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公开(公告)号：US4398049A
公开(公告)日：1983-08-09
申请号：US425347
申请日：1982-09-28
IPC分类号： B01J31/04 , B01J31/00 , C07B61/00 , C07C1/00 , C07C2/26 , C07C2/30 , C07C11/02 , C07C51/00 , C07C51/41 , C07C53/126 , C07C53/16 , C07C53/18 , C07C53/19 , C07C53/21 , C07C67/00 , C07F15/04 , C08F4/60 , C08F4/70 , C08F10/00 , C07C3/12 , C07C3/18 , C07C3/21
CPC分类号： C07C53/16 , C07C2/30 , C07C53/126 , C07C53/18 , C07C53/19 , C07C53/21 , C07C2531/04 , C07C2531/14
摘要： A catalyst composition is manufactured by admixing a hydrocarbyl aluminum halide of a nickel compound of the formula (R.sub.1 COO)(R.sub.2 COO)Ni, where R.sub.1 is hydrocarbyl with at least 5 carbon atoms and R.sub.2 is haloalkyl of 1-3 carbon atoms. Olefins such as ethylene, propylene and butenes can be oligomerized, for example, dimerized and trimerized, with the above catalyst composition.
摘要翻译： 催化剂组合物通过将式（R1COO）（R2COO）Ni的镍化合物的烃基铝卤化物与其中R1是烃基与至少5个碳原子并且R2是1-3个碳原子的卤代烷基混合来制备。 烯烃如乙烯，丙烯和丁烯可以用上述催化剂组合物低聚，例如二聚和三聚。
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公开(公告)号：US4366087A
公开(公告)日：1982-12-28
申请号：US248582
申请日：1981-03-27
IPC分类号： B01J31/04 , B01J31/00 , C07B61/00 , C07C1/00 , C07C2/26 , C07C2/30 , C07C11/02 , C07C51/00 , C07C51/41 , C07C53/126 , C07C53/16 , C07C53/18 , C07C53/19 , C07C53/21 , C07C67/00 , C07F15/04 , C08F4/60 , C08F4/70 , C08F10/00 , B01J31/14
CPC分类号： C07C53/16 , C07C2/30 , C07C53/126 , C07C53/18 , C07C53/19 , C07C53/21 , C07C2531/04 , C07C2531/14
摘要： A catalyst composition is manufactured by admixing a hydrocarbyl aluminum halide with a nickel compound of the formula (R.sub.1 COO) (R.sub.2 COO) Ni, wherein R.sub.1 is hydrocarbyl of at least 5 carbon atoms and R.sub.2 is haloalkyl of 1-3 carbon atoms. Olefins such as ethylene, propylene and butenes can be oligomerized, for example, dimerized and trimerized, with the above catalyst composition.
摘要翻译： 通过将烃基卤化铝与式（R1COO）（R2COO）Ni的镍化合物混合制备催化剂组合物，其中R1是至少5个碳原子的烃基，R2是1-3个碳原子的卤代烷基。 烯烃如乙烯，丙烯和丁烯可以用上述催化剂组合物低聚，例如二聚和三聚。
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公开(公告)号：US4316851A
公开(公告)日：1982-02-23
申请号：US183792
申请日：1980-09-03
IPC分类号： B01J31/04 , B01J31/00 , C07B61/00 , C07C1/00 , C07C2/26 , C07C2/30 , C07C11/02 , C07C51/00 , C07C51/41 , C07C53/126 , C07C53/16 , C07C53/18 , C07C53/19 , C07C53/21 , C07C67/00 , C07F15/04 , C08F4/60 , C08F4/70 , C08F10/00 , C09F7/00 , C11C3/00
CPC分类号： C07C53/16 , C07C2/30 , C07C53/126 , C07C53/18 , C07C53/19 , C07C53/21 , C07C2531/04 , C07C2531/14
摘要： Nickel compounds of the formula (R.sub.1 COO) (R.sub.2 COO) Ni, where R.sub.1 is hydrocarbyl of at least 5 carbon atoms and R.sub.2 is haloalkyl of 1-3 carbon atoms, are manufactured from the corresponding acids R.sub.1 COOH and R.sub.2 COOH or salts thereof. The resultant nickel compounds are soluble in hydrocarbons and can be used in admixture with organoaluminum compounds as constituents of catalytic compositions; olefins can be oligomerized, for example, dimerized and trimerized, therewith.
