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    Apparatus for the Gas-Phase Polymerization of Olefins,in Particular Ethylene
    1.
    发明申请
    Apparatus for the Gas-Phase Polymerization of Olefins,in Particular Ethylene 有权
    用于烯烃气相聚合的装置，特别是乙烯

    公开(公告)号：US20070264171A1

    公开(公告)日：2007-11-15

    申请号：US11667349

    申请日：2005-11-09

    申请人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

    发明人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

    IPC分类号： C08F2/34

    CPC分类号： B01J8/1872 ,  B01J8/0055 ,  B01J8/24 ,  B01J2208/00256 ,  B01J2208/00274 ,  B04C5/081 ,  C08F6/02 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08F2/34

    摘要： An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tube (5) extending essentially axially symmetrically down into the upper section and, if appropriate, the middle section for discharging the recycle gas which has been freed of the particles. According to the invention the ratio Hi of the distance hi from the lower end of the tube (5) extending downward into the cyclone to the intersection (6) of an imaginary extension of the wall of the downward-extending tube (5) with the wall of the middle section (3b) to the diameter di of the downward-extending tube (5) is from 3 to 8, in particular from 4 to 7.

    摘要翻译： 用于烯烃聚合的装置，特别是乙烯，包括气相流化床反应器（1），连接到反应器的再循环气体管线（2），用于排出和再循环包含未聚合烯烃的循环气流和 旋流器（3），其位于循环气体管线中，用于还原和沉淀夹带在来自反应器的再循环气体中的固体颗粒，旋风分离器包括具有基本上垂直的中心轴线的上部分（3a），其上壁延伸 沿着旋转对称体并且设置有相对于中心轴线偏心布置的旋风入口（4），邻近上部（3a）并且其壁沿旋转对称体延伸的中间部分（3b） 用于排出邻近中间部分（3b）并且其壁延伸的再循环气体沉淀的固体颗粒的下部分（3c） 旋转对称体和基本上轴向对称地延伸到上部的管（5）以及适当的中间部分用于排出已经没有颗粒的循环气体。 根据本发明，与从下游进入旋风分离器的管（5）的下端距离h i i的距离h i i的比例H i 向下延伸的管（5）的壁与中间部分（3b）的壁与向下延伸的管（5）的直径d iI i的假想延伸为3至 8，特别是4到7。

    Apparatus and Process for the Gas-Phase Polymerization of Olefins
    2.
    发明申请
    Apparatus and Process for the Gas-Phase Polymerization of Olefins 有权
    用于烯烃气相聚合的装置和方法

    公开(公告)号：US20080014128A1

    公开(公告)日：2008-01-17

    申请号：US11667417

    申请日：2005-11-08

    申请人： Eberhard Herrmann ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

    发明人： Eberhard Herrmann ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

    IPC分类号： C08F10/00 ,  B01J19/18

    CPC分类号： B01J8/003 ,  B01J8/006 ,  B01J8/1872 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00761 ,  C08F10/00 ,  C08F110/02 ,  C08F2/34

    摘要： Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8). The inlet chamber (4) has a dividing wall (10) which is arranged essentially parallel to the filter medium (9) and separates the inlet chamber (4) into an inflow region (4a), which is connected to the gas inlet (6), and a filter region (4b) in which the filter medium is located and has an upper opening and a lower opening which are dimensioned so that from 60 to 90% of the volume flow flows through the upper opening so that flow along the filter medium (9) from the top downward results.

