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1.发明授权Amide and hydroxymethyl functionalized polyethers as thermoplastic barrier resins 失效酰胺和羟甲基官能化聚醚作为热塑性阻隔树脂
公开(公告)号：US5218075A
公开(公告)日：1993-06-08
申请号：US836626
申请日：1992-02-13
IPC分类号： C07C235/34 , C07D303/24 , C08G59/62
CPC分类号： C07D303/24 , C07C235/34 , C08G59/621
摘要： Polyethers having improved barrier to oxygen are normally solid, thermoplastic polyethers having aromatic ether repeating units in their backbones and pendent hydroxyl moieties and pendent amido, N-substituted amido and/or hydroxyalkyl moieties. Such polyethers are prepared by reacting diglycidyl ethers of dihydric aromatic compounds such as the diglycidyl ether of bisphenol A with dihydric phenols having pendent amido, N-substituted amido and/or hydroxyalkyl moieties such as 2,2-bis(4-hydroxyphenyl)acetamide and 3,5-dihydroxybenzamide.
摘要翻译： 具有改善的对氧的屏障的聚醚通常是固体，其主链中具有芳族醚重复单元的热塑性聚醚和侧挂的羟基部分以及侧链酰胺基，N-取代的酰胺基和/或羟烷基部分。 这样的聚醚通过使二羟基芳族化合物的二缩水甘油醚如双酚A的二缩水甘油醚与具有侧酰氨基的二元酚，N-取代的酰氨基和/或羟烷基部分如2,2-双（4-羟基苯基）乙酰胺和 3,5-二羟基苯甲酰胺。
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2.发明授权Amide and hydroxymethyl functionalized polyethers as thermoplastic barrier resins 失效酰胺和羟甲基官能化聚醚作为热塑性阻隔树脂
公开(公告)号：US5115075A
公开(公告)日：1992-05-19
申请号：US520689
申请日：1990-05-08
IPC分类号： C07C235/34 , C07D303/24 , C08G59/62
CPC分类号： C08G59/621 , C07C235/34 , C07D303/24
摘要： Polyethers having improved barrier to oxygen are normally solid, thermoplastic polyethers having aromatic ether repeating units in their backbones and pendent hydroxyl moieties and pendent amido, N-substituted amido and/or hydroxyalkyl moieties. Such polyethers are prepared by reacting diglycidyl ethers of dihydric aromatic compounds such as diglycidyl ether of bisphenol A with dihydric phenols having pendent amido, N-substituted amido and/or hydroxyalkyl moieties such as 2,2-bis(4-hydroxyphenyl)acetamide and 3,5-dihydroxybenzamide.
摘要翻译： 具有改善的对氧的屏障的聚醚通常是固体，其主链中具有芳族醚重复单元的热塑性聚醚和侧挂的羟基部分以及侧链酰胺基，N-取代的酰胺基和/或羟烷基部分。 这样的聚醚通过使二羟基芳族化合物的二缩水甘油醚如双酚A的二缩水甘油醚与具有侧枝酰氨基的二元酚，N-取代的酰氨基和/或羟烷基部分如2,2-双（4-羟基苯基）乙酰胺和3 ，5-二羟基苯甲酰胺。
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3.发明授权
公开(公告)号：US5143998A
公开(公告)日：1992-09-01
申请号：US759288
申请日：1991-09-13
CPC分类号： C08G59/621 , C08G69/40
摘要： Hydroxy-functional poly(amide-ethers) are fabricated into articles such as rigid containers and flexible films exhibiting high barrier to oxygen transmission in both dry and moist environments. For example, a polymer prepared by reacting the diglycidyl ether of 4,4'-isopropylidene bisphenol with .alpha.,.alpha.'-bis(4-hydroxybenzamido)-1,3-xylene exhibits especially high barrier.
