Method of stabilizing electrodes coated with mixed oxide
electrocatalysts during use in electrochemical cells
    2.
    发明授权
    Method of stabilizing electrodes coated with mixed oxide electrocatalysts during use in electrochemical cells 失效
    在电化学电池使用期间使用混合氧化物电催化剂涂覆电极的方法

    公开(公告)号:US4426269A

    公开(公告)日:1984-01-17

    申请号:US170668

    申请日:1979-10-22

    CPC分类号: C25B11/00

    摘要: An electrochemical cell with an electrode having deposited thereon an electrocatalyst which is a mixed oxide of nickel-molydenum, nickel-tungsten, cobalt-molydenum or cobalt-tungsten and containing an aqueous alkaline electrolyte comprising an aqueous solution of a molybdenum, vanadium or tungsten compound. The electrodes are preferably prepared by alternately coating an electrode core with a compound of nickel or cobalt, and with a compound of molydenum or tungsten, said compounds being capable of thermal decomposition to the corresponding oxides, heating the coated core at an elevated temperature to form a layer of the mixed oxides on the core and finally curing the core with the mixed oxide layer thereon in a reducing atmosphere at a temperature between 350.degree. C. and 600.degree. C. The cells are particularly suitable for use in the electrolysis of water or brine.

    摘要翻译: PCT No.PCT / GB79 / 00040 Sec。 371日期1979年10月22日 102(e)1979年10月22日日期PCT提交1979年3月5日PCT公布。 出版物WO79 / 00709 日本9月20日,1979年。一种具有电极的电化学电池,其上沉积有镍 - 钼,镍 - 钨,钴 - 钼或钴 - 钨的混合氧化物并含有碱性电解液的电催化剂,其包含水溶液 钼,钒或钨化合物。 电极优选通过用镍或钴的化合物交替地涂覆电极芯,并且与钼或钨的化合物交替地涂覆,所述化合物能够热分解成相应的氧化物,在升高的温度下加热涂覆的芯以形成 一层核心上的混合氧化物,并在350℃至600℃之间的温度下,在还原气氛中,将其上的混合氧化物层的核心固化。该电池特别适用于电解水或 盐水。

    Method of inhibiting formation of and breaking of mercury butter in
chlor-alkali cells
    3.
    发明授权
    Method of inhibiting formation of and breaking of mercury butter in chlor-alkali cells 失效
    抑制氯碱电池中汞黄油的形成和破坏的方法

    公开(公告)号:US4391681A

    公开(公告)日:1983-07-05

    申请号:US377606

    申请日:1982-05-13

    IPC分类号: C25B1/36 C25B1/16 C25B1/42

    CPC分类号: C25B1/36

    摘要: The present invention relates to a method of inhibiting the formation of and/or breaking of preformed mercury butter in chlor-alkali cells. The method comprises introducing at any one of the numerous stages of the electrolytic process an aqueous solution of a surfactant material which enables the interfacial tension of the sodium-amalgam interface to be increased to or maintained above a value of 180 dynes/cm. The surfactants may be extracts of decaying vegetation, solutions of carboxylic acids or chlorohydrocarbons. Extracts containing lignite or humic acids are most effective.

    摘要翻译: 本发明涉及一种在氯碱电池中抑制预形成的汞黄油的形成和/或断裂的方法。 该方法包括在电解过程的许多阶段的任何一个阶段引入表面活性剂材料的水溶液,使得能够将钠 - 汞齐界面的界面张力增加到180达因/厘米以上。 表面活性剂可以是腐烂植被,羧酸或氯代烃溶液的提取物。 含有褐煤或腐殖酸的提取物是最有效的。

    Electrodes and method of preparation thereof for use in electrochemical
cells
    4.
    发明授权
    Electrodes and method of preparation thereof for use in electrochemical cells 失效
    用于电化学电池的电极及其制备方法

    公开(公告)号:US4342792A

    公开(公告)日:1982-08-03

    申请号:US262415

    申请日:1981-05-11

    CPC分类号: C25B11/0478 H01M4/90

    摘要: This invention relates to novel electrodes and a method of preparation thereof for use in electrochemical cells. The novel electrodes contain a combination of electrocatalysts deposited on a metal substrate.The electrocatalysts are deposited from a homogeneous solution of the compounds of (a) at least one metal selected from iron, cobalt, manganese and nickel, (b) at least one metal selected from molybdenum, vanadium and tungsten, and (c) at least one rare earth metal of the lanthanide group having an atomic number of 57-71 inclusive, the metal compounds are decomposed to the oxides and the oxide coated substrate cured at elevated temperature in a reducing atmosphere. The electrodes thus produced can be used as an anode or as a cathode in fuel cells and in cells for the electrolysis of water or brines.

    摘要翻译: 本发明涉及新型电极及其制备方法,用于电化学电池。 新型电极包含沉积在金属基底上的电催化剂的组合。 所述电极催化剂由(a)选自铁,钴,锰和镍中的至少一种金属的化合物的均匀溶液沉积,(b)至少一种选自钼,钒和钨的金属,和(c)至少 镧系元素的一种稀土金属的原子序数为57-71,其中金属化合物分解成氧化物,氧化物涂覆的基底在还原气氛中在升高的温度下固化。 由此产生的电极可用作燃料电池中的阳极或阴极,以及用于电解水或盐水的电池。

    Electrochemical organic synthesis
    5.
    发明授权
    Electrochemical organic synthesis 失效
    电化学有机合成

    公开(公告)号:US4474652A

    公开(公告)日:1984-10-02

    申请号:US578665

    申请日:1984-02-09

    IPC分类号: C25B3/04 C25B1/00

    CPC分类号: C25B3/04

    摘要: The present invention relates to an electrochemical process for synthesizing carboxylic acids by reduction of gaseous oxides of carbon in which a gas transfer electrode is used as the cathode.The gas transfer electrodes are preferably used as hydrophobic gas transfer electrodes. In carrying out the process it is particularly preferred to use porous, hydrophobic gas transfer electrodes made from an electrocatalyst e.g. carbon, bound in a polymer such as polyethylene or polytetrafluoroethylene (PTFE). In the case of some reactions another electro-catalyst may be added to the carbon/polymer mixture.The process is particularly suited to producing acids such as formic acid and oxalic acid.