摘要翻译： 其中R1为至少5个碳原子的烃基，R2为1-3个碳原子的卤代烷基的式（R1COO）（R2COO）Ni的镍化合物由相应的酸R1COOH和R2COOH或其盐制备。 所得的镍化合物可溶于烃类，可与有机铝化合物混合使用，作为催化组合物的成分; 烯烃可以被低聚，例如二聚和三聚。
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4.发明授权Process for selective dimerization of propylene principally into branched dimers 有权主要将丙烯选择性二聚化为支化二聚体的方法公开(公告)号：US06501001B2
公开(公告)日：2002-12-31
申请号：US09775555
申请日：2001-02-05
IPC分类号： C07C226
CPC分类号： C07C2/36 , C07C2527/053 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/22 , C07C2531/24 , C07C11/107
摘要： In order to carry out selective dimerization of propylene principally into branched dimers, a catalytic composition resulting from at least partly dissolving a nickel compound mixed or complexed with a tertiary phosphine carrying a functional group is used in a medium resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide and optionally at least one organometallic aluminum compound.
摘要翻译： 为了将丙烯主要进行支化二聚体的选择性二聚反应，将至少部分溶解与携带有官能团的叔膦混合或络合的镍化合物的催化剂组合物用于混合至少一种季铵 卤化物和/或至少一种卤化鏻，至少一种卤化铝和任选的至少一种有机金属铝化合物。
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5.发明授权Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins 有权用于二烯化，共二聚和低聚烯烃的催化组合物公开(公告)号：US06706657B2
公开(公告)日：2004-03-16
申请号：US09775556
申请日：2001-02-05
IPC分类号： B01J3100
CPC分类号： C07C2/32 , B01J31/0284 , B01J31/0288 , B01J31/14 , B01J31/143 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2409 , B01J2231/20 , B01J2531/847 , C07C2/26 , C07C2527/128 , C07C2531/22
摘要： A catalytic composition comprising at least one nickel compound mixed or complexed with at least one tertiary phosphine or a phosphite carrying a functional group, at least partly dissolved in a non-aqueous medium with an ionic nature resulting from bringing at least one aluminum halide into contact with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, is useful for dimerizing, co-dimerizing and oligomerizing olefins. Functional groups include, but are not limited to, an amine, a cyclic amine, a nitrogen-containing heterocycle, an ester, an acid, an alcohol, a quaternary ammonium, a quaternary phosphonium, a sulfonium, a sulfonate or a phosphonate group.
摘要翻译： 一种催化组合物，其包含与至少一种叔膦或携带官能团的亚磷酸酯混合或络合的至少一种镍化合物，至少部分地溶解在具有离子性质的非水介质中，所述非水介质使至少一种卤化铝接触 与至少一种季铵卤化物和/或至少一种季鏻卤化物可用于烯烃的二聚，共二聚和低聚。 官能团包括但不限于胺，环胺，含氮杂环，酯，酸，醇，季铵，季鏻，锍，磺酸盐或膦酸酯基团。
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6.发明授权Process for the production of light alpha olefins by oligomerization of ethylene 失效通过乙烯低聚生产轻质α-烯烃的方法
公开(公告)号：US5345023A
公开(公告)日：1994-09-06
申请号：US88508
申请日：1993-07-09
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/38 , Y02P20/52
摘要： Process for oligomerizing ethylene into light alpha olefins, mainly 1-butene, 1-hexene, 1-octene and 1-decene, in which the ethylene is contacted with a catalyst obtained by mixing a zirconium compound with an organic compound chosen from within the class of acetals and ketals and with a chlorine or bromine-containing compound of aluminum hydrocarbyl.
