摘要:
Polyacetylene having an apparent density at 20.degree. C. greater than 0.6 g/ccm and a surface area below 60 m.sup.2 /g is prepared by polymerizing gaseous acetylene in the presence of a catalytic system consisting of:(a) an oxygenized compound of Ti or V, containing at least one metal-oxygen bond;(b) an organometallic compound of aluminum containing at least one hetero-atom, of the formula: ##STR1## wherein: ##STR2## while R=a hydrocarbon radical with 1-18 carbon atoms, and where R'.dbd.R, or halogen or alcoxyl.
摘要:
A process for the production of primarily syndiotactic vinyl aromatic polymers by polymerizing or copolymerizing vinyl aromatic monomers such as styrene or styrene derivatives in the presence of a catalyst system comprising the product of the reaction between:a) a compound of a transition metal (M) different from titanium and containing at least a bond M-O, M-C, M-N, M-P, M-S or M-halogen, andb) an organoaluminum compound containing at least an oxygen atom bound to the aluminum atom or bound between two aluminum atoms.Compound a) can be used as such or may be supported on a suitable carrier.
摘要:
Compositions comprising from 5 to 50% by weight of a polyphenylene ether and from 95 to 50% by weight of a styrene polymer having a syndiotactic structure. Such compositions are endowed with enhanced mechanical properties compared to those containing amorphous polystyrene, or polystyrene having an isotactic structure.
摘要:
Thermotropic melt processable liquid crystalline aromatic polyesters comprising units derived from a dicarboxylic acid and from a mixture of aromatic diols in which from 50% to 80% is (1-phenylethyl)hydroquinone and from 20% to 50% is hydroquinone.
摘要:
A superconductive element is described, comprising a rigid support made of a non-superconductive material, said support comprising at least one superconductive track formed by a groove containing a superconductive material having a density equal to at least 85% of the value of its theoretical density, and the process for producing said element. The present invention also relates to the possible uses of the superconductive elements, and also to superconductive devices comprising said superconductive elements.
摘要:
A process is described for the preparation of magnesium borohydride having a high purity and crystallinity, which comprises the reaction of an orgenometallic compound of magnesium of the type MgX2, wherein X is an organic binder selected from alkyl, amide, alkoxide, cyclopentadienyl, aryl, with a derivative of a boron hydride, in a hydrocarbon solvent.
摘要:
A description follows of an article based on a nickel-chromium-silicon metal alloy, including microcrystalline borides, obtained by the rapid solidification and subsequent thermal treatment of a nickel-chromium-boron-silicon metal alloy comprising from 39.0 to 69.4 atom % of nickel, from 11.8 to 33.9 atom % of chromium, from 7.6 to 27.4 atom % of boron and from 7.6 to 17.5 atom % of silicon. The above article is preferably a tape or a sheet or a fiber having high mechanical properties and is particularly resistant to oxidation.
摘要:
A process is described for the preparation of magnesium borohydride having a high purity and crystallinity, which comprises the reaction of an orgenometallic compound of magnesium of the type MgX2, wherein X is an organic binder selected from alkyl, amide, alkoxide, cyclopentadienyl, aryl, with a derivative of a boron hydride, in a hydrocarbon solvent.
摘要:
A method is described for the production of superconductive wires based on hollow filaments made of MgB2, which comprises: a) the formation of a composite billet by means of the coaxial insertion in a tubular metallic container of a cylindrical bar made of metallic magnesium and amorphous boron powder in the interspace between the container and bar, said powder being pressed between the metallic container and the magnesium bar, in such a quantity that the weight ratio magnesium/boron is higher than 1.2; b) at least one plastic deformation treatment of the composite billet thus obtained until a wire with a prefixed diameter is obtained, with the subsequent winding of the wire onto a support; c) a thermal treatment of the filament product thus obtained, at a temperature ranging from 700° C. to 950° C. for a time ranging from 15 minutes to three hours.
摘要翻译:描述了一种用于生产基于由MgB 2 N 2制成的中空丝的超导丝的方法,其包括:a)通过同轴插入在管状金属容器中形成复合坯料 在金属容器和镁棒之间的间隙中将金属镁和无定形硼粉制成的圆柱形棒在金属容器和镁棒之间的间隙中,镁/硼的重量比高于1.2; b)对由此获得的复合钢坯进行至少一次塑性变形处理,直到获得具有预定直径的钢丝,随后将钢丝卷绕到支撑件上; c)将由此获得的长丝产品在700℃至950℃的温度范围内热处理15分钟至3小时。
摘要:
A superconductive element is described, comprising a rigid support made of a non-superconductive material, said support comprising at least one superconductive track formed by a groove containing a superconductive material having a density equal to at least 85% of the value of its theoretical density, and the process for producing said element. The present invention also relates to the possible uses of the superconductive elements, and also to superconductive devices comprising said superconductive elements.