公开(公告)号：US10112887B2

公开(公告)日：2018-10-30

申请号：US15286975

申请日：2016-10-06

申请人： Dmitri Goussev ,  Denis Spasyuk ,  Samantha Smith

发明人： Dmitri Goussev ,  Denis Spasyuk ,  Samantha Smith

IPC分类号： C07C67/40 ,  C07C323/25 ,  C07C5/03 ,  C07C209/52 ,  C01B3/26 ,  C07C5/08 ,  C07C45/00 ,  C07C29/147 ,  C07C41/18 ,  C07C67/00 ,  B01J31/18 ,  B01J31/22 ,  B01J31/20 ,  B01J31/24 ,  C01B3/02 ,  C01B3/04 ,  C07F15/00

摘要： The present application discloses novel amino-sulfide metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

公开(公告)号：US20170073298A1

公开(公告)日：2017-03-16

申请号：US15286975

申请日：2016-10-06

申请人： Dmitri Goussev ,  Denis Spasyuk ,  Samantha Smith

发明人： Dmitri Goussev ,  Denis Spasyuk ,  Samantha Smith

IPC分类号： C07C67/40 ,  C07F15/00 ,  B01J31/18 ,  C07C5/03 ,  B01J31/22 ,  B01J31/24

CPC分类号： C07C67/40 ,  B01J31/1805 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/22 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2231/763 ,  B01J2531/0238 ,  B01J2531/821 ,  B01J2531/825 ,  C01B3/02 ,  C01B3/04 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/1064 ,  C07C5/03 ,  C07C5/08 ,  C07C29/147 ,  C07C41/18 ,  C07C45/002 ,  C07C67/00 ,  C07C209/52 ,  C07C323/25 ,  C07C2531/22 ,  C07C2531/24 ,  C07F15/0026 ,  C07F15/0046 ,  C07F15/0053 ,  Y02E60/364 ,  C07C211/45 ,  C07C9/06 ,  C07C9/15 ,  C07C15/073 ,  C07C47/06

摘要： The present application discloses novel amino-sulfide metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

摘要翻译： 本申请公开了用于有机化学合成的新型氨基硫化物金属催化剂，包括不饱和化合物的氢化（还原）或底物脱氢。 氢化底物化合物的范围包括酯，内酯，油和脂肪，产生作为反应产物的醇，二醇和三醇。 目前应用的催化剂可用于在无溶剂条件下催化氢化反应。 本发明的催化剂还允许氢化进行而不加入碱，并且可以代替使用主要组分的氢化物的常规还原方法。 此外，本申请的催化剂可以在均匀和/或无接受条件下催化脱氢反应。 因此，本文提供的催化剂可用于显着降低成本并改善各种化学品的制造方法的环境特征。

公开(公告)号：US20150202609A1

公开(公告)日：2015-07-23

申请号：US14426049

申请日：2013-09-04

申请人： Dmitri GOUSSEV ,  Denis SPASYUK ,  Samantha SMITH

发明人： Dmitri Goussev ,  Denis Spasyuk ,  Samantha Smith

IPC分类号： B01J31/22 ,  B01J31/20 ,  C01B3/02 ,  C07C41/18 ,  C07F15/00 ,  C07C67/00 ,  C07C29/147 ,  C07C209/52 ,  B01J31/24 ,  C01B3/04

CPC分类号： C07C67/40 ,  B01J31/1805 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/22 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2231/763 ,  B01J2531/0238 ,  B01J2531/821 ,  B01J2531/825 ,  C01B3/02 ,  C01B3/04 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/1064 ,  C07C5/03 ,  C07C5/08 ,  C07C29/147 ,  C07C41/18 ,  C07C45/002 ,  C07C67/00 ,  C07C209/52 ,  C07C323/25 ,  C07C2531/22 ,  C07C2531/24 ,  C07F15/0026 ,  C07F15/0046 ,  C07F15/0053 ,  Y02E60/364 ,  C07C211/45 ,  C07C9/06 ,  C07C9/15 ,  C07C15/073 ,  C07C47/06

摘要： The present application discloses novel amino-sulfide metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

摘要翻译： 本申请公开了用于有机化学合成的新型氨基硫化物金属催化剂，包括不饱和化合物的氢化（还原）或底物脱氢。 氢化底物化合物的范围包括酯，内酯，油和脂肪，产生作为反应产物的醇，二醇和三醇。 目前应用的催化剂可用于在无溶剂条件下催化氢化反应。 本发明的催化剂还允许氢化进行而不加入碱，并且可以代替使用主要组分的氢化物的常规还原方法。 此外，本申请的催化剂可以在均匀和/或无接受条件下催化脱氢反应。 因此，本文提供的催化剂可用于显着降低成本并改善各种化学品的制造方法的环境特征。

公开(公告)号：US20050058821A1

公开(公告)日：2005-03-17

申请号：US10661908

申请日：2003-09-12

申请人： Samantha Smith ,  Gene Shipman ,  Robert Floyd ,  Harold Freemyer ,  Steven Hamrock ,  Michael Yandrasits ,  David Walton

