Process for esterifying or transesterifying side chains in polymers
    1.
    发明授权
    Process for esterifying or transesterifying side chains in polymers 失效
    在聚合物中酯化或酯交换侧链的方法

    公开(公告)号:US08273555B2

    公开(公告)日:2012-09-25

    申请号:US12095068

    申请日:2006-11-24

    摘要: Provided is a process for esterifying or transesterifying side chains in polymers, which involves esterifying or transesterifying the carboxyl group having the R4 radical of a copolymer obtained by polymerizing a (meth)acrylate of formula (I), and a monomer of formula (II): wherein R1 and R3 are independently H or CH3, R2 and R4 are independently H or an alkyl radical which is optionally substituted by functional groups such as acryloyl, ether, amino, epoxy, halogen or sulfonic acid groups, and n is from 1 to 40, with an alcohol in the presence of an enzyme which catalyzes the esterifying or transesterifying. Further provided is the esterified or transesterified polymer product and its use.

    摘要翻译: 本发明提供聚合物中侧链的酯化或酯交换的方法,该方法包括使通过聚合式(I)的(甲基)丙烯酸酯得到的共聚物的R4基团的羧基和式(II)的单体酯化或酯交换, :其中R 1和R 3独立地是H或CH 3,R 2和R 4独立地是H或任选被官能团如丙烯酰基,醚,氨基,环氧基,卤素或磺酸基取代的烷基,n是1〜 40,在催化酯化或酯交换的酶存在下用醇。 进一步提供酯化或酯交换聚合物产品及其用途。

    SOUND DEADENER COMPOSITION WITH EMULSION POLYMER STABILIZED BY PROTECTIVE COLLOIDS
    2.
    发明申请
    SOUND DEADENER COMPOSITION WITH EMULSION POLYMER STABILIZED BY PROTECTIVE COLLOIDS 有权
    具有由保护胶体稳定的乳液聚合物的声衰减剂组合物

    公开(公告)号:US20120027941A1

    公开(公告)日:2012-02-02

    申请号:US13186637

    申请日:2011-07-20

    IPC分类号: E04B1/82 B05D3/02

    摘要: A description is given of the use of a polymer dispersion for preparing sound deadener compositions, the polymer dispersion being obtainable by emulsion polymerization of free-radically polymerizable monomers in the presence of at least one protective colloid which is an amphiphilic graft copolymer. Preferred protective colloids have a polyalkylene oxide main chain and vinyl ester-comprising side chains. A description is also given of corresponding sound deadener compositions which comprise the polymer dispersion, and of a method for damping oscillations or vibrations of vehicle components.

    摘要翻译: 给出了聚合物分散体用于制备声音消音组合物的用途,聚合物分散体可通过在至少一种作为两亲性接枝共聚物的保护胶体存在下的可自由基聚合单体的乳液聚合获得。 优选的保护胶体具有聚环氧烷主链和含乙烯基酯的侧链。 还给出了包含聚合物分散体的对应的消声器组合物的描述,以及用于阻止车辆部件的振荡或振动的方法。

    Method for Applying Dissolved or Dispersed Substances
    4.
    发明申请
    Method for Applying Dissolved or Dispersed Substances 审中-公开
    溶解或分散物质的应用方法

    公开(公告)号:US20080193648A1

    公开(公告)日:2008-08-14

    申请号:US11911355

    申请日:2006-04-11

    IPC分类号: C09D11/02 C09D11/10 B05D5/06

    CPC分类号: C09D11/30

    摘要: A process for applying dissolved or dispersed substances (A) from a formulation in a polar medium, preferably aqueous formulation, to substrates (B) using at least one auxiliary substance (C) by a formulation in a polar medium comprising dissolved or dispersed substance (A) and at least one auxiliary substance (C) being applied to substrate (B), wherein the pKa value of auxiliary substance (C) is higher than that of substrate (B) and of dissolved or dispersed substance (A) and wherein auxiliary substance (C) is selected from three-dimensional amphoteric core-shell polymers.

    摘要翻译: 一种使用至少一种辅助物质(C)通过包含溶解或分散物质的极性介质中的制剂将溶解或分散的物质(A)从极性介质,优选水性制剂中的制剂施用于底物(B)的方法 A)和至少一种辅助物质(C)施加到基底(B)上,其中辅助物质(C)的pK aα值高于底物(B)的pKα值,溶解或 分散物质(A),其中辅助物质(C)选自三维两性核 - 壳聚合物。

    Use of cationic polycondensation products as additives for fixing colours and/or inhibiting the running of colours, for washing products and washing aftertreatment products
    6.
    发明授权
    Use of cationic polycondensation products as additives for fixing colours and/or inhibiting the running of colours, for washing products and washing aftertreatment products 有权
    使用阳离子缩聚产物作为固色和/或抑制颜色运行的添加剂,用于洗涤产品和洗涤后处理产品

    公开(公告)号:US07919451B2

    公开(公告)日:2011-04-05

    申请号:US11909396

    申请日:2006-03-21

    IPC分类号: C11D3/37

    摘要: The invention relates to the use of cationic polycondensation products as additives for fixing colors and/or inhibiting the running of colors, for washing products and washing aftertreatment products. Said cationic polycondensation products can be produced by the condensation of (A1) non-cyclic amines obtained by the reaction of (A1 a) mono(N,N-dialkylaminoalkyl)amines with (A1 b) bifunctional compounds selected from the group containing urea, thiourea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids, and aliphatic and aromatic diisocyanates, in a molar ratio 1.2:1 to 2.1:1, or (A2) mixtures of non-cyclic amines (A1) and cyclic amines (A3) in a molar ratio 10:1 to 1:10 with (B) bifunctional compounds selected from the group containing alkylene dihalogenides, dihalogen alkyl ethers, halomethyl oxiranes, and bisepoxides, in a molar ratio (B) to (A1) or (B) to (A2) from 0.6:1 to 1.3:1.

