Type of modified gelatin and its use in a DTR material
    1.
    发明授权
    Type of modified gelatin and its use in a DTR material 失效
    改性明胶的类型及其在DTR材料中的用途

    公开(公告)号:US5474885A

    公开(公告)日:1995-12-12

    申请号:US249723

    申请日:1994-05-26

    摘要: A modified gelatin is disclosed wherein part of the free carboxyl groups is replaced by modifiers having more acid end-standing groups chosen from --SO.sub.3 M, --OSO.sub.3 M, --SSO.sub.3 M, --OPO(OH).sub.2, --OPO(OH)(OR.sup.2), --PO(OH).sub.2, --PO(OH)(OR.sup.2).In a preferred embodiment such a modified gelatin is incorporated in a DTR photographic material which after processing can serve as a lithographic printing plate. Thanks to the more hydrophilic character of the modified gelatin the differentiation between printing and non-printing areas is improved and toning at printing start-up is reduced.

    摘要翻译: 公开了一种改性明胶,其中部分游离羧基被具有更多酸选自-SO 3 M,-OSO 3 M,-SSO 3 M,-OPO(OH)2,-OPO(OH)(OR 2), -PO(OH)2,-PO(OH)(OR2)。 在优选的实施方案中,这种改性明胶掺入DTR照相材料中,其在加工后可用作平版印刷版。 由于改性明胶的亲水性更好,印刷和非印刷区域之间的差异得到改善,印刷启动时的色调降低。

    Type of modified gelatin and its use in a DTR material
    2.
    发明授权
    Type of modified gelatin and its use in a DTR material 失效
    改性明胶的类型及其在DTR材料中的用途

    公开(公告)号:US5536817A

    公开(公告)日:1996-07-16

    申请号:US520990

    申请日:1995-08-30

    摘要: A modified gelatin is disclosed wherein part of the free carboxyl groups is replaced by modifiers having more acid end-standing groups chosen from --SO.sub.3 M, --OSO.sub.3 M, --SSO.sub.3 M, ---OPO(OH).sub.2, --OPO(OH)(OR.sup.2), --PO(OH).sub.2, --PO(OH)(OR.sup.2).In a preferred embodiment such a modified gelatin is incorporated in a DTR photographic material which after processing can serve as a lithographic printing plate. Thanks to the more hydrophilic character of the modified gelatin the differentiation between printing and non-printing areas is improved and toning at printing start-up is reduced.

    摘要翻译: 公开了一种改性明胶,其中部分游离羧基被具有更多酸选自-SO 3 M,-OSO 3 M,-SSO 3 M,-OPO(OH)2,-OPO(OH)(OR 2)的酸性末端基团的改性剂代替, ,-PO(OH)2,-PO(OH)(OR 2)。 在优选的实施方案中,这种改性明胶掺入DTR照相材料中,其在加工后可用作平版印刷版。 由于改性明胶的亲水性更好,印刷和非印刷区域之间的差异得到改善,印刷启动时的色调降低。

    Developer composition for use in the processing of light-sensitive silver halide photographic materials
    4.
    发明授权
    Developer composition for use in the processing of light-sensitive silver halide photographic materials 失效
    用于加工感光卤化银照相材料的显影剂组合物

    公开(公告)号:US06238854B1

    公开(公告)日:2001-05-29

    申请号:US09588226

    申请日:2000-06-06

    IPC分类号: G03C5305

    摘要: A black-and-white silver halide developer composition has been disclosed comprising, besides one or more developing agent(s), agent(s) preventing oxidation thereof and agent(s) providing pH buffering, at least one silver complexing agent, characterized in that said silver complexing agent has a silver complexing stability ratio of at least 70% and, besides said silver complexing agent, at least one agent preventing silver dissolution characterized in that said agent preventing silver dissolution, if present in an amount of 50 mg/l of developer, makes silver content of the developer decrease in an amount of more than 50% versus in the absence thereof, without loss in speed in an amount of more than 0.10 log Exposure after processing in said developer composition.

    摘要翻译: 公开了一种黑白卤化银显影剂组合物,除了一种或多种显影剂之外还包含防止其氧化的试剂和提供pH缓冲剂的试剂,至少一种银络合剂,其特征在于 所述银络合剂的银络合稳定性比率至少为70%,除了所述银络合剂外,至少一种防银溶解的试剂,其特征在于所述防银溶解的试剂(如果以50mg / l的量存在) 的显影剂使显影剂的银含量相对于不存在显影剂的量减少超过50%,而在所述显影剂组合物中加工后不超过0.10log曝光量的速度损失。

    Processing method of light-sensitive silver halide photographic materials showing less tendency to sludge formation
    5.
    发明授权
    Processing method of light-sensitive silver halide photographic materials showing less tendency to sludge formation 失效
    感光卤化银照相材料的加工方法显示较少的污泥形成倾向

    公开(公告)号:US06238853B1

    公开(公告)日:2001-05-29

    申请号:US09588007

    申请日:2000-06-06

    IPC分类号: G03C526

    摘要: A method of processing has been described for a light-sensitive black-and-white silver halide photographic material comprising the distinct steps of developing, fixing, rinsing and drying, wherein during said processing said developer comprises, besides one or more developing agent(s), one or more agent(s) preventing oxidation thereof and agent(s) providing pH buffering in running equilibrium conditions during said processing, at least one agent preventing silver dissolution and at least one silver complexing agent, characterized in that said agent preventing silver dissolution, if present in an amount of 50 mg/l of developer, makes silver content of the developer decrease in an amount of more than 50% versus in the absence thereof, without loss in speed in an amount of more than 0.10 log Exposure after processing in said developer composition; said silver complexing agent makes silver content of the said developer increase in an amount of more than 1 mg per liter per mmole of said complexing agent.

