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公开(公告)号:US11840506B2
公开(公告)日:2023-12-12
申请号:US18310975
申请日:2023-05-02
Applicant: Evonik Operations GmbH
Inventor: Dirk Fridag , Johannes Knossalla , Alexander Brächer , Peter Kucmierczyk , Anna Chiara Sale , Robert Franke , Ana Markovic
CPC classification number: C07C45/505 , B01J31/185 , C07C45/83
Abstract: A process for preparing C5 aldehydes involves hydroformylation of butenes with synthesis gas in the presence of a homogeneous catalyst system and a solvent. It is a feature of the process that the aldehyde concentration in the reaction mixture is limited.
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公开(公告)号:US20230357117A1
公开(公告)日:2023-11-09
申请号:US18310975
申请日:2023-05-02
Applicant: Evonik Operations GmbH
Inventor: Dirk Fridag , Johannes Knossalla , Alexander Brächer , Peter Kucmierczyk , Anna Chiara Sale , Robert Franke , Ana Markovic
CPC classification number: C07C45/505 , C07C45/83 , B01J31/185
Abstract: A process for preparing C5 aldehydes involves hydroformylation of butenes with synthesis gas in the presence of a homogeneous catalyst system and a solvent. It is a feature of the process that the aldehyde concentration in the reaction mixture is limited.
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公开(公告)号:US11773042B2
公开(公告)日:2023-10-03
申请号:US18064946
申请日:2022-12-13
Applicant: EVONIK OPERATIONS GMBH
Inventor: Carolin Schneider , Ralf Jackstell , Matthias Beller , Robert Franke
CPC classification number: C07C45/505 , B01J31/2457 , B01J37/04 , B01J2231/321 , B01J2531/828
Abstract: Process for hydroformylation of olefins using Pt and iodine.
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公开(公告)号:US20230250040A1
公开(公告)日:2023-08-10
申请号:US18165245
申请日:2023-02-06
Applicant: Evonik Operations GmbH
Inventor: Alexander BRÄCHER , Ana Markovic , Anna Chiara Sale , Dirk Fridag , Johannes Knossalla , Peter Kucmierczyk , Robert Franke
CPC classification number: C07C45/77 , B01J31/1845 , C07C45/786
Abstract: A process can be used for preparing aldehydes from C2 to C20 olefins with a subsequent thermal separation for removal of the aldehyde formed. The process involves a membrane separation, which is preceded by performance of a gas exchange by which the proportion of the partial pressure represented by carbon monoxide or hydrogen is increased in order to reduce catalyst losses.
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5.
公开(公告)号:US20230173467A1
公开(公告)日:2023-06-08
申请号:US18063072
申请日:2022-12-07
Applicant: Evonik Operations GmbH
Inventor: Johannes KNOSSALLA , Thomas Quandt , Robert Franke
CPC classification number: B01J23/755 , B01J21/12 , B01J37/0018 , B01J37/04 , B01J37/031 , B01J37/0236 , B01J37/088 , B01J37/0063 , C07C2/58 , C07C2523/755
Abstract: A process for producing an oligomerization catalyst includes hydrothermal treatment. An oligomerization catalyst produced by the process is useful for the oligomerization of C2 to C12 olefins.
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公开(公告)号:US11565991B2
公开(公告)日:2023-01-31
申请号:US17718542
申请日:2022-04-12
Applicant: EVONIK OPERATIONS GMBH
Inventor: Anna Chiara Sale , Robert Franke , Alexander Brächer , Dirk Fridag , Johannes Knossalla , Peter Kucmierczyk , Ana Markovic
Abstract: Mixture of bisphosphites having an open and a closed outer unit and the use thereof as a catalyst mixture in hydroformylation.
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公开(公告)号:US11440863B2
公开(公告)日:2022-09-13
申请号:US16888920
申请日:2020-06-01
Applicant: Evonik Operations GmbH
Inventor: Peter Kucmierczyk , Robert Franke , Dirk Fridag , Johannes Knossalla , Marc Schäpertöns , Frederik Gluth
IPC: C07C29/149 , C07C67/38 , C07C29/76 , C07C29/78 , C07C29/80 , C07C29/86 , B01J31/22 , C07C67/48 , C07C29/132 , C07C67/03
Abstract: The invention provides a process for preparing an alcohol by hydrogenating an ester which is obtained by alkoxycarbonylating a C2 to C20 hydrocarbon having at least one multiple bond, preferably having at least one olefinic double bond, in which the homogeneous catalyst system used is separated from the product mixture by means of membrane separation. In a development of the present invention, the ester thus formed is converted to another ester by transesterification and then hydrogenated.
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公开(公告)号:US20220193611A1
公开(公告)日:2022-06-23
申请号:US17549709
申请日:2021-12-13
Applicant: Evonik Operations GmbH
Inventor: Frederik Gluth , Marc Schäpertöns , Thomas Quell , Frank Geilen , Stefan Drees , Fabian Höckelmann , Robert Franke
Abstract: The invention provides an improvement in terms of control and process technology for a method of continuous removal of a component from a liquid mixture using a membrane unit comprising at least one membrane stage. The improvement is that a portion of the overall permeate stream is recycled to the feed vessel and/or beyond the feed vessel but upstream of the conveying device, and the remainder of the overall permeate stream is removed, with the recycled permeate having a higher concentration of the component to be separated off than the removed permeate. The presently disclosed method can especially be used for separation of a homogeneously dissolved catalyst from a liquid reaction mixture.
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9.
公开(公告)号:US20220162147A1
公开(公告)日:2022-05-26
申请号:US17530629
申请日:2021-11-19
Applicant: EVONIK OPERATIONS GMBH
Inventor: Peter KUCMIERCZYK , Robert Franke , Matthias Beller , Ricarda Dühren , Ralf Jackstell
Abstract: Ru-catalysed domino hydroformylation/hydrogenation/esterification using phosphine ligands.
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公开(公告)号:US10654784B2
公开(公告)日:2020-05-19
申请号:US16574217
申请日:2019-09-18
Applicant: Evonik Operations GmbH
Inventor: Jennifer Haßelberg , Robert Franke , Frank Stenger , Peter Kreis , Corinna Hecht , Marc Oliver Kristen
Abstract: The invention relates to a process for hydroformylating short-chain olefins, especially C2 to C5 olefins, in which the catalyst system is in heterogenized form on a support of a porous ceramic material, and to plants for performing this process.
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