摘要:
The present invention relates to a process for preparing a phosphorus-containing polymer, comprising the steps of (i) copolymerizing at least (a) monoethylenically unsaturated dicarboxylic anhydrides having from 4 to 6 carbon atoms with (b) olefins of the formula CH2═C(R1)R2 where R1 is H or CH3 and R2 is H, CH3, C2H5 or phenyl; (ii) reacting the polymer formed in step (i) with at least one primary or secondary phosphorus-containing amine or a phosphorus-containing alcohol and (iii) at least partly ring-opening the remaining anhydride groups. The invention further relates to phosphorus-containing polymers obtainable from this process, and to processes for preventing Ba/Sr scale with the aid of the polymer.
摘要翻译:本发明涉及一种制备含磷聚合物的方法,包括以下步骤:(i)至少(a)具有4至6个碳原子的单烯属不饱和二羧酸酐与(b)式CH 2 = C (R1)R2,其中R1是H或CH3,R2是H,CH3,C2H5或苯基; (ⅱ)使步骤(ⅰ)中形成的聚合物与至少一种一级或二级含磷胺或含磷醇反应,和(iii)至少部分打开剩余的酸酐基团。 本发明还涉及可从该方法获得的含磷聚合物,以及借助聚合物防止Ba / Sr垢的方法。
摘要:
Water-soluble, hydrophobically associating copolymer comprising a monoethylenically unsaturated, water-soluble, surface-active monomer (a), and a monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a). The copolymer is prepared in the presence of a nonpolymerizable surfactant and has marked thickening properties in aqueous systems.
摘要:
Surfactants of the general formula R1—X where R1 is an aliphatic C17H35-alkyl radical and X is a hydrophilic group, and the mean degree of branching of the R1 radical is from 2.8 to 3.7. Mixtures which comprise such surfactants and the use of such surfactants and of mixtures thereof for tertiary mineral oil extraction.
摘要:
The invention relates to a process for mineral oil production by means of Winsor Type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least one ionic surfactant of the general formula R1—O—(CH2C(CH3)HO)m(CH2CH2O)n—XY−M+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to ionic surfactants of the general formula.
摘要:
Use of copolymers comprising alkylene oxide units, which copolymers comprise incorporated randomly or blockwise by polymerization (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of the formula I where the variables have the following meaning: R1 hydrogen or methyl; R2 a chemical bond or unbranched or branched C1-C6-alkylene; R3 identical or different unbranched or branched C2-C4-alkylene radicals; R4 unbranched or branched C1-C6-alkyl; n 3 to 50, as additive to phosphate- and/or phosphonate-comprising aqueous systems in industrial technical plants.
摘要:
Compositions comprising: (A) at least one surfactant of the general formula (I) (R1—[(O—(CH2)2)x1(O—CH(CH3)CH2)x2]O)kP(═O)(OH)3-k (I) wherein the sequence of the alkyleneoxy units is arbitrary, each R1 independently represents a moiety selected from the group consisting of linear and branched C12-C22-alkyl, C12-C22-alkenyl, C12-C22-alkynyl, (C11-C21-alkyl)carbonyl, (C11-C21-alkenyl)carbonyl and (C11-C21-alkynyl)carbonyl, k represents 1 or 2 and x1 and x2 each independently represent an integer of 0 to 20, the sum of x1 and x2 being a number of 1 to 20; and (B) at least one thickener comprising at least two hydrophobic groups R2 which are linked to one another via a bridging hydrophilic group (α), wherein each R2, independently represents a moiety selected from the group consisting of C8-C32-alkyl, C8-C32-alkenyl, C8-C32-alkynyl, cycloalkyl, aryl, and aryl-C1-C32-alkyl, which in each case may have up to 3 hydroxyl substituents; wherein the composition has a pH which is viscosity-dependent.
摘要:
The use of nondendrimeric hyperbranched polyesters and/or polyesteramides which comprise alkyl- and/or alkenyl-substituted succinic acid units as demulsifiers for splitting oil-water emulsions, especially crude oil emulsions, and also nondendrimeric hyperbranched polyesters or polyesteramides which comprise alkyl- and/or alkenyl-substituted succinic acid units.
摘要:
A process for preparing a paraffin inhibitor formulation comprising (a) preparing a mixture comprising a waxy paraffin inhibitor component having a melting point of >0° C. and an emulsifier component, wherein the mixture is prepared at a first temperature range above the melting point of the waxy paraffin inhibitor; (b) adding water to the mixture to produce an o/w emulsion; and (c) cooling the o/w emulsion to a temperature in a second temperature range which is below the melting point of the waxy paraffin inhibitor. The mixture prepared in step (a) may further comprise water to produce a w/o emulsion, the water being present in a proportion by weight that is lower than the sum of the proportions by weight of the paraffin inhibitor and the emulsifier component. The process may further comprise (d) adding an at least partially water-miscible organic solvent in which the paraffin inhibitor is insoluble.
摘要:
Compositions comprising: (A) at least one surfactant of the general formula (I) (R1—[(O—(CH2)2)x1(O—CH(CH3)CH2)x2]O)kP(═O)(OH)3-k (I) wherein the sequence of the alkyleneoxy units is arbitrary, each R1 independently represents a moiety selected from the group consisting of linear and branched C12-C22-alkyl, C12-C22-alkenyl, C12-C22-alkynyl, (C11-C21-alkyl)carbonyl, (C11-C21-alkenyl)carbonyl and (C11-C21-alkynyl)carbonyl, k represents 1 or 2 and x1 and x2 each independently represent an integer of 0 to 20, the sum of x1 and x2 being a number of 1 to 20; and (B) at least one thickener comprising at least two hydrophobic groups R2 which are linked to one another via a bridging hydrophilic group (α), wherein each R2, independently represents a moiety selected from the group consisting of C8-C32-alkyl, C8-C32-alkenyl, C8-C32-alkynyl, cycloalkyl, aryl, and aryl-C1-C32-alkyl, which in each case may have up to 3 hydroxyl substituents; wherein the composition has a pH which is viscosity-dependent.