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    IRREGULARLY SHAPED NON-SPHERICAL SUPPORTED CATALYST, AND A PROCESS FOR HYDROCONVERTING HEAVY OIL FRACTIONS
    1.
    发明申请
    IRREGULARLY SHAPED NON-SPHERICAL SUPPORTED CATALYST, AND A PROCESS FOR HYDROCONVERTING HEAVY OIL FRACTIONS 审中-公开
    非正式形状的非球形载体催化剂，以及用于氢化重油油脂的方法

    公开(公告)号：US20090166260A1

    公开(公告)日：2009-07-02

    申请号：US12158594

    申请日：2006-12-14

    申请人： Stephane Kressmann ,  Magalie Roy-Auberger ,  Jean Luc Le Loarer ,  Denis Guillaume ,  Jean Francois Chapat

    发明人： Stephane Kressmann ,  Magalie Roy-Auberger ,  Jean Luc Le Loarer ,  Denis Guillaume ,  Jean Francois Chapat

    IPC分类号： C10G45/06

    CPC分类号： B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/0063 ,  B01J37/10 ,  C10G45/04 ,  C10G45/08

    摘要： The present invention concerns a catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape of which results from a crushing step, and containing at least one catalytic metal or a compound of a catalytic metal from group VIB and/or group VIII (groups 8, 9 and 10 of the new periodic table notation), optionally at least one doping element selected from the group constituted by phosphorus, boron and silicon (or silica which does not form part of that which may be contained in the selected support) and halogens, said catalyst essentially being constituted by a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate generally being oriented radially with respect to each other and with respect to the centre of the agglomerate. The specific shape of the catalyst improves its performance when using it for hydroconverting/hydrotreating heavy metal-containing hydrocarbon feeds.The invention also concerns the use of said catalyst alone or as a mixture in a fixed bed or ebullated bed reactor.

    摘要翻译： 本发明涉及用于加氢处理和/或加氢转化含重金属的烃进料的催化剂，所述催化剂包括主要是不规则的和非球形的氧化铝基附聚物形式的载体，其特定形状来自破碎步骤，以及 含有至少一种催化金属或来自VIB族组和/或第VIII族催化金属的化合物（新周期表符号的第8,9和10族），任选的至少一种选自磷， 硼和硅（或二氧化硅，其不构成可以包含在所选择的载体中的硅的一部分）和卤素，所述催化剂基本上由多个并列聚集体组成，每个聚集体由多个针状血小板形成，每个附聚物的血小板 通常相对于彼此和相对于附聚物的中心径向取向。 当将其用于加氢转化/加氢处理含重金属的烃进料时，催化剂的具体形状改善了其性能。 本发明还涉及在固定床或沸腾床反应器中单独或作为混合物使用所述催化剂。

    PROCESS FOR SLURRY PHASE HYDROCONVERSION OF HEAVY HYDROCARBON FEEDS AND/OR COAL USING A SUPPORTED CATALYST
    4.
    发明申请
    PROCESS FOR SLURRY PHASE HYDROCONVERSION OF HEAVY HYDROCARBON FEEDS AND/OR COAL USING A SUPPORTED CATALYST 有权
    使用支持的催化剂的重油相进料和/或煤的浆液相变过程

    公开(公告)号：US20080149531A1

    公开(公告)日：2008-06-26

    申请号：US11961132

    申请日：2007-12-20

    申请人： Magalie Roy-Auberger ,  Denis Guillaume

    发明人： Magalie Roy-Auberger ,  Denis Guillaume

    IPC分类号： C10G47/02

    CPC分类号： B01J37/0063 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J27/19 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/10 ,  C10G45/08 ,  C10G49/04 ,  C10G2300/301

    摘要： The invention concerns a process for converting heavy feeds carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalyst comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or VIII supported on alumina, the pore structure of which is composed of a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially oriented with respect to the others and with respect to the centre of the agglomerate, said catalyst having an irregular and non-spherical shape and being mainly in the form of fragments, obtained using a process including the following steps: a) granulation starting from an active alumina powder having a low crystallinity and/or amorphous structure, to obtain agglomerates in the form of beads; b) maturing in a moist atmosphere between 60° C. and 100° C. then drying said beads; c) sieving to recover a fraction of said beads; d) crushing said fraction; e) calcining at least a portion of said crushed fraction at a temperature in the range 250° C. to 900° C.; f) impregnating with acid and hydrothermal treatment at a temperature in the range 80° C. to 250° C.; g) drying then calcining at a temperature in the range 500° C. to 1100° C. h) depositing at least one catalytic metal or compound of a catalytic metal from group VIB and/or group VIII by impregnation. The process of the invention employs a catalyst with a specific pore texture, shape and granulometry, resulting in improved performances.