    摘要翻译： 用于烯烃聚合的设备，特别是乙烯，包括气相流化床反应器（1），用于从反应器（1）连续或不连续地获取聚合物颗粒的出口管线（15），该管线（15） ）连接到用于分离聚合物颗粒和气体的减压容器（2），用于释放连接到减压容器（2）的夹带的细颗粒的气体的循环气体过滤器（3），压缩已经被 释放细颗粒并将其再循环到反应器（1）中，循环气体过滤器（3）具有设置有气体入口（6）的入口室（4），设置有气体出口的出口室（5） 7），用于保持将入口室（4）与出口室（5）分离的细颗粒和颗粒出口（8）的基本垂直的片状过滤介质（9）。 入口室（4）具有基本上与过滤介质（9）平行布置的分隔壁（10），并将入口室（4）分离成入口区域（4a），该入口区域连接到气体入口 6）和过滤器区域（4b），其中过滤介质位于并具有上开口和下开口，其尺寸使得体积流量的60％至90％流过上开口，使得沿着 过滤介质（9）从顶部向下的结果。

    Apparatus for the gas-phase polymerization of olefins, in particular ethylene
    3.
    发明授权
    Apparatus for the gas-phase polymerization of olefins, in particular ethylene 有权
    用于烯烃气相聚合的装置，特别是乙烯

    公开(公告)号：US07781544B2

    公开(公告)日：2010-08-24

    申请号：US11667349

    申请日：2005-11-09

    申请人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

    发明人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

    IPC分类号： C08F2/00 ,  F27B15/08

    CPC分类号： B01J8/1872 ,  B01J8/0055 ,  B01J8/24 ,  B01J2208/00256 ,  B01J2208/00274 ,  B04C5/081 ,  C08F6/02 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08F2/34

    摘要： An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tube (5) extending essentially axially symmetrically down into the upper section and, if appropriate, the middle section for discharging the recycle gas which has been freed of the particles. According to the invention the ratio Hi of the distance hi from the lower end of the tube (5) extending downward into the cyclone to the intersection (6) of an imaginary extension of the wall of the downward-extending tube (5) with the wall of the middle section (3b) to the diameter di of the downward-extending tube (5) is from 3 to 8, in particular from 4 to 7.

    摘要翻译： 用于烯烃聚合的装置，特别是乙烯，包括气相流化床反应器（1），连接到反应器的再循环气体管线（2），用于排出和再循环包含未聚合烯烃的循环气流和 旋风分离器（3）位于循环气体管线中，用于还原和沉淀夹带在来自反应器的再循环气体中的固体颗粒，其中旋风分离器包括具有基本垂直的中心轴线的上部分（3a），其上壁沿着 旋转对称体，并且设置有相对于中心轴偏心布置的旋风入口（4），邻接上部（3a）的中间部分（3b），并且其壁沿着旋转对称的体 用于排出邻近中间部分（3b）的循环气体沉淀的固体颗粒的下部（3c），并且其壁沿旋转方向延伸 对称体和管（5），其基本上轴向对称地延伸到上部，并且如果适当的话，中间部分用于排出已经没有颗粒的循环气体。 根据本发明，从管（5）的下端向下延伸到旋风分离器中的距离hi的距离hi与向下延伸的管（5）的壁的假想延伸部的交点（6） 中间部分（3b）的壁向下延伸管（5）的直径di为3至8，特别是4至7。

    Apparatus and process for the gas-phase polymerization of olefins
    4.
    发明授权
    Apparatus and process for the gas-phase polymerization of olefins 有权
    用于烯烃气相聚合的装置和方法

    公开(公告)号：US07776278B2

    公开(公告)日：2010-08-17

    申请号：US11667417

    申请日：2005-11-08

    申请人： Eberhard Herrmann ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

    发明人： Eberhard Herrmann ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

    IPC分类号： B01J19/00

    CPC分类号： B01J8/003 ,  B01J8/006 ,  B01J8/1872 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00761 ,  C08F10/00 ,  C08F110/02 ,  C08F2/34

    摘要： Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8). The inlet chamber (4) has a dividing wall (10) which is arranged essentially parallel to the filter medium (9) and separates the inlet chamber (4) into an inflow region (4a), which is connected to the gas inlet (6), and a filter region (4b) in which the filter medium is located and has an upper opening and a lower opening which are dimensioned so that from 60 to 90% of the volume flow flows through the upper opening so that flow along the filter medium (9) from the top downward results.