摘要翻译： 羟基官能的聚（酰胺 - 醚）被制成制品，例如刚性容器和在干燥和潮湿的环境中对透氧具有高阻隔性的柔性膜。 例如，通过使4,4'-异亚丙基双酚的二缩水甘油醚与α，α'-双（4-羟基苯甲酰氨基）-1,3-二甲苯反应而制备的聚合物显示出特别高的阻隔性。
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公开(公告)号：US5686551A
公开(公告)日：1997-11-11
申请号：US179029
申请日：1994-01-07
IPC分类号： C08G59/14 , C08G59/24 , C08G59/42 , C08G59/44 , C08G59/50 , C08G59/62 , C08G59/66 , C08G59/10 , C08G59/20 , C08G65/14
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/245 , C08G59/42 , C08G59/444 , C08G59/50 , C08G59/621
摘要： Thermoplastic hydroxy ether polymers containing inertly substituted or unsubstituted stilbene and ether linkages in the backbone chain and pendant hydroxyl moieties are prepared by reacting (a) an inertly substituted or unsubstituted dihydroxy-stilbene with (b) a diglycidyl ether and, optionally, (c) a difunctional monomer under conditions sufficient to cause the hydroxyl moieties to react with the epoxy moieties to form ether linkages and pendant hydroxyl moieties. The polymers exhibit excellent oxygen barrier properties and are useful in packaging oxygen-sensitive materials.
摘要翻译： 通过使（a）惰性取代或未取代的二羟基 - 二苯乙烯与（b）二缩水甘油醚和任选地（c）的二缩水甘油醚反应，制备在主链和侧羟基部分含惰性取代或未取代的二苯乙烯和醚键的热塑性羟基醚聚合物， 双官能单体在足以使羟基部分与环氧部分反应以形成醚键和侧羟基部分的条件下进行。 聚合物表现出优异的氧气阻隔性能，并且可用于包装氧敏感材料。
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公开(公告)号：US5962621A
公开(公告)日：1999-10-05
申请号：US69015
申请日：1998-04-28
CPC分类号： C08G63/42
摘要： A process for preparing a thermoplastic hydroxy-functionalized polyester comprises contacting a dicarboxylic acid or a mixture of dicarboxylic acids with a diepoxide in a given solvent in the presence of an end-capping agent and a catalyst under conditions sufficient to form the hydroxy-functionalized polyesters or polyethers.
摘要翻译： 制备热塑性羟基官能化聚酯的方法包括使二羧酸或二羧酸的混合物在给定的溶剂中，在封端剂和催化剂存在下，在足以形成羟基官能化聚酯的条件下， 或聚醚。
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公开(公告)号：US5401814A
公开(公告)日：1995-03-28
申请号：US135712
申请日：1993-10-13
CPC分类号： C08G59/688 , C08G59/621
摘要： Poly(hydroxy ethers) are prepared by reacting a dihydric phenol with a diepoxide in the presence of a catalyst selected from the group consisting of bis(trihydrocarbylphosphoranylidene)ammonium salt, bis[tris(dihydrocarbylamino)phosphoranylidene]ammonium salt, and tetrakis[tris(dihydrocarbylamino)phosphoranylideneamino]phosphonium salt. The reaction between the dihydric phenol and the diepoxide is conducted in an ether or hydroxy ether solvent at a temperature sufficiently high to produce a poly(hydroxy ether). Polymers prepared by the new process are more highly branched than those produced by known methods.
摘要翻译： 聚（羟基醚）通过二选苯酚与二环氧化物在选自双（三烃基亚正膦基）铵盐，双[三（二烃基氨基）亚正膦基]铵盐和四[三 二烃基氨基）正膦亚基氨基]鏻盐。 二羟基酚和二环氧化物之间的反应在足够高的温度下在醚或羟基醚溶剂中进行以产生聚（羟基醚）。 通过新方法制备的聚合物比通过已知方法制备的聚合物分枝得多。
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公开(公告)号：US5246751A
公开(公告)日：1993-09-21
申请号：US884673
申请日：1992-05-18
IPC分类号： C07D209/48 , C07D487/04 , C08G59/62
CPC分类号： C07D209/48 , C07D487/04 , C08G59/621 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： Hydroxy-functionalized polyethers having imide groups in their backbones are prepared by contacting an imide-containing bisphenol with the diglycidyl ether of the same or another bisphenol under conditions sufficient to cause the nucleophilic phenolic hydroxyl moieties to react with epoxy groups. These poly(hydroxy ether imides) possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rates of less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day) and high heat resistance (i.e., T.sub.g above 120.degree. C.). These polymers are suitable for use in the manufacture of packaging materials with high barrier to oxygen.