    摘要翻译： 本发明涉及一种在氢气存在下，在含有至少一种催化金属或催化金属化合物的催化剂存在下，在淤浆反应器中进行重质进料的方法，所述催化剂金属或载体在氧化铝上的VIB族和/或VIII族的催化剂金属化合物 其孔结构由多个并列聚集体组成，每个团聚体由多个针状血小板形成，每个附聚物的血小板通常相对于其它凝聚块大致径向取向，并且相对于附聚物的中心，所述催化剂具有 不规则的和非球形的并且主要以片段的形式，使用包括以下步骤的方法获得：a）从具有低结晶度和/或无定形结构的活性氧化铝粉末开始制粒，以获得形式的附聚物 的珠子 b）在60℃至100℃之间的潮湿环境中熟化，然后干燥所述珠粒; c）筛分以回收所述珠粒的一部分; d）破碎所述级分; e）在250℃至900℃的温度范围内煅烧所述粉碎部分的至少一部分; f）在80℃至250℃的温度下用酸浸渍和水热处理; g）干燥，然后在500℃至1100℃的温度下煅烧。h）通过浸渍沉积至少一种催化金属或来自VIB族和/或VIII族的催化金属的化合物。 本发明的方法采用具有特定孔结构，形状和粒度的催化剂，从而提高了性能。

    Process for slurry phase hydroconversion of heavy hydrocarbon feeds and/or coal using a supported catalyst
    6.
    发明授权
    Process for slurry phase hydroconversion of heavy hydrocarbon feeds and/or coal using a supported catalyst 有权
    使用负载型催化剂对重质烃进料和/或煤的浆料相加氢转化的方法

    公开(公告)号：US07807044B2

    公开(公告)日：2010-10-05

    申请号：US11961132

    申请日：2007-12-20

    申请人： Magalie Roy-Auberger ,  Denis Guillaume

    发明人： Magalie Roy-Auberger ,  Denis Guillaume

    IPC分类号： C10G47/04

    CPC分类号： B01J37/0063 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J27/19 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/10 ,  C10G45/08 ,  C10G49/04 ,  C10G2300/301

    摘要： The invention concerns a process for converting heavy feeds carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalyst comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or VIII supported on alumina, the pore structure of which is composed of a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially oriented with respect to the others and with respect to the center of the agglomerate, the catalyst having an irregular and nonspherical shape and being mainly in the form of fragments. The process of the invention employs a catalyst with a specific pore texture, shape and granulometry, resulting in improved performances.

    摘要翻译： 本发明涉及一种在氢气存在下，在含有至少一种催化金属或催化金属化合物的催化剂存在下，在淤浆反应器中进行重质进料的方法，所述催化剂金属或载体在氧化铝上的VIB族和/或VIII族的催化剂金属化合物 其孔结构由多个并列聚集体组成，每个团聚体由多个针状血小板形成，每个附聚物的血小板通常相对于其它凝聚块大致径向取向，并且相对于附聚物的中心，催化剂具有 形状不规则和非球形，主要以片段的形式。 本发明的方法采用具有特定孔结构，形状和粒度的催化剂，从而提高了性能。

    Catalyst and process for hydrocracking hydrocarbon-containing feedstocks
    9.
    发明授权
    Catalyst and process for hydrocracking hydrocarbon-containing feedstocks 有权
    用于加氢裂化含烃原料的催化剂和方法

    公开(公告)号：US07270738B2

    公开(公告)日：2007-09-18

    申请号：US10696561

    申请日：2003-10-30

    申请人： Patrick Euzen ,  Carole Bobin ,  Magalie Roy-Auberger ,  Eric Benazzi ,  Patrick Bourges ,  Christophe Gueret

    发明人： Patrick Euzen ,  Carole Bobin ,  Magalie Roy-Auberger ,  Eric Benazzi ,  Patrick Bourges ,  Christophe Gueret

    IPC分类号： C01G47/00 ,  C01G45/00 ,  C01G17/00 ,  B01J23/00 ,  B01J21/00

    CPC分类号： B01J35/10 ,  B01J21/12 ,  B01J23/24 ,  B01J23/42 ,  B01J23/74 ,  B01J23/85 ,  B01J23/888 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G47/12 ,  C10G47/14 ,  C10G47/16 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2300/70

    摘要： This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 Å, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 500 Å, of less than 0.01 ml/g, an X diffraction diagram contains at least the main lines that are characteristic of at least one of the transition aluminas contained in the group that consists of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.

    摘要翻译： 本发明涉及硅铝基板，催化剂以及使用它们的加氢裂化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和非沸石二氧化硅 - 氧化铝基底物的含氢量超过5的氢脱氢元件 重量百分比和小于或等于95重量％的二氧化硅（SiO 2/2），并具有以下特征：通过水银孔率法测量的平均孔径包含在20和140之间，a 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，包括在 100和550m 2 / g，通过水银孔率法测量的孔体积包含在直径大于140埃，小于0.1ml / g的孔中，孔体积由 包含在直径大于160埃，小于0的孔中的水银孔率法。 1毫升/克，通过水银孔率测定法测量的孔体积，直径大于200埃，小于0.1毫升/克，通过水银孔率法测定的孔体积，包含在直径为 大于500埃，小于0.01ml / g，X衍射图至少包含由α，rho，chi，eta等组成的组中包含的至少一种过渡氧化铝的特征的主线， γ，κ，θ和δ氧化铝。