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公开(公告)号：US11753555B2
公开(公告)日：2023-09-12
申请号：US18005062
申请日：2021-10-11
发明人： Patrick J. Fryfogle , Julie Cook , Tim Mitchell , Yihan Liu , Rebecca Beeson , Miroslav Janco , Mikayla T. Miller , Brad J. Phillips
IPC分类号： C09D7/65 , C09D7/20 , C09D183/06 , C09D4/06 , C09D145/00
CPC分类号： C09D7/65 , C09D4/06 , C09D145/00
摘要： A dispersion contains: (a) a polyorganosiloxane with at least 90 mole % dimethyl D units and viscosity of one kPa*s or more dispersed as 0.5-20 micrometer particles; (b) a condensation product of: (i) a polysiloxane resin (Mw of 4,000-50,000) with composition: (R3SiO1/2)a(SiO4/2)b(ZO1/2)c where a is 0.30-0.60, b is 0.40-0.70, c is 0.05-0.20, a+b is one, R is selected from hydrogen, C1−30 alkyl groups and aryl groups, and Z is selected from H, and C18 alkyls; and (ii) a polyoxyalkylene polymer (Mn of 4,500-50,000) with composition: A—O—(C2H4O)e(C3H6O)p—A′ where e/p is 1-9, A and A′ are selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl groups and at least one of A and A′ is H; (c) non-aqueous fluid carrier miscible with (a); and (d) monoterpene; the weight-ratio of (c) to (b) is 0.5-1; weight-ratio of (b) and (c) to (a) is 0.01-0.50; and the composition contains below one ppm aromatic solvent.
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公开(公告)号：US20200237639A1
公开(公告)日：2020-07-30
申请号：US16624152
申请日：2018-06-15
发明人： Thomas D. Bekemeier , Patrick J. Fryfogle , Gary M. Wieber , Kimmai T. Nguyen , Zhi Li , Julie Cook , Jason Vogel
摘要： This invention relates to a cosmetic composition comprising: (A) a film forming composition that can produce a tack free surface comprising: (I) a hydrosilylation reaction product of: (a) a silicone resin having the formula: (R1R22SiO1/2)w(R1R3SiO2/2)x(R1R2SiO3/2)y(SiO4/2)z wherein R2 is a C1 to C10 hydrocarbon group free of aliphatic unsaturation, R1 is R2 or an alkenyl group, w is from 0.3 to 0.6, x is from 0.0 to 0.2, y is 0, z is from 0.4 to 0.7, w+x+y+z=1.0, and w+z is from 0.85 to 1.0, with the proviso that the silicone resin (a) has at least two silicon-bonded alkenyl groups per number average molecule; (b) a polyether compound having the formula: R3O(C2H4O)c(C3H6O)dR3 wherein R3 is a monovalent unsaturated aliphatic hydrocarbon M group containing 2 to 12 carbon atoms, c is from 0 to 50, d is from 0 to 50, and the value of c+d is greater than zero; (c) an SiH functional organopolysiloxane having the general formula: HcR3-cSiO(R2SiO)a(RHSiO)bSiR3-cHc wherein c is 0 or 1, R can be identical or different and is a monovalent, optionally substituted hydrocarbon group with 1 to 18 carbon atoms per molecule, a and b are integers, with the proviso that the sum of a+b is 0 to 300, and wherein the organopolysiloxane contains SiH in amounts from 0.01 to 0.4 wt %; (d) a hydrosilylation catalyst; and (e) carrier solvent; and (II) a silicone resin having the formula: (R43SiO1/2)u(SiO4/2)v wherein R4 is a C1 to C10 to do hydrocarbon group free of aliphatic unsaturation, u is from 0.3 to 0.6, v is from 0.4 to 0.7, and the value of u+v is 1.0; and (B) at least one cosmetic ingredient.
