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    IRREGULARLY SHAPED NON-SPHERICAL SUPPORTED CATALYST, AND A PROCESS FOR HYDROCONVERTING HEAVY OIL FRACTIONS
    3.
    发明申请
    IRREGULARLY SHAPED NON-SPHERICAL SUPPORTED CATALYST, AND A PROCESS FOR HYDROCONVERTING HEAVY OIL FRACTIONS 审中-公开
    非正式形状的非球形载体催化剂，以及用于氢化重油油脂的方法

    公开(公告)号：US20090166260A1

    公开(公告)日：2009-07-02

    申请号：US12158594

    申请日：2006-12-14

    申请人： Stephane Kressmann ,  Magalie Roy-Auberger ,  Jean Luc Le Loarer ,  Denis Guillaume ,  Jean Francois Chapat

    发明人： Stephane Kressmann ,  Magalie Roy-Auberger ,  Jean Luc Le Loarer ,  Denis Guillaume ,  Jean Francois Chapat

    IPC分类号： C10G45/06

    CPC分类号： B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/0063 ,  B01J37/10 ,  C10G45/04 ,  C10G45/08

    摘要： The present invention concerns a catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape of which results from a crushing step, and containing at least one catalytic metal or a compound of a catalytic metal from group VIB and/or group VIII (groups 8, 9 and 10 of the new periodic table notation), optionally at least one doping element selected from the group constituted by phosphorus, boron and silicon (or silica which does not form part of that which may be contained in the selected support) and halogens, said catalyst essentially being constituted by a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate generally being oriented radially with respect to each other and with respect to the centre of the agglomerate. The specific shape of the catalyst improves its performance when using it for hydroconverting/hydrotreating heavy metal-containing hydrocarbon feeds.The invention also concerns the use of said catalyst alone or as a mixture in a fixed bed or ebullated bed reactor.

    摘要翻译： 本发明涉及用于加氢处理和/或加氢转化含重金属的烃进料的催化剂，所述催化剂包括主要是不规则的和非球形的氧化铝基附聚物形式的载体，其特定形状来自破碎步骤，以及 含有至少一种催化金属或来自VIB族组和/或第VIII族催化金属的化合物（新周期表符号的第8,9和10族），任选的至少一种选自磷， 硼和硅（或二氧化硅，其不构成可以包含在所选择的载体中的硅的一部分）和卤素，所述催化剂基本上由多个并列聚集体组成，每个聚集体由多个针状血小板形成，每个附聚物的血小板 通常相对于彼此和相对于附聚物的中心径向取向。 当将其用于加氢转化/加氢处理含重金属的烃进料时，催化剂的具体形状改善了其性能。 本发明还涉及在固定床或沸腾床反应器中单独或作为混合物使用所述催化剂。

    Intensive hydrofining of petroleum fractions
    4.
    发明授权
    Intensive hydrofining of petroleum fractions 失效
    石油馏分的加氢精制

    公开(公告)号：US5954950A

    公开(公告)日：1999-09-21

    申请号：US524631

    申请日：1995-09-07

    申请人： Frederic Morel ,  Pierre Trambouze ,  Jean-Paul Euzen ,  Stephane Kressmann

    发明人： Frederic Morel ,  Pierre Trambouze ,  Jean-Paul Euzen ,  Stephane Kressmann

    IPC分类号： C10G49/00 ,  C10G25/00

    CPC分类号： C10G49/002

    摘要： Intensive hydrofining of petroleum fractions wherein an at least partly together with hydrogen circulate in a given direction, in at least one reactor containing at least one fixed bed of a hydrofining catalyst in solid form, is characterized in that the reactor is equipped with at least one inlet pipe for the mixture of the petroleum fraction and hydrogen and at least one outlet pipe for the resultant hydrofined petroleum fraction, and that at least one static mixer is positioned upstream from said outlet of the hydrofined petroleum fraction.