    摘要翻译: 已经描述了一种用于感光黑白卤化银照相材料的方法,其包括显影,定影,漂洗和干燥的不同步骤,其中在所述处理期间,除了一种或多种显影剂 ),一种或多种防止其氧化的试剂和在所述加工过程中在运行平衡条件下提供pH缓冲的试剂,至少一种防止银溶解的试剂和至少一种银络合剂,其特征在于,所述防止银溶解的试剂 如果以50mg / l显影剂的量存在,则显影剂的银含量相对于不存在显影剂而言,其含量大于50%,而不会以大于0.10log的量的速度损失处理后的曝光 在所述显影剂组合物中;所述银络合剂使所述显影剂的银含量增加,每毫升所述补体大于1mg / 外用剂。

    Preparation method of copolymerizable photoinitiators
    7.
    发明授权
    Preparation method of copolymerizable photoinitiators 失效
    可共聚光引发剂的制备方法

    公开(公告)号:US08664431B2

    公开(公告)日:2014-03-04

    申请号:US12744966

    申请日:2008-11-27

    申请人: Johan Loccufier

    发明人: Johan Loccufier

    IPC分类号: C07C69/63

    摘要: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of CI, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group-, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).

    摘要翻译: 用于制备根据式(I)的(甲基)丙烯酸酯化光引发剂的中间体:其中:R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自由Cl,Br,I和R 2 SO 3组成的组中的基团; 并且R 2表示选自烷基,烯基,炔基,烷芳基 - ,芳烷基,芳基和杂芳基中的任选取代的基团。 此外,通过根据式(I)的中间体β-去除HX制备(甲基)丙烯酸酯化光引发剂的方法。

    Polymerizable photoinitiators and radiation curable compositions
    9.
    发明授权
    Polymerizable photoinitiators and radiation curable compositions 有权
    可聚合光引发剂和可辐射固化组合物

    公开(公告)号:US08492452B2

    公开(公告)日:2013-07-23

    申请号:US13129413

    申请日:2009-12-01

    IPC分类号: C08F2/50 C08J3/28

    摘要: A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.

    摘要翻译: 可聚合的光引发剂由式(I)表示:其中R 1,R 2和R 3独立地选自氢,任选取代的烷基和任选取代的芳基,或者R 1和R 3表示必要的原子以形成 五至八元环; p,w,y和z都是整数,y代表值1到6; p表示w和z的和; p代表1到6的值; w = 1〜(p-z),z = 0〜(p-w) L表示含有1至14个碳原子的任选取代的(p + y)价连接基团; A表示选自丙烯酸酯基,甲基丙烯酸酯基,苯乙烯基,丙烯酰胺基,甲基丙烯酰胺基,马来酸酯基,富马酸酯基,衣康酸酯基,乙烯基醚基中的自由基聚合性基团 烯丙基醚基,烯丙基酯基和乙烯基酯基; 并且X表示光引发部分,其包含至少一个能够在暴露于光化辐射时引发自由基聚合反应的基团。

    CURABLE LIQUIDS AND INKS FOR TOYS AND FOOD PACKAGING APPLICATIONS
    10.
    发明申请
    CURABLE LIQUIDS AND INKS FOR TOYS AND FOOD PACKAGING APPLICATIONS 有权
    用于玩具和食品包装应用的可固化液体和墨水

    公开(公告)号:US20100313782A1

    公开(公告)日:2010-12-16

    申请号:US12739160

    申请日:2008-10-21

    IPC分类号: B41F31/00 C09D11/10 A23B7/154

    摘要: A free radical curable liquid for inkjet printing of food packaging materials includes no initiator or otherwise one or more initiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric initiators, polymeric initiators, and polymerizable initiators; and a polymerizable composition of the liquid consists essentially of: a) 25-100 wt % of one or more polymerizable compounds A having at least one acrylate group G1 and at least one second ethylenically unsaturated polymerizable functional group G2 selected from the group consisting of a vinlyether group, an allylether group, and a allylester group; b) 0-55 wt % of one or more polymerizable compounds B selected from the group consisting of monofunctional acrylates and difunctional acrylates; and c) 0-55 wt % of one or more polymerizable compounds C selected from the group consisting of trifunctional acrylates, tetrafunctional acrylates, pentafunctional acrylates and hexafunctional acrylates. If the weight percentage of compounds B>24 wt %, then the weight percentage of compounds C>1 wt %, and all weight percentages of A, B, and C are based upon the total weight of the polymerizable composition. At least one polymerizable compound B or C is present in the polymerizable composition if the free radical curable liquid contains no initiator.

    摘要翻译: 用于食品包装材料的喷墨印刷的自由基可固化液体不包括引发剂或其它一种或多种选自非聚合二 - 或多官能引发剂,低聚引发剂,聚合引发剂和可聚合引发剂的引发剂; 并且所述液体的可聚合组合物基本上由以下组成:a)25-100重量%的一种或多种可聚合化合物A,其具有至少一个丙烯酸酯基团G1和至少一个第二烯属不饱和可聚合官能团G2,所述第二烯键式不饱和可聚合官能团选自 乙烯醚基,烯丙基醚基和烯丙基; b)0-55重量%的选自单官能丙烯酸酯和双官能丙烯酸酯的一种或多种可聚合化合物B; 和c)0-55重量%的选自三官能丙烯酸酯,四官能丙烯酸酯,五官能丙烯酸酯和六官能丙烯酸酯的一种或多种可聚合化合物C。 如果化合物B的重量百分比> 24重量%,则C> 1重量%的化合物的重量百分数,以及A,B和C的所有重量百分数都是基于可聚合组合物的总重量。 如果自由基可固化液体不含引发剂,则可聚合组合物中存在至少一种可聚合化合物B或C.