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    Room temperature curable compositions
    1.
    发明授权
    Room temperature curable compositions 失效
    室温固化组合物

    公开(公告)号：US4296228A

    公开(公告)日：1981-10-20

    申请号：US126230

    申请日：1980-03-03

    申请人： Ernst Innertsberger ,  Oswin Sommer ,  Erhard Bosch ,  Johann Muller ,  August Schiller

    发明人： Ernst Innertsberger ,  Oswin Sommer ,  Erhard Bosch ,  Johann Muller ,  August Schiller

    IPC分类号： C08L83/04 ,  C08G77/04

    CPC分类号： C08K5/54 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/44 ,  C08G77/70 ,  Y10S528/901

    摘要： Room temperature curable compositions, which can be stored under anhydrous conditions, but when exposed to atmospheric moisture at room temperature cure to an elastomer comprising a diorganopolysiloxane having terminal condensable groups, a silicon compound containing acetoxy, tert-butoxy and SiC-bonded alkyl groups and a condensation catalyst, if desired, in which at least a portion of the silicon compound containing acetoxy, tert-butoxy and SiC-bonded alkyl groups is obtained from the reaction of an alkyltriacetoxysilane and tert-butanol in aqueous acetic acid.

    摘要翻译： 室温可固化组合物，其可以在无水条件下储存，但是当暴露于常温水分时在室温下固化到包含具有末端可缩合基团的二有机聚硅氧烷，含有乙酰氧基，叔丁氧基和与SiC键合的烷基的硅化合物的弹性体，以及 如果需要，缩合催化剂，其中至少一部分含有乙酰氧基，叔丁氧基和与SiC键合的烷基的硅化合物是由烷基三乙酰氧基硅烷和叔丁醇在乙酸水溶液中的反应得到的。

    Room temperature crosslinkable compositions
    2.
    发明授权
    Room temperature crosslinkable compositions 失效
    室温可交联组合物

    公开(公告)号：US4801673A

    公开(公告)日：1989-01-31

    申请号：US69749

    申请日：1987-07-06

    申请人： Erhard Bosch ,  Franz Neuhauser ,  August Schiller ,  Oswin Sommer

    发明人： Erhard Bosch ,  Franz Neuhauser ,  August Schiller ,  Oswin Sommer

    IPC分类号： C08L83/04 ,  C08K5/54 ,  C08K5/549 ,  C08G77/04

    CPC分类号： C08K5/5406 ,  Y10S528/901

    摘要： Compositions which are storable under anhydrous conditions, but when exposed to atmospheric moisture crosslink at room temperature to form elastomers comprising a diorganopolysiloxane having one Si-bonded hydroxyl group in each of its terminal units, and a cyclic silane of the formula ##STR1## where R represents a divalent hydrocarbon radical, R.sup.1 represents the same or different monovalent hydrocarbon radicals, which can be substituted by an alkoxy group, and R.sup.2 represents hydrogen or an alkyl or aminoalkyl radical in which the silicon atom of the cyclic silane is bonded to a nitrogen atom and to two monovalent hydrocarbon radicals, which can be substituted with an alkoxy group via oxygen and to a hydrocarbon radical via carbon.

    摘要翻译： 可在无水条件下储存的组合物，但当暴露于大气中的水分在室温下交联以形成包含其每个末端单元中具有一个与Si键合的羟基的二有机聚硅氧烷的弹性体，以及具有下式的环状硅烷：其中R 表示二价烃基，R 1表示可被烷氧基取代的相同或不同的一价烃基，R 2表示氢或环状硅烷的硅原子与氮原子键合的烷基或氨基烷基 和可以被烷氧基经由氧取代的两个一价烃基和通过碳取代烃基。

    Organopolysiloxanes having retarded skin formation
    3.
    发明授权
    Organopolysiloxanes having retarded skin formation 失效
    有机聚硅氧烷延缓皮肤形成

    公开(公告)号：US4399267A

    公开(公告)日：1983-08-16

    申请号：US401809

    申请日：1982-07-26

    申请人： Erhard Bosch ,  Ingo Craubner ,  Norman Dorsch ,  August Schiller ,  Oswin Sommer

    发明人： Erhard Bosch ,  Ingo Craubner ,  Norman Dorsch ,  August Schiller ,  Oswin Sommer