摘要翻译： 将乙烯低聚成轻质α-烯烃，主要是1-丁烯，1-己烯，1-辛烯和1-癸烯的方法，其中乙烯与通过混合锆化合物与选自类中的有机化合物获得的催化剂接触 的缩醛和缩酮以及含有氯或溴的铝盐化合物。
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7.发明授权Non-aqueous liquid composition with an ionic character and its use as a solvent 失效非水性液体组合物，具有离子性，并作为溶剂使用
公开(公告)号：US5104840A
公开(公告)日：1992-04-14
申请号：US672236
申请日：1991-03-20
申请人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/24 , B01J31/28 , C07B61/00 , C07C2/32 , C07C11/02 , C07C15/12 , C07F5/06 , C08F10/00
CPC分类号： B01J31/24 , B01J31/0284 , B01J31/0288 , B01J31/1805 , C07F5/06 , C07F5/064 , C08F10/00 , B01J2231/20 , B01J2531/847 , B01J31/0239 , B01J31/0268 , B01J31/2234
摘要： A non-aqueous liquid composition with an ionic character resulting from the contacting of at least one alkylaluminum dihalide with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, said composition being liquid below 80.degree. C., for example, between -70.degree. and +40.degree. C., is useful as a solvent of catalysts for the dimerization, codimerization and oligomerization of olefins.
摘要翻译： 由至少一种烷基铝二卤化物与至少一种季铵卤化物和/或至少一种季鏻卤化物接触而产生的具有离子性质的非水性液体组合物，所述组合物在低于80℃的液体下，例如， 在-70℃至+ 40℃之间，可用作烯烃二聚，共聚和低聚的催化剂溶剂。
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8.发明授权Process for homologating alcohols through the intermediate production of ketals with cobalt carbonyl complexes as catalysts 失效通过羰基配合物作为催化剂通过中间体生产缩酮来使醇同步化的方法
公开(公告)号：US4511743A
公开(公告)日：1985-04-16
申请号：US548737
申请日：1983-11-04
申请人： Claude Seite , Dominique Commereuc , Yves Chauvin
发明人： Claude Seite , Dominique Commereuc , Yves Chauvin
IPC分类号： C07C29/14 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C41/50 , C07C45/00 , C07C45/49 , C07C45/51 , C07C67/00 , C07C27/20
CPC分类号： C07C41/50 , C07C29/141 , C07C45/49 , C07C45/515
摘要： Process for the homologation of an alcohol wherein a ketal of the alcohol is reacted with hydrogen and carbon monoxide in the presence of a cobalt carbonyl complex and the resultant product is hydrolyzed to yield the aldehyde with one more carbon atom.
摘要翻译： 醇的同系化方法，其中醇的缩酮在羰基钴络合物的存在下与氢气和一氧化碳反应，并将所得产物水解以产生具有多一个碳原子的醛。
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公开(公告)号：US4005047A
公开(公告)日：1977-01-25
申请号：US547032
申请日：1975-02-04
CPC分类号： C08G61/08
摘要： New catalytic composition of improved activity in the process of polymerizing cycloolefins, comprising a carbonyl compound or a carbonyl-metal-carbenic compound of molybdenum or tungsten and titanium tetrachloride, said composition being preferably subjected to an irradiation with rays of a wave length from 180 to 700 nanometers during or before use.
摘要翻译： 在包含钼或钨和四氯化钛的羰基化合物或羰基 - 金属 - 碳化合物的环烯烃聚合过程中改进的活性的新催化组合物，所述组合物优选经受从180至 使用期间或之前700纳米。
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10.发明授权Catalyst for the production of light alpha olefins by oligomerization of ethylene 失效用于通过乙烯低聚生产轻质α-烯烃的催化剂
公开(公告)号：US5496783A
公开(公告)日：1996-03-05
申请号：US253017
申请日：1994-06-02
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/38 , Y02P20/52
摘要： Process for oligomerizing ethylene into light alpha olefins, mainly 1-butene, 1-hexene, 1-octene and 1-decene, in which the ethylene is contacted with a catalyst obtained by mixing a zirconium compound with an organic compound chosen from within the class of acetals and ketals and with a chlorine or bromine-containing compound of aluminium hydrocarbyl.
摘要翻译： 将乙烯低聚成轻质α-烯烃，主要是1-丁烯，1-己烯，1-辛烯和1-癸烯的方法，其中乙烯与通过混合锆化合物与选自类中的有机化合物获得的催化剂接触 的缩醛和缩酮以及含有氯或溴的铝盐化合物。
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