发明人： Samantha Smith ,  Gene Shipman ,  Robert Floyd ,  Harold Freemyer ,  Steven Hamrock ,  Michael Yandrasits ,  David Walton

IPC分类号： B01D67/00 ,  B01D71/34 ,  B29C55/00 ,  B32B3/26 ,  B32B5/14 ,  B32B9/00 ,  C08J5/22 ,  C08J9/28 ,  H01M4/02 ,  H01M8/10 ,  B32B35/00

CPC分类号： H01M8/1044 ,  B01D67/0009 ,  B01D67/0011 ,  B01D67/0016 ,  B01D67/0027 ,  B01D69/141 ,  B01D71/34 ,  B01D2323/46 ,  B01D2325/022 ,  B01D2325/20 ,  B01D2325/24 ,  C08J5/2281 ,  C08J2327/16 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/106 ,  H01M8/1079 ,  H01M8/1083 ,  Y02E60/521 ,  Y02P70/56 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/249953 ,  Y10T428/249958 ,  Y10T428/249959 ,  Y10T428/249978 ,  Y10T428/249987 ,  Y10T428/3154

摘要： Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.

摘要翻译： 成型微孔制品由聚偏氟乙烯（PVDF）和使用热诱导相分离（TIPS）工艺的成核剂制备。 成形的微孔制品以至少约1.1至1.0的拉伸比在至少一个方向上取向。 成型制品还可以包含稀释剂，三乙酸甘油酯。 成形的微孔制品也可以具有填充足量的离子导电电解质的微孔，以允许膜用作离子导电膜。 制造微孔制品的方法包括熔融共混聚偏二氟乙烯，成核剂和三乙酸甘油酯的步骤; 形成混合物的成型制品; 冷却成型制品以引起聚偏二氟乙烯的结晶和聚偏二氟乙烯和甘油三乙酸酯的相分离; 并且以至少约1.1至1.0的拉伸比在至少一个方向上拉伸成形制品。

公开(公告)号：US20080113242A1

公开(公告)日：2008-05-15

申请号：US12014435

申请日：2008-01-15

申请人： Samantha Smith ,  Gene Shipman ,  Robert Floyd ,  Harold Feemyer ,  Steven Hamrock ,  Michael Yandrasits ,  David Walton

发明人： Samantha Smith ,  Gene Shipman ,  Robert Floyd ,  Harold Feemyer ,  Steven Hamrock ,  Michael Yandrasits ,  David Walton

IPC分类号： H01M8/10 ,  H01M4/00 ,  H01M14/00 ,  H01M2/16

CPC分类号： H01M8/1044 ,  B01D67/0009 ,  B01D67/0011 ,  B01D67/0016 ,  B01D67/0027 ,  B01D69/141 ,  B01D71/34 ,  B01D2323/46 ,  B01D2325/022 ,  B01D2325/20 ,  B01D2325/24 ,  C08J5/2281 ,  C08J2327/16 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/106 ,  H01M8/1079 ,  H01M8/1083 ,  Y02E60/521 ,  Y02P70/56 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/249953 ,  Y10T428/249958 ,  Y10T428/249959 ,  Y10T428/249978 ,  Y10T428/249987 ,  Y10T428/3154

摘要： Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.

摘要翻译： 成型微孔制品由聚偏氟乙烯（PVDF）和使用热诱导相分离（TIPS）工艺的成核剂制备。 成形的微孔制品以至少约1.1至1.0的拉伸比在至少一个方向上取向。 成型制品还可以包含稀释剂，三乙酸甘油酯。 成形的微孔制品也可以具有填充足量的离子导电电解质的微孔，以允许膜用作离子导电膜。 制造微孔制品的方法包括熔融共混聚偏二氟乙烯，成核剂和三乙酸甘油酯的步骤; 形成混合物的成型制品; 冷却成型制品以引起聚偏二氟乙烯的结晶和聚偏二氟乙烯和甘油三乙酸酯的相分离; 并且以至少约1.1至1.0的拉伸比在至少一个方向上拉伸成形制品。

公开(公告)号：US20060057370A1

公开(公告)日：2006-03-16

申请号：US10940520

申请日：2004-09-14

申请人： Thierry Pasquier ,  Samantha Smith

发明人： Thierry Pasquier ,  Samantha Smith

IPC分类号： B32B7/12

CPC分类号： C08J5/127 ,  C09J7/21 ,  C09J7/22 ,  C09J7/32 ,  C09J7/38 ,  C09J2201/28 ,  C09J2201/614 ,  C09J2203/334 ,  C09J2400/283 ,  C09J2429/00 ,  C09J2431/00 ,  G09F3/10 ,  Y10T428/283 ,  Y10T428/2878

摘要： Labels, labeled containers and method of labeling a container wherein the label comprises a pre-applied adhesive that is reactivated with moistenable.

摘要翻译： 标签，标记的容器和标记容器的方法，其中标签包括预先施加的粘合剂，其被再润湿可湿润。