摘要:
A thermal barrier coating system for high temperature superalloys includes an intermetallic bond coating on the substrate and a ceramic topcoat having a columnar grain structure with the columnar axis perpendicular to the surface of the coating. The intermetallic coating is preferably a nickel aluminide or a platinum aluminide, whose upper surface is oxidized during processing to form a thin layer of predominantly aluminum oxide. The ceramic topcoat is preferably zirconium oxide having from about 6 to 20 percent yttrium oxide.
摘要:
According to an embodiment of the invention, an article of manufacture for use in a gas turbine engine is disclosed. The article comprises a part having a surface covered with a ceramic thermal barrier coating. The thermal barrier coating has an outer surface covered with a sacrificial phosphate coating, wherein the sacrificial phosphate coating reacts with contaminant compositions to prevent contaminant infiltration into the thermal barrier coating.
摘要:
In accordance with an embodiment of the invention, a thermal barrier coating for inclusion in a thermal barrier coating/environmental barrier coating system (TBC/EBC system) for use on a silicon based substrate is disclosed. The thermal barrier coating comprising up to about 9 mol percent of a stabilizer and up to 91 mol percent of primary oxide selected from the group consisting of zirconia, hafnia and mixtures thereof. The stabilizer comprises: a first metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof, a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosia, ytterbia, erbia, and mixtures thereof. The first metal oxide is in an amount of from about 3 to about 5 mol %, the second metal oxide is in an amount of from about 0.25 to about 6 mol %.
摘要:
A high temperature gas turbine component for use in the gas flow path that also is a specular optical reflector. A thin layer of a high temperature reflector is applied to the gas flow path of the component, that is, the surface of the component that forms a boundary for hot combustion gases. The component typically includes a thermal barrier coating overlying the high temperature metallic component that permits the component to operate at elevated temperatures. The thermal barrier coating must be polished in order to provide a surface that can suitably reflect the radiation into the gas flow path. A thin layer of the high temperature reflector the is applied over the polished thermal barrier coating by a process that can adequately adhere the reflector to the polished surface without increasing the roughness of the surface. The high temperature reflector can be applied to any surface aft of the compressor, such as on a turbine nozzle. The surface reflects radiation back into the hot gas flow path. The reflected radiation is not focused onto any other hardware component. The design of the component is such that the radiation is returned to the gas flow path rather than absorbed into a component wall that only serves to increase the temperature of the wall.
摘要:
Improved adhesion of thermal barrier coatings to nonmetallic substrates using a dense layer of ceramic on an underlying nonmetallic substrate that includes at least one oxidizable component. The improved adhesion occurs because the application of the dense ceramic layer forms a diffusion barrier for oxygen. This diffusion barrier prevents the oxidizable component of the substrate from decomposing. The present invention applies ceramic by a process that deposits a relatively thick and dense ceramic layer on the underlying substrate. The formation of the dense layer of ceramic avoids the problem of void formation associated with ceramic formation by most prior art thermal decomposition processes. The formation of voids has been associated with premature spalling of thermal barrier layers and other protective layers applied to substrates.
摘要:
A gas turbine component has a platform, a shank extending downwardly from the platform, and an airfoil extending upwardly from the platform. The gas turbine component is coated by first applying a first chromide layer overlying the base metal of at least a portion of the shank and interdiffused therewith, and second applying a second coating on at least a portion of the airfoil. The second coating optionally includes a second chromide layer contacting the base metal of the airfoil and interdiffused therewith, and includes an aluminide protective layer overlying the second chromide layer. The first chromide layer on the shank and the second chromide layer on the airfoil may be within the same chromium composition range (for example, from about 20 to about 30 weight percent chromium) and thickness range (for example, from about 0.001 to about 0.002 inch), and deposited at the same time.
摘要:
A method of repairing a thermal barrier coating on an article designed for use in a hostile thermal environment, such as turbine, combustor and augmentor components of a gas turbine engine. The method is particularly suited for the repair of thermal barrier coatings composed of a metallic bond layer formed on the surface of the article, and a columnar ceramic layer overlaying the bond layer. The method entails the steps of cleaning the bond layer exposed by localized spallation, treating the bond layer so as to texture its exposed surface, and then depositing a ceramic material on the surface of the bond layer so as to form a ceramic repair layer that completely covers the bond layer. Deposition of the repair layer can be carried out such that its upper surface projects above the adjacent ceramic layer, followed by abrading the repair layer to a height substantially level with the ceramic layer.
摘要:
An article coated with a thermal barrier coating system for high temperature use, has its thermal cyclic spallation life improved by the application of an aluminide to the outer portion of a bonding coating disposed on a substrate. The bond coating has a surface roughness in the range of about 200-600 microinches Ra prior to application of covering thermal barrier coating.
摘要:
A method for producing a thermal barrier coating/environmental barrier coating system on a silicon containing material substrate includes applying an environmental barrier coating (EBC) over the silicon containing material substrate; and applying a thermal barrier coating (TBC) over the EBC. The thermal barrier coating includes a compound having a primary constituent portion and a stabilizer portion stabilizing said primary constituent. The primary constituent portion of the thermal barrier coating includes hafnia present in an amount of at least about 5 mol % of the primary constituent and the stabilizer portion of said thermal barrier coating includes at least one metal oxide comprised of cations with a +2 or +3 valence present in the amount of about 10 to about 40 mol % of the thermal barrier coating.
摘要:
A gas turbine engine turbine blade comprising an airfoil section, a platform section, an under platform section, and a dovetail section, an exterior surface of the dovetail section comprising a shank exterior surface and a serrated exterior surface. The blade further comprises a silicon-modified diffusion aluminide layer a surface of a turbine blade section selected from the group consisting of an exterior surface of the under platform section, the exterior surface of the dovetail section, and combinations thereof, the silicon modified diffusion aluminide layer having a concentration of silicon at a surface of the silicon-modified diffusion aluminide layer in the range of about 1 weight percent to about 10 weight percent and a concentration of aluminum at the surface of the silicon modified diffusion aluminide layer in the range of about 5 weight percent to about 25 weight percent.