    摘要翻译: 本发明涉及通过还原其中使用气体转移电极作为阴极的碳的气态氧化物来合成羧酸的电化学方法。 气体转移电极优选用作疏水性气体转移电极。 在进行该方法时,特别优选使用由电催化剂制成的多孔疏水性气体转移电极。 碳,结合在聚合物如聚乙烯或聚四氟乙烯(PTFE)中。 在一些反应的情况下,可以向碳/聚合物混合物中加入另一种电催化剂。 该方法特别适用于生产酸如甲酸和草酸。

    Method of preparing active electrodes
    6.
    发明授权
    Method of preparing active electrodes 失效
    制备活性电极的方法

    公开(公告)号:US4358475A

    公开(公告)日:1982-11-09

    申请号:US242458

    申请日:1981-03-11

    CPC分类号: C25B11/0478 Y02E60/366

    摘要: This invention relates to a method of producing metal electrodes by treating a metal electrode substrate so as to coat the substrate surface with a homogeneous solution of the compounds of (i) at least one metal selected from a first group of iron, cobalt, nickel and manganese (ii) at least one other metal selected from a second group of molybdenum, tungsten and vanadium, each of which compound is capable of thermal decomposition to the corresponding metal oxide. The coated substrate is then thermally decomposed and the oxide-coated substrate is cured in a reducing atmosphere at elevated temperature. Substrates coated with Ni-Mo oxides are preferred. The electrodes thus produced exhibit very low overvoltage, are of high stability with respect to their activity and can be used as cathodes for the electrolysis of water or brine.

    摘要翻译: 本发明涉及一种金属电极的制造方法,其特征在于,通过处理金属电极基板,以使(i)选自第一组铁,钴,镍中的至少一种的金属和 锰(ii)选自第二组钼,钨和钒中的至少一种其它金属,其中每种化合物能够热分解成相应的金属氧化物。 然后将涂覆的基材热分解,并且氧化物涂覆的基材在升高的温度下在还原气氛中固化。 用Ni-Mo氧化物涂覆的基材是优选的。 由此产生的电极表现出非常低的过电压,相对于它们的活性具有高稳定性,并且可以用作电解水或盐水的阴极。

    Method of using mask film to form relief images
    8.
    发明授权
    Method of using mask film to form relief images 有权
    使用掩模膜形成浮雕图像的方法

    公开(公告)号:US08632944B2

    公开(公告)日:2014-01-21

    申请号:US13468376

    申请日:2012-05-10

    IPC分类号: G03C1/00

    摘要: A mask-forming film has a transparent layer between the imageable layer and the carrier sheet, which transparent layer has a refractive index that is lower (by at least 0.04) than that of the carrier sheet or any immediately adjacent layer between it and the carrier sheet. This lower refractive index layer modifies the path of incident radiation during mask image transfer so as to provide steeper shoulder angles in the relief image solid areas. This mask film is used to form a relief image such as in a flexographic printing plate.

    摘要翻译: 掩模形成膜在可成像层和载体片之间具有透明层,该透明​​层的折射率比载体片材或其与载体之间的任何紧邻层的折射率低至少(至少0.04) 片。 该低折射率层在掩模图像转印期间改变入射辐射的路径,以便在浮雕图像实心区域中提供较陡的肩部角度。 该掩模膜用于形成诸如柔版印刷版中的浮雕图像。

    Method and system for coordinated multiple cluster failover
    10.
    发明授权
    Method and system for coordinated multiple cluster failover 有权
    协调多集群故障切换的方法和系统

    公开(公告)号:US08429450B2

    公开(公告)日:2013-04-23

    申请号:US12790628

    申请日:2010-05-28

    IPC分类号: G06F11/00

    摘要: Hyperclusters are a cluster of clusters. Each cluster has associated with it one or more resource groups, and independent node failures within the clusters are handled by platform specific clustering software. The management of coordinated failovers across dependent or independent resources running on heterogeneous platforms is contemplated. A hypercluster manager running on all of the nodes in a cluster communicates with platform specific clustering software regarding any failure conditions, and utilizing a rule-based decision making system, determines actions to take on the node. A plug-in extends exit points definable in non-hypercluster clustering technologies. The failure notification is passed to other affected resource groups in the hypercluster.

    摘要翻译: 超集群是一组集群。 每个集群与一个或多个资源组相关联,并且集群内的独立节点故障由平台特定的集群软件处理。 预期在异构平台上运行的依赖或独立资源的协调故障转移管理。 在集群中的所有节点上运行的超群集管理器与平台特定的集群软件通信有关任何故障条件,并使用基于规则的决策系统来确定对节点采取的操作。 插件扩展了非超群集技术中可定义的出口点。 故障通知被传递到超集群中的其他受影响的资源组。