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公开(公告)号：US20210261818A1
公开(公告)日：2021-08-26
申请号：US17253343
申请日：2019-07-17
发明人： Alan M. Piwowar , Ray E. Drumright , Erin B. Vogel , Gary M. Wieber , Patrick J. Fryfogle , Yanxiang Li , Susan M. Machelski , Paul J. Popa , Adam C. Tomasik , Gerald Lawrence Witucki
IPC分类号： C09D183/08 , C09D133/08 , C09D133/10 , C08G77/26 , C08G77/00 , C08G77/08 , C08F220/14 , C08F220/18 , C08F220/20 , C08F220/32
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and silicone imine resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups and the silicone imine forms an amino-functional silicone in the presence of water. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US11834584B2
公开(公告)日：2023-12-05
申请号：US17253341
申请日：2019-07-17
发明人： Erin B. Vogel , Susan Machelski , Ray E. Drumright , Paul J. Popa , Gary M. Wieber , Gerald Lawrence Witucki , Patrick J. Fryfogle , Adam C. Tomasik
IPC分类号： C09D133/12 , C09D133/14 , C09D183/08 , C09D133/06 , C08G77/26 , C08L83/08 , C08F220/32 , C08L33/14 , C08L33/06
CPC分类号： C09D183/08 , C09D133/068 , C09D133/12 , C08F220/325 , C08G77/26 , C08L33/068 , C08L33/14 , C08L83/08 , C09D133/14
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US11267976B2
公开(公告)日：2022-03-08
申请号：US17427982
申请日：2020-04-16
发明人： Patrick J. Fryfogle , Yihan Liu , Timothy P. Mitchell , Jennifer A. Reil , Michael R. Reiter , John Roberts , Gary M. Wieber , Brett L. Zimmerman
IPC分类号： C09D7/65 , C09D7/20 , C09D175/04
摘要： A composition contains a polyorganosiloxane dispersed in a combination of a condensation product of a polysiloxane resin and a polyoxyalkylene polymer, and a non-aqueous fluid carrier; wherein the weight-ratio of non-aqueous fluid carrier to condensation product is 0.5 or more and 10 or less; the weight-ratio of the combination of condensation product and non-aqueous fluid carrier to polyorganosiloxane is 0.01 or more and 0.50 or less; and wherein the composition contains less than one weight-part aromatic solvent per million weight parts composition.
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公开(公告)号：US10940099B2
公开(公告)日：2021-03-09
申请号：US15544432
申请日：2016-04-04
发明人： Severine Cauvin , Patrick J. Fryfogle , Sophie Hanssens , Donald Kadlec , Stephane Ugazio , Marine Viaud , Brett Lee Zimmerman
IPC分类号： C08J3/03 , A61K8/06 , C08L83/14 , A61Q5/12 , A61Q19/00 , A61K8/895 , A61K8/25 , A61Q5/00 , A61Q5/02 , C11D3/00 , C11D3/12 , C11D3/37 , C08G77/50
摘要： The present invention provides methods for preparing emulsions of silicone fluids having pituitous rheological properties. The present invention also provides emulsions of a silicone fluid having pituitous rheological properties and composition comprising the emulsions. The compositions include, but are not limited to, personal care compositions and compositions for hair shampoo, hair conditioner, hair treatment composition, or skin care product.