    IPC分类号： C09K3/10 ,  C08K5/5415 ,  C08K5/544 ,  C08L83/00 ,  C08L83/04 ,  C08G77/22

    CPC分类号： C08K5/54 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/26 ,  C08G77/28 ,  Y10S528/901

    摘要： The invention relates to organopolysiloxane compositions which are stable when stored under anhydrous conditions, but when exposed to moisture cure to an elastomer containing (a) a diorganopolysiloxane having terminal condensable groups, (b) a silicon compound having 3 amino groups bonded to silicon via nitrogen and/or oxime groups bonded to silicon via oxygen per molecule and (c) a silicon compound having at least one thiol group selected from mercapto-functional silanes or siloxanes. The presence of the mercapto-functional silanes or siloxanes substantially retards the formation of skin but does not substantially extend the cure time of the organopolysiloxanes compositions. These compositions are useful in, for example, screen printing, where a long skin-over time is desired.

    摘要翻译： 本发明涉及有机聚硅氧烷组合物，其在无水条件下储存时是稳定的，但当暴露于水分固化至含有（a）具有末端可缩合基团的二有机聚硅氧烷的弹性体时，（b）具有3个氨基的硅化合物通过氮键接到硅上， 和/或每分子通过氧键连接至硅的肟基团和（c）具有至少一个选自巯基官能硅烷或硅氧烷的硫醇基团的硅化合物。 巯基官能硅烷或硅氧烷的存在基本上延缓了皮肤的形成，但基本上延长了有机聚硅氧烷组合物的固化时间。 这些组合物可用于例如期望丝网印刷长时间的丝网印刷。

    Curable compositions and elastomers prepared therefrom
    6.
    发明授权
    Curable compositions and elastomers prepared therefrom 失效
    可固化组合物和由其制备的弹性体

    公开(公告)号：US4191817A

    公开(公告)日：1980-03-04

    申请号：US925909

    申请日：1978-07-19

    申请人： August Schiller ,  Eckhart Louis ,  Erhard Bosch ,  Karl Braunsperger

    发明人： August Schiller ,  Eckhart Louis ,  Erhard Bosch ,  Karl Braunsperger

    IPC分类号： C08L83/00 ,  C08L83/04 ,  C08G77/26

    CPC分类号： C08L83/04 ,  C08G77/045 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/26 ,  C08G77/46 ,  Y10S528/901 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31678

    摘要： Curable compositions which can be stored under anhydrous conditions, but when exposed to atmospheric moisture cross-link to form elastomers, which consists of (1) a diorganopolysiloxane having terminal condensable groups, (2) a silicon compound containing at least three hydrolyzable groups per molecule in which the hydrolyzable groups are amino groups bonded to silicon via nitrogen and/or oxime groups bonded to silicon via oxygen and (3) at least one additional component which improves adhesion of the elastomers obtained from said compositions to substrates, in which the additional component (3) is an organosilicon compound containing at least one siloxane-oxygen atom and at least one amino group which is bonded to silicon by carbon.

    摘要翻译： 可固化的组合物可以在无水条件下储存，但当暴露于大气中的水分交联形成弹性体时，其由（1）具有末端可缩合基团的二有机聚硅氧烷，（2）每分子含有至少三个可水解基团的硅化合物 其中所述可水解基团是通过经由氧键接到硅上的氮和/或肟基团与硅结合的氨基，和（3）至少一种另外的组分，其改善了由所述组合物获得的弹性体对底物的粘合性，其中附加组分 （3）是含有至少一个硅氧烷 - 氧原子和至少一个与碳键合的氨基的有机硅化合物。

    Compositions which can be crosslinked by radiation to form elastomers
    7.
    发明授权
    Compositions which can be crosslinked by radiation to form elastomers 失效
    可以通过辐射交联以形成弹性体的组合物

    公开(公告)号：US4929647A

    公开(公告)日：1990-05-29

    申请号：US221960

    申请日：1988-07-08

    申请人： Christa Burger ,  Johann Muller ,  Erhard Bosch

    发明人： Christa Burger ,  Johann Muller ,  Erhard Bosch

    IPC分类号： C08L83/05 ,  C08K3/00 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07 ,  C08L83/08