    摘要翻译： 石油馏分的强化加氢精制，其中至少部分与氢在给定方向循环，在至少一个含有至少一个固体床形式的加氢精制催化剂固定床的反应器中，其特征在于反应器配备有至少一种 用于石油馏分和氢气的混合物的入口管和用于所得加氢精制石油馏分的至少一个出口管，并且至少一个静态混合器位于加氢精炼馏分的出口的上游。

    Method and processing equipment for hydrocarbons and for separation of the phases produced by said processing
    6.
    发明申请
    Method and processing equipment for hydrocarbons and for separation of the phases produced by said processing 审中-公开
    用于碳氢化合物的方法和加工设备以及用于分离由所述处理产生的相

    公开(公告)号：US20050075527A1

    公开(公告)日：2005-04-07

    申请号：US10373197

    申请日：2003-02-26

    申请人： Mathieu Pinault ,  Frederic Hoffmann ,  Stephane Kressmann ,  Pierre Porot ,  John Duddy

    发明人： Mathieu Pinault ,  Frederic Hoffmann ,  Stephane Kressmann ,  Pierre Porot ,  John Duddy

    IPC分类号： B01D19/00 ,  C10G49/12 ,  C07C7/00 ,  B01J10/00

    CPC分类号： B01D19/0042 ,  C10G49/12

    摘要： Method for processing hydrocarbons comprising at least two processing chambers and means for separating the liquid and gaseous fractions contained in the polyphasic mixture produced in the first processing chamber, said mixture coming from a zone (700) where a batch of liquid hydrocarbons, a gaseous batch and solid particles come into contact, said method comprising separation of liquid and gaseous phases located in the chamber. Equipment comprising: a) At least a first chamber comprising means inside said chamber for separating gaseous and liquid fractions coming from said zone, b) means for conveying said liquid fraction toward a second chamber, c) a second chamber comprising a second contact zone and means of introducing, into said zone, a gaseous batch and a liquid batch comprising at least a portion of the liquid fraction coming from the first chamber.

    摘要翻译： 用于处理包含至少两个处理室的烃的方法和用于分离包含在第一处理室中产生的多相混合物中的液相和气态馏分的装置，所述混合物来自区域（700），其中一批液体烃，气态批料 并且固体颗粒接触，所述方法包括分离位于室中的液相和气相。 一种设备，包括：a）至少一个第一室，包括在所述室内的装置，用于分离来自所述区域的气态和液态馏分; b）用于将所述液体馏分输送到第二室的装置，c）第二室，包括第二接触区和 在所述区域中引入气态批料和包含至少一部分来自第一室的液体馏分的液体批料的装置。

    Multi-step catalytic process for conversion of a heavy hydrocarbon fraction
    8.
    发明授权
    Multi-step catalytic process for conversion of a heavy hydrocarbon fraction 失效
    用于转化重质烃馏分的多步催化方法

    公开(公告)号：US6017441A

    公开(公告)日：2000-01-25

    申请号：US942047

    申请日：1997-10-01

    申请人： Frederic Morel ,  Gerard Heinrich ,  Stephane Kressmann ,  Alain Billon ,  Jean-Luc Duplan ,  Thierry Chapus

    发明人： Frederic Morel ,  Gerard Heinrich ,  Stephane Kressmann ,  Alain Billon ,  Jean-Luc Duplan ,  Thierry Chapus

    IPC分类号： C10G67/04 ,  C10G69/04 ,  C10G21/00

    CPC分类号： C10G67/0454 ,  C10G69/04

    摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor. At least a portion of the hydroconverted liquid effluent is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; and at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, an atmospheric distillate and a heavier liquid fraction of the hydrotreated feed are recovered by atmospheric distillation separation, said section comprising at least one three-phase reactor containing at least one ebullated bed hvdroconversion catalyst operating in liquid and gas riser mode, the reactor comprising at least one means for extracting catalyst from the reactor and at least one means for adding fresh catalyst to the reactor.

    摘要翻译： 用于转化重质烃馏分的方法包括在氢的存在下在加氢转化段中处理烃进料，该部分包含至少一个含有至少一个沸腾床加氢转化催化剂的三相反应器，其以液体和气体提升管模式运行， 所述反应器包括至少一种用于从所述反应器除去催化剂的装置和用于将新鲜催化剂加入到所述反应器中的至少一种装置。 将至少一部分加氢转化的液体流出物送入常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空蒸馏物和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 并且至少一部分脱沥青烃切割被送到加氢处理部分，通过常压蒸馏分离回收加氢处理的进料的气体馏分，常压馏出物和较重的液体馏分，所述部分包含至少一个三相 反应器包含至少一种以液体和气体提升管模式运行的沸腾床转化催化剂，该反应器包括至少一种用于从反应器中提取催化剂的装置和至少一种用于向反应器中加入新鲜催化剂的装置。

