polymer includes a repeating unit derived from a fluorine-containing monomer (a) having a Q value of 2.0 or more and comprising a fluoroalkyl group, and a repeating unit derived from a chloride monomer (b) that is at least one selected from vinyl chloride and vinylidene chloride. Further, the dispersion has a concentration of unreacted chloride monomer (b) of 2.0 ppm or less.

    SURFACE TREATMENT AGENT
    4.
    发明申请
    SURFACE TREATMENT AGENT 有权
    表面处理剂

    公开(公告)号：US20160137765A1

    公开(公告)日：2016-05-19

    申请号：US14901334

    申请日：2014-06-18

    申请人： DAIKIN INDUSTRIES, LTD.

    发明人： Tetsuya UEHARA ,  Masahiro MIYAHARA ,  Masaki FUKUMORI ,  Kanako FUKUMOTO ,  Ikuo YAMAMOTO

    IPC分类号： C08F216/14 ,  D06M15/356 ,  D06M15/277 ,  C11D7/30

    CPC分类号： C08F216/1408 ,  C08F220/22 ,  C08G77/14 ,  C08G77/20 ,  C09D183/10 ,  C11D7/30 ,  D06M15/277 ,  D06M15/3568 ,  C08F220/30 ,  C08F2220/1891 ,  C08F230/08 ,  C08F220/34 ,  C08F222/06

    摘要： A fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH2═C(—X)—C(═O)—Y—Z—Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2═CQ11-C(═O)—O-Q12, and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2═CQ21-C(═O)—O-Q22. The fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent.

    摘要翻译： 具有（a）由式CH 2 = C（-X）-C（= O）-Y-Z-Rf表示的含氟单体的重复单元的含氟聚合物，（b）衍生自 由式CH2 = CQ11-C（ΟO）-O-Q12表示的含环烃基的丙烯酸酯单体和（c）衍生自含脂肪族烃基的丙烯酸酯单体的重复单元 由式CH2 = CQ21-C（ΟO）-O-Q22表示。 含氟聚合物通过在（d）含硅单体和含硅链转移剂中的一种或两种的存在下聚合来制备。

    SURFACE TREATMENT AGENT
    5.
    发明申请
    SURFACE TREATMENT AGENT 有权

    公开(公告)号：US20210130668A1

    公开(公告)日：2021-05-06

    申请号：US16473737

    申请日：2017-12-20

    申请人： DAIKIN INDUSTRIES, LTD.

    发明人： Ryousuke HARA ,  Rumi KAWABE ,  Masahiro MIYAHARA ,  Ikuo YAMAMOTO

    IPC分类号： C09K3/18 ,  C08F220/18 ,  C08F214/06 ,  C08F2/24 ,  C08K5/10

    摘要： A water- and oil-repellent agent that is an aqueous dispersion containing (A) a fluorine-free polymer having repeating units derived from a fluorine-free (meth)acrylic acid ester monomer, (B) a wax, (C) an aqueous medium, and (D) an emulsifier. The fluorine-free (meth)acrylic acid ester monomer is a compound represented by the formula CH2=CA11-C(═O)—O-A12 where A11 is a hydrogen atom or a methyl group and A12 is a linear or branched C18-30 hydrocarbon group. The emulsifier includes a sorbitan ester and another emulsifier, and the emulsifier has a hydrophilic-lipophilic balance (HLB) of 7.5 to 13.5. Also disclosed is a method of producing the water- and oil-repellent agent and a method of producing a treated substrate by applying the water- and oil-repellent agent to a substrate.