    CPC分类号： C08L83/06 ,  C08L83/08

    摘要： Compositions which can be crosslinked by radiation to form elastomers comprising (a) an organopolysiloxane containing triorganosiloxane units of the formulaH.sub.2 C=CHCXOR.sup.1 SiR.sub.2 O.sub.1/2in which R is selected from monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R.sup.1 is selected from divalent hydrocarbon radicals and divalent halogenated hydrocarbon radicals and X is selected from oxygen and sulfur, in which at least 80 percent of the siloxane units other than the triorganosiloxane units are diorganosiloxane units, where the SiC-bonded organic radicals of the triorganosiloxane units and the diorganosiloxane units are selected from monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, (b) a filler having a surface area of at least 50 m.sup.2 /g, and if necessary (c) a photoinitiator, where the organopolysiloxane (a) contains diorganosiloxane units in which one of the SiC-bonded organic radicals contains an aliphatic carbon-carbon double bond, and/or the compositions contain, in addition to components (a), (b) and if necessary (c), and at least one (d) organopolysiloxane resin containing units of the formulasR.sup.2.sub.3 SiO.sub.1/2 and R.sup.2 SiO.sub.3/2 and/or SiO.sub.4/2where R.sup.2 is selected from monovalent hydrocarbon radicals, halogenated hydrocarbon radicals and hydrogen, with the proviso that at least an average of 4 Si-bonded hydrogen atoms are present in each molecule of the polysiloxane resins, in which siloxane units of the formulaHSR.sup.1 SiROin an amount of from 0.1 to 5 such siloxane units per radical of the formulaH.sub.2 C=CHCXOR.sup.1,where R, R.sup.1 and X are the same as above, are excluded in organopolysiloxane (a) if the organopolysiloxane resin (d) is omitted from the compositions.

    摘要翻译： 可以通过辐射交联以形成弹性体的组合物，其包含（a）含有式H2C = CHCXOR1SiR2O1 / 2的三有机硅氧烷单元的有机聚硅氧烷，其中R选自一价烃基和卤代一价烃基，R 1选自二价烃基和 二价卤代烃基，X选自氧和硫，其中至少80％的除三有机硅氧烷单元之外的硅氧烷单元是二有机硅氧烷单元，其中三有机硅氧烷单元和二有机硅氧烷单元的与SiC键合的有机基团选自 一价烃基和卤化一价烃基，（b）表面积至少为50m 2 / g的填料，如果需要（c）光引发剂，其中有机聚硅氧烷（a）含有二有机硅氧烷单元，其中一种SiC 键合的有机基团含有脂族碳 - 碳双键， d）或组合物除了组分（a），（b）和必要的（c）外还含有至少一种含有式R23SiO1 / 2和R2SiO3 / 2和/或SiO4单元的有机聚硅氧烷树脂 / 2，其中R2选自单价烃基，卤代烃基和氢，条件是在聚硅氧烷树脂的每个分子中至少存在4个Si键合的氢原子的平均值，其中式HSR1SiRO的硅氧烷单元 如果从有机聚硅氧烷树脂（d）中省略有机聚硅氧烷树脂（d），则在有机聚硅氧烷（a）中不包括每一个式为H 2 C = CHCXOR 1，其中R，R 1和X与上述相同的硅氧烷单元为0.1至5个 组合物。

    Rendering building materials hydrophobic
    8.
    发明授权
    Rendering building materials hydrophobic 失效
    渲染建筑材料疏水

    公开(公告)号：US4076868A

    公开(公告)日：1978-02-28

    申请号：US681354

    申请日：1976-04-29

    申请人： Michael Roth ,  Erhard Bosch

    发明人： Michael Roth ,  Erhard Bosch

    IPC分类号： C04B41/49 ,  C04B41/64 ,  B05D3/12 ,  B32B13/12

    CPC分类号： C04B41/009 ,  C04B41/4927 ,  C04B41/4972 ,  C04B41/64

    摘要： A process for simultaneously cleaning and rendering building materials hydrophobic which comprises applying to the surface of the building material a solution of a hydrophobic agent having admixed therewith a filler having a surface area of at least 50 mg.sup.2 /g and after evaporation of the solvent, removing the filler residue.

    摘要翻译： 一种同时清洁和使建筑材料疏水的方法，其包括向建筑材料的表面施加具有与表面积至少为50mg2 / g的填料一起混合的疏水剂的溶液，并且在蒸发溶剂之后，除去 填料残渣。