    摘要翻译: 本发明涉及阳离子缩聚产物作为用于固色和/或抑制颜色运行,用于洗涤产品和洗涤后处理产品的添加剂的用途。 所述阳离子缩聚产物可以通过(A1a)单(N,N-二烷基氨基烷基)胺与(A1b)双官能化合物的反应得到的(A1)非环状胺缩合而制备,所述(A1b) 硫代脲,碳酸二烷基酯,脂族和芳族二羧酸以及脂族和芳族二异氰酸酯,摩尔比为1.2:1至2.1:1,或(A2)非环胺(A1)和环胺(A3)的混合物 (B)至(A1)或(B)至(B)至(B)的摩尔比为(B)选自含有亚烷基二卤化物,二卤代烷基醚,卤代甲基环氧乙烷和双环氧化物的双官能化合物,摩尔比为10:1至1:10; A2)为0.6:1至1.3:1。

    PROCESS AND POLYMER FOR PREVENTING Ba/Sr SCALE WITH A DETECTABLE PHOSPHORUS FUNCTIONALITY
    7.
    发明申请
    PROCESS AND POLYMER FOR PREVENTING Ba/Sr SCALE WITH A DETECTABLE PHOSPHORUS FUNCTIONALITY 审中-公开
    用于防止具有可检测磷光功能的Ba / Sr量规的方法和聚合物

    公开(公告)号:US20100171070A1

    公开(公告)日:2010-07-08

    申请号:US12520642

    申请日:2007-12-17

    摘要: The present invention relates to a process for preparing a phosphorus-containing polymer, comprising the steps of (i) copolymerizing at least (a) monoethylenically unsaturated dicarboxylic anhydrides having from 4 to 6 carbon atoms with (b) olefins of the formula CH2═C(R1)R2 where R1 is H or CH3 and R2 is H, CH3, C2H5 or phenyl; (ii) reacting the polymer formed in step (i) with at least one primary or secondary phosphorus-containing amine or a phosphorus-containing alcohol and (iii) at least partly ring-opening the remaining anhydride groups. The invention further relates to phosphorus-containing polymers obtainable from this process, and to processes for preventing Ba/Sr scale with the aid of the polymer.

    摘要翻译: 本发明涉及一种制备含磷聚合物的方法,包括以下步骤:(i)至少(a)具有4至6个碳原子的单烯属不饱和二羧酸酐与(b)式CH 2 = C (R1)R2,其中R1是H或CH3,R2是H,CH3,C2H5或苯基; (ⅱ)使步骤(ⅰ)中形成的聚合物与至少一种一级或二级含磷胺或含磷醇反应,和(iii)至少部分打开剩余的酸酐基团。 本发明还涉及可从该方法获得的含磷聚合物,以及借助聚合物防止Ba / Sr垢的方法。

    Use of Cationic Polycondensation Products as Additives for Fixing Colours and/or Inhibiting the Running of Colours, for Washing Products and Washing Aftertreatment Products
    8.
    发明申请
    Use of Cationic Polycondensation Products as Additives for Fixing Colours and/or Inhibiting the Running of Colours, for Washing Products and Washing Aftertreatment Products 有权
    使用阳离子缩聚产物作为添加剂固定颜色和/或抑制颜色运行,用于洗涤产品和洗涤后处理产品

    公开(公告)号:US20090005286A1

    公开(公告)日:2009-01-01

    申请号:US11909396

    申请日:2006-03-21

    IPC分类号: C11D3/30 C08G69/26

    摘要: The invention relates to the use of cationic polycondensation products as additives for fixing colours and/or inhibiting the running of colours, for washing products and washing aftertreatment products. Said cationic polycondensation products can be produced by the condensation of (A1) non-cyclic amines obtained by the reaction of (A1 a) mono(N,N-dialkylaminoalkyl)amines with (A1 b) bifunctional compounds selected from the group containing urea, thiourea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids, and aliphatic and aromatic diisocyanates, in a molar ratio 1.2:1 to 2.1:1, or (A2) mixtures of non-cyclic amines (A1) and cyclic amines (A3) in a molar ratio 10:1 to 1:10 with (B) bifunctional compounds selected from the group containing alkylene dihalogenides, dihalogen alkyl ethers, halomethyl oxiranes, and bisepoxides, in a molar ratio (B) to (A1) or (B) to (A2) from 0.6:1 to 1.3:1.

    摘要翻译: 本发明涉及阳离子缩聚产物作为用于固色和/或抑制颜色运行,用于洗涤产品和洗涤后处理产品的添加剂的用途。 所述阳离子缩聚产物可以通过(A1a)单(N,N-二烷基氨基烷基)胺与(A1b)双官能化合物的反应得到的(A1)非环状胺缩合而制备,所述(A1b) 硫代脲,碳酸二烷基酯,脂族和芳族二羧酸以及脂族和芳族二异氰酸酯,摩尔比为1.2:1至2.1:1,或(A2)非环胺(A1)和环胺(A3)的混合物 (B)至(A1)或(B)至(B)至(B)的摩尔比为(B)选自含有亚烷基二卤化物,二卤代烷基醚,卤代甲基环氧乙烷和双环氧化物的双官能化合物,摩尔比为10:1至1:10; A2)为0.6:1至1.3:1。