摘要翻译： 在其主链中具有酰亚胺基团的羟基官能化聚醚通过使含酰亚胺的双酚与相同或另一双酚的二缩水甘油醚在足以使亲核性酚羟基部分与环氧基团反应的条件下接触来制备。 这些聚（羟基醚酰亚胺）具有高的透氧阻隔性（即氧传输速率小于10.0立方厘米/ 100英寸-2天）和高耐热性（即Tg高于120℃）的组合。 ）。 这些聚合物适用于制造具有高氧阻隔性的包装材料。
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8.发明授权Hydroxy-functional poly(ether sulfonamides) as thermoplastic barrier resins 失效作为热塑性阻隔树脂的羟基官能聚（醚磺酰胺）
公开(公告)号：US5149768A
公开(公告)日：1992-09-22
申请号：US718684
申请日：1991-06-21
申请人： Jerry E. White , Anthony P. Haag , R. Garth Pews
发明人： Jerry E. White , Anthony P. Haag , R. Garth Pews
CPC分类号： C08G59/444 , C09J2459/00 , C09J2463/00 , Y10T428/1379 , Y10T428/1383 , Y10T428/31511
摘要： Hydroxy-functional poly(ether sulfonamides) prepared by polymerizing an N,N'-dialkyl or N,N'-diaryldisulfonamide with a diepoxide in the presence of a suitable catalyst exhibit high barrier properties. These are suitable for use in the manufacture of articles such as rigid containers and flexible films exhibiting high barrier to oxygen.
摘要翻译： 通过在合适的催化剂存在下通过用二环氧化物聚合N，N'-二烷基或N，N'-二芳基二磺酰胺制备的羟基官能的聚（醚磺酰胺）显示出高阻隔性。 这些适用于制造诸如刚性容器和表现出高的阻氧性的柔性膜的制品。
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公开(公告)号：US6011111A
公开(公告)日：2000-01-04
申请号：US138300
申请日：1993-10-18
CPC分类号： C08K7/04
摘要： A thermoplastic composite is prepared by applying a hydroxy-phenoxyether polymer onto the surface of reinforcing fibers or by the in-situ polymerization of mixtures of diepoxides and difunctional species in the presence of reinforcing fibers. The composites can be molded into shaped articles useful for structural materials and parts by conventional thermoforming or other fabrication techniques.
摘要翻译： 通过在增强纤维的表面上施加羟基 - 苯氧基醚聚合物或通过在增强纤维的存在下二环氧化物和双官能物质的混合物的原位聚合来制备热塑性复合材料。 复合材料可以通过常规热成型或其他制造技术模制成用于结构材料和部件的成型制品。
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公开(公告)号：US5731094A
公开(公告)日：1998-03-24
申请号：US735284
申请日：1996-10-22
CPC分类号： B32B27/36 , B32B27/34 , Y10T428/31725 , Y10T428/31739 , Y10T428/31786
摘要： A laminate structure comprises one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be prepared by coextruding one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be fabricated into articles using conventional fabrication techniques such as compression molding, injection molding, blow molding, extrusion, solvent casting, calendering and thermoforming.
摘要翻译： 层压结构包括一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物。 层压结构可以通过共挤出一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物来制备。 层压结构可以使用常规的制造技术如压塑，注塑，吹塑，挤出，溶剂浇铸，压延和热成型制成制品。
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