    摘要翻译： 用于烯烃聚合的设备，特别是乙烯，包括气相流化床反应器（1），用于从反应器（1）连续或不连续地获取聚合物颗粒的出口管线（15），该管线（15） ）连接到用于分离聚合物颗粒和气体的减压容器（2），用于释放连接到减压容器（2）的夹带的细颗粒的气体的循环气体过滤器（3），压缩已经被 释放细颗粒并将其再循环到反应器（1）中，循环气体过滤器（3）具有设置有气体入口（6）的入口室（4），设置有气体出口的出口室（5） 7），用于保持将入口室（4）与出口室（5）分离的细颗粒和颗粒出口（8）的基本垂直的片状过滤介质（9）。 入口室（4）具有基本上与过滤介质（9）平行布置的分隔壁（10），并将入口室（4）分离成入口区域（4a），该入口区域连接到气体入口 ）和过滤器区域（4b），其中所述过滤介质定位并具有上开口和下开口，所述上开口和下开口的尺寸使得所述体积流的60至90％流过所述上开口，使得沿着所述过滤器的流动 中等（9）从上方下降。

    Method for activation of chromium containing catalyst precursor for polymerization and the resulting polymerization catalyst
    7.
    发明授权
    Method for activation of chromium containing catalyst precursor for polymerization and the resulting polymerization catalyst 有权
    活化用于聚合的含铬催化剂前体的方法和所得的聚合催化剂

    公开(公告)号：US09266976B2

    公开(公告)日：2016-02-23

    申请号：US13990490

    申请日：2011-11-29

    申请人： Manfred Hecker ,  Paulus De Lange ,  Rainer Karer

    发明人： Manfred Hecker ,  Paulus De Lange ,  Rainer Karer

    IPC分类号： C08F4/24 ,  B01J23/26 ,  B01J37/14 ,  B01J38/14 ,  B01J38/30 ,  B01J38/32 ,  C08F10/00

    CPC分类号： C08F4/24 ,  B01J23/26 ,  B01J37/14 ,  B01J38/14 ,  B01J38/30 ,  B01J38/32 ,  C08F10/00 ,  Y02P20/584 ,  C08F4/69

    摘要： The instant invention relates to an activation of a polymerization catalyst precursor by heat treatment comprising a support material and a catalyst precursor deposited thereon in a fluidized bed activator and to the use of the activated polymerization catalyst in the manufacture of polyolefins. The activation involves heat treatment in the presence of oxygen. After that activation the oxygen in the activator is replaced by inert gas via flushing until the fluidization gas emerging from the activator comprises oxygen in a maximum amount of up to 5 ppm. The catalyst prepared by that method is improved with respect to prevent reactor fouling during gas-phase polymerization or slurry polymerization either in stirred vessel or loop.

    摘要翻译： 本发明涉及通过热处理的聚合催化剂前体的活化，其包括在流化床活化剂中沉积在其上的载体材料和催化剂前体，以及活性聚合催化​​剂在制备聚烯烃中的用途。 活化包括在氧气存在下的热处理。 在该活化之后，通过冲洗将活化剂中的氧替代为惰性气体，直到从活化剂出来的流化气体包含最高达5ppm的氧气。 通过该方法制备的催化剂相对于在搅拌容器或循环中的气相聚合或淤浆聚合期间防止反应器结垢而改进。

    METHOD FOR ACTIVATION OF CHROMIUM CONTAINING CATALYST PRECURSOR FOR POLYMERIZATION AND THE RESULTING POLYMERIZATION CATALYST
    9.
    发明申请
    METHOD FOR ACTIVATION OF CHROMIUM CONTAINING CATALYST PRECURSOR FOR POLYMERIZATION AND THE RESULTING POLYMERIZATION CATALYST 有权
    用于活化含有催化剂前体用于聚合和结晶聚合催化剂的铬的方法