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公开(公告)号：US11932775B2
公开(公告)日：2024-03-19
申请号：US17253343
申请日：2019-07-17
发明人： Alan M. Piwowar , Ray E. Drumright , Erin B. Vogel , Gary M. Wieber , Patrick J. Fryfogle , Yanxiang Li , Susan M. Machelski , Paul J. Popa , Adam C. Tomasik , Gerald Lawrence Witucki
IPC分类号： C09D183/08 , C08F220/14 , C08F220/18 , C08F220/20 , C08F220/32 , C08G77/00 , C08G77/08 , C08G77/26 , C09D133/08 , C09D133/10
CPC分类号： C09D183/08 , C08F220/14 , C08F220/1808 , C08F220/20 , C08F220/325 , C08G77/08 , C08G77/26 , C08G77/80 , C09D133/08 , C09D133/10
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and silicone imine resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups and the silicone imine forms an amino-functional silicone in the presence of water. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US20230242775A1
公开(公告)日：2023-08-03
申请号：US18005062
申请日：2021-10-11
发明人： Patrick J. Fryfogle , Julie Cook , Tim Mitchell , Yihan Liu , Rebecca Beeson , Miroslav Janco , Mikayla T. Miller , Brad J. Phillips
IPC分类号： C09D7/65 , C09D145/00 , C09D4/06
CPC分类号： C09D7/65 , C09D145/00 , C09D4/06
摘要： A dispersion contains: (a) a polyorganosiloxane with at least 90 mole % dimethyl D units and viscosity of one kPa*s or more dispersed as 0.5-20 micrometer particles; (b) a condensation product of: (i) a polysiloxane resin (Mw of 4,000-50,000) with composition: (R3SiO1/2)a(SiO4/2)b(ZO1/2)c where a is 0.30-0.60, b is 0.40-0.70, c is 0.05-0.20, a+b is one, R is selected from hydrogen, C1-30 alkyl groups and aryl groups, and Z is selected from H, and C1-8 alkyls; and (ii) a polyoxyalkylene polymer (Mn of 4,500-50,000) with composition: A-O—(C2H4O)e(C3H6O)p-A′ where e/p is 1-9, A and A′ are selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl groups and at least one of A and A′ is H; (c) non-aqueous fluid carrier miscible with (a); and (d) monoterpene; the weight-ratio of (c) to (b) is 0.5-10; weight-ratio of (b) and (c) to (a) is 0.01-0.50; and the composition contains below one ppm aromatic solvent.
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公开(公告)号：US20210253900A1
公开(公告)日：2021-08-19
申请号：US17253341
申请日：2019-07-17
发明人： Erin B. Vogel , Susan M. Machelski , Ray E. Drumright , Paul J. Popa , Gary M. Wieber , Gerald Lawrence Witucki , Patrick J. Fryfogle , Adam C. Tomasik
IPC分类号： C09D183/08 , C09D133/12 , C09D133/06
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US20200222302A1
公开(公告)日：2020-07-16
申请号：US16624160
申请日：2018-06-15
发明人： Thomas D. Bekemeier , Patrick J. Fryfogle , Gary M. Wieber , Kimmai T. Nguyen , Zhi Li , Julie Cook , Jason Vogel
IPC分类号： A61K8/894 , C09D183/06 , A61Q1/00
摘要： This invention relates to a film forming composition that can produce a tack free surface comprising: (I) a hydrosilylation reaction product of: (a) a silicone resin having the formula: (R1R22SiO1/2)w(R1R2SiO2/2)x(R2SiO3/2)y(SiO4/2)z wherein R2 is C1 to C10 hydrocarbon group free of aliphatic unsaturation, R1 is R2 or an alkenyl group, w is from 0.3 to 0.6, x is from 0.0 to 0.2, y is 0, z is from 0.4 to 0.7, w+x+y+z=1.0, and w+z is from 0.85 to 1.0, with the proviso that the silicone resin (a) has at least two silicon-bonded alkenyl groups per number average molecule; (b) a polyether compound having the formula: R3O(C2H4))c(C3H6O)dR3 wherein R3 is a monovalent unsaturated aliphatic hydrocarbon group containing 2 to 12 carbon atoms, c is from 0 to 50, d is from 0 to 50, and the value of c+d is greater than zero; (c) an SiH functional organopolysiloxane having the general formula: HcR3-cSiO(R2SiO)a(RHSiO)bSiR3-cHc wherein c is 0 or 1, R can be identical or different and is a monovalent, optionally substituted hydrocarbon group with 1 to 18 carbon atoms per molecule, a and b are integers, with the proviso that the sum of a+b is 0 to 300, and wherein the organopolysiloxane contains SiH in amounts from 0.01 to 0.4 wt %; (d) a hydrosilylation catalyst; and (e) a carrier solvent; and (II) a silicone resin having the formula: (R43SiO1/2)u(SiO4/2)v wherein R4 is a C1 to C10 hydrocarbon group free of aliphatic unsaturation, u is from 0.3 to 0.6, v is from 0.4 to 0.7, and the value of u+v is 1.0. The film forming composition of this invention are useful in manufacturing personal care compositions, which may also be described as a personal care product composition.
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