    Multi-step process for conversion of a petroleum residue
    9.
    发明授权
    Multi-step process for conversion of a petroleum residue 失效
    用于转化石油残渣的多步法

    公开(公告)号：US6007703A

    公开(公告)日：1999-12-28

    申请号：US942901

    申请日：1997-10-01

    申请人： Frederic Morel ,  Stephane Kressmann ,  Jean-Luc Duplan ,  Alain Billon ,  Thierry Chapus ,  Gerard Heinrich

    发明人： Frederic Morel ,  Stephane Kressmann ,  Jean-Luc Duplan ,  Alain Billon ,  Thierry Chapus ,  Gerard Heinrich

    IPC分类号： C10G67/04 ,  C10G69/04 ,  C10G45/00

    CPC分类号： C10G69/04 ,  C10G67/0454

    摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydrodemetallization section, the section comprising at least one fixed bed hydrodemetallization catalyst. At least a portion of the hydrotreated liquid effluent from step a) is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; and at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, a fuel fraction and a heavier liquid fraction of the hydrotreated feed are recovered, said section comprising at least one three-phase reactor containing at least one ebullated bed hydrotreatment catalyst operating in liquid and gas riser mode, the reactor comprising at least one means for removing catalyst from the reactor and at least one means for adding fresh catalyst to the reactor.

    摘要翻译： 用于转化重质烃馏分的方法包括在加氢脱金属部分中处理烃进料，该部分包含至少一个固定床加氢脱金属催化剂。 将来自步骤a）的加氢处理的液体流出物的至少一部分送至常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空馏分和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 并且至少一部分脱沥青烃切割被送到加氢处理部分，从该馏分回收加氢处理的进料的气体馏分，燃料馏分和较重的液体馏分，所述部分包含至少一个至少包含一个三相反应器 一种以液体和气体提升管模式运行的沸腾床加氢处理催化剂，该反应器包括至少一种用于从反应器中除去催化剂的装置和至少一种用于向反应器中加入新鲜催化剂的装置。

    Integrated SDA and ebullated-bed process
    10.
    发明申请
    Integrated SDA and ebullated-bed process 有权
    综合SDA和沸腾床过程

    公开(公告)号：US20060118463A1

    公开(公告)日：2006-06-08

    申请号：US11005062

    申请日：2004-12-06

    申请人： James Colyar ,  Stephane Kressmann ,  Christophe Gueret

    发明人： James Colyar ,  Stephane Kressmann ,  Christophe Gueret

    IPC分类号： C10G67/04

    CPC分类号： C10G67/00 ,  C10G67/0463 ,  C10G67/049 ,  C10G69/02 ,  C10G2400/02 ,  C10G2400/04

    摘要： This invention relates to a novel integrated method for economically processing vacuum residue from heavy crude oils. This is accomplished by utilizing a solvent deasphalter (SDA) in the first step of the process with a C3/C4/C5 solvent such that the DAO product can thereafter be processed in a classic fixed-bed hydrotreater or hydrocracker. The SDA feed also includes recycled stripper bottoms containing unconverted residue/asphaltenes from a downstream steam stripper unit. The asphaltenes from the SDA are sent to an ebullated-bed reactor for conversion of the residue and asphaltenes. Residue conversion in the range of 60-80% is achieved and asphaltene conversion is in the range of 50-70%. The overall residue conversion, with the DAO product considered non-residue, is in the range of 80 W %-90 W % and significantly higher than could be achieved without utilizing the present invention.

    摘要翻译： 本发明涉及一种用于从重质原油经济处理减压渣油的新型综合方法。 这是通过在第一步骤中利用溶剂脱沥青（SDA）与C 3 N 3 C 4 C 5 C 5溶剂 使得DAO产品此后可以在经典的固定床加氢处理器或加氢裂化器中加工。 SDA进料还包括来自下游蒸汽汽提塔单元的含有未转化的残余物/沥青质的再循环汽提塔底物。 来自SDA的沥青质被送入沸腾床反应器以转化残渣和沥青质。 实现了60-80％范围内的残渣转化率，沥青质转化率在50-70％的范围内。 考虑到非残留物的DAO产物的总残留物转化率在80W％-90W％的范围内，并且显着高于在不利用本发明的情况下可以实现的。