    公开(公告)号：US20130252809A1

    公开(公告)日：2013-09-26

    申请号：US13990490

    申请日：2011-11-29

    申请人： Manfred Hecker ,  Paulus De Lange ,  Rainer Karer

    发明人： Manfred Hecker ,  Paulus De Lange ,  Rainer Karer

    IPC分类号： C08F4/24

    CPC分类号： C08F4/24 ,  B01J23/26 ,  B01J37/14 ,  B01J38/14 ,  B01J38/30 ,  B01J38/32 ,  C08F10/00 ,  Y02P20/584 ,  C08F4/69

    摘要： The instant invention relates to an activation of a polymerization catalyst precursor by heat treatment comprising a support material and a catalyst precursor deposited thereon in a fluidized bed activator and to the use of the activated polymerization catalyst in the manufacture of polyolefins. The activation involves heat treatment in the presence of oxygen. After that activation the oxygen in the activator is replaced by inert gas via flushing until the fluidization gas ermerging from the activator comprises oxygen in a maximum amount of up to 5 ppm. The catalyst prepared by that method is improved with respect to prevent reactor fouling during gas-phase polymerization or slurry polymerization either in stirred vessel or loop.

    摘要翻译： 本发明涉及通过热处理的聚合催化剂前体的活化，其包括在流化床活化剂中沉积在其上的载体材料和催化剂前体，以及活性聚合催化​​剂在制备聚烯烃中的用途。 活化包括在氧气存在下的热处理。 在该活化之后，通过冲洗将活化剂中的氧替代为惰性气体，直到来自活化剂的流化气体含量最高达5ppm的氧气。 通过该方法制备的催化剂相对于在搅拌容器或循环中的气相聚合或淤浆聚合期间防止反应器结垢而改进。

    Process and apparatus for the polymerization of ethylene
    10.
    发明授权
    Process and apparatus for the polymerization of ethylene 有权
    用于乙烯聚合的方法和设备

    公开(公告)号：US07582723B2

    公开(公告)日：2009-09-01

    申请号：US11883713

    申请日：2006-01-30

    申请人： Giuseppe Penzo ,  Cyrus Ahmadzade-Youssefi ,  Rainer Karer ,  Ulrich Nieken

    发明人： Giuseppe Penzo ,  Cyrus Ahmadzade-Youssefi ,  Rainer Karer ,  Ulrich Nieken

    IPC分类号： C08F6/00 ,  C08F2/34 ,  B01D53/72

    CPC分类号： C08F10/02 ,  B01J8/0035 ,  B01J8/006 ,  B01J8/24 ,  B01J2208/00274 ,  B01J2208/00761 ,  B01J2219/00006 ,  C08F6/005 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  Y02P20/582 ,  Y10S526/92 ,  C08L23/06 ,  C08L23/0815 ,  C08F4/69 ,  C08F2/34 ,  C08F2/01 ,  C08F210/08 ,  C08F210/14

    摘要： Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion of 1-olefins and alkanes having from 4 to 12 carbon atoms in the propane fraction being less than 4 mol %, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process. In this way, a high heat discharge from the reactor, satisfactory degassing of the discharged polymer particles and recovery of the reaction gas discharged together with the polymer particles and also the gas used for degassing the polymer particles are made possible.

    摘要翻译： 乙烯或乙烯与进一步的1-烯烃聚合的方法，其中乙烯在催化剂存在下在气相反应器和包含丙烷和未聚合乙烯的反应气体中聚合循环以除去聚合热， 其中聚合物颗粒从反应器中连续或不连续地排出，聚合物颗粒与伴随排出气体的主要部分分离，聚合物颗粒脱气，气体不含夹带的细颗粒，并从低沸点 在第一分离阶段，包含乙烯或含有另外的具有4至12个碳原子的1-烯烃或烷烃的高沸点馏分的馏分在第二分离阶段分离出丙烷馏分，该丙烷馏分用于使聚合物脱气 从反应器排出的颗粒，丙烷馏分中乙烯的比例小于1mol ％，丙烷馏分中具有4至12个碳原子的1-烯烃和烷烃的比例小于4mol％，基于总丙烷馏分。 此外，一种用于执行该过程的装置。 以这种方式，可以从反应器的高热放电，排出的聚合物颗粒的令人满意的脱气和与聚合物颗粒一起排放的反应气体的回收以及用于使聚合物颗粒脱气的气体成为可能。