公开(公告)号：US5460790A

公开(公告)日：1995-10-24

申请号：US38435

申请日：1993-03-29

申请人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

发明人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

IPC分类号： F01N3/22 ,  B01D53/86 ,  B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/02 ,  F01N3/08 ,  F01N3/20 ,  F01N3/24 ,  F01N3/28 ,  F01N3/30 ,  F01N3/32 ,  F01N13/02 ,  B01D53/34 ,  B01D53/94

CPC分类号： B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/0207 ,  F01N13/0097 ,  F01N3/0814 ,  F01N3/206 ,  F01N3/28 ,  F01N3/2807 ,  F01N3/2814 ,  F01N3/2828 ,  F01N3/2832 ,  F01N3/2846 ,  F01N3/2896 ,  F01N3/30 ,  F01N2250/12 ,  F01N2330/321 ,  F01N2330/322 ,  F01N2430/04 ,  F01N2470/18 ,  F01N2610/01 ,  F01N3/32 ,  Y02T10/22 ,  Y10T29/49345 ,  Y10T428/24149

摘要： A catalytic vessel for adsorbing catalytic metals, such as from automotive exhaust gases, and carrying out three-way catalysis includes an inlet at an upstream end, a plurality of catalytic chambers located downstream of the inlet, and an outlet. At least one of the catalytic chambers contains a plurality of sheet members preferably made of steel and adapted for deposition of a metal selected from the group of noble and non-noble metals, and more particularly from the group including platinum, rhodium, rhenium, palladium, and gold. The vessel may be used in a catalytic system which contains a liquid source of metal catalysts, such as a solution or a gasoline additive, from which the metal catalysts are added to a combustion system, and the catalytic vessel, which collects the metal catalysts and is a site for three-way catalytic conversion of starting materials such as automotive emissions to final products.

摘要翻译： 用于吸附催化金属（例如来自汽车废气）和进行三元催化的催化容器包括在上游端的入口，位于入口下游的多个催化室和出口。 催化室中的至少一个包含多个优选由钢制成并适于沉积选自贵金属和非贵金属的金属的片状部件，更具体地，包括铂，铑，铼，钯 和黄金。 该容器可以用于催化体系，该催化体系含有金属催化剂的液体源，例如将金属催化剂从其中加入到燃烧系统中的溶液或汽油添加剂，以及收集金属催化剂的催化容器和 是将汽车排放物等原料三元催化转化成最终产品的场所。

公开(公告)号：US6152972A

公开(公告)日：2000-11-28

申请号：US38426

申请日：1993-03-29

申请人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  VEniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

发明人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  VEniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

IPC分类号： C10L1/12 ,  C10L1/30 ,  C10L10/00

CPC分类号： C10L10/06 ,  C10L1/1225 ,  C10L1/305 ,  C10L10/02

摘要： Catalytic metal additives that directly dissolve in gasoline in concentrations providing efficient and economical three-way catalysis of exhaust gases from internal combustion engines. The additives are compounds of noble (e.g., Pt, Pd, Au and Rh) or non-noble (e.g., Re) metals. The preferred compounds have polar metal ligand bonds, preferably with inorganic ligands such as halogens, oxygen, etc., and/or salts with highly ionic (polarizable) cations such as of alkali metals. The preferred additive is a combination of X.sub.2 PtCl.sub.6, RhCl.sub.3 and XReO.sub.4, where X=K, Rh or Cs. A combination of these finely ground materials is fabricated into a briquette or filter which is deposited in the gas tank or placed in a gas line. The catalytic metals are carried by the exhaust gases through the exhaust system where they are deposited on surfaces of the system to convert toxic emissions. In this way, the invention allows for the delivery of efficient gasoline additives without the use of solvents or extraneous agents.

摘要翻译： 直接溶于汽油的催化金属添加剂，其浓度为内燃机排气提供了有效和经济的三元催化作用。 添加剂是贵金属（例如Pt，Pd，Au和Rh）或非贵金属（例如Re）金属的化合物。 优选的化合物具有极性金属配体键，优选具有无机配体如卤素，氧等，和/或与高离子（可极化）阳离子如碱金属的盐。 优选的添加剂是X2PtCl6，RhCl3和XReO4的组合，其中X = K，Rh或Cs。 将这些精细研磨的材料的组合制成沉积在气罐中或放置在气体管线中的团块或过滤器。 催化金属由废气通过排气系统运送，在那里它们沉积在系统的表面上以转化有毒排放物。 以这种方式，本发明允许在不使用溶剂或外来物质的情况下递送有效的汽油添加剂。

公开(公告)号：US5604980A

公开(公告)日：1997-02-25

申请号：US512611

申请日：1995-08-08

申请人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

发明人： Alexander Shustorovich ,  Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Nikolai Moiseev ,  Aleksandr Bragin

IPC分类号： F01N3/22 ,  B01D53/86 ,  B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/02 ,  F01N3/08 ,  F01N3/20 ,  F01N3/24 ,  F01N3/28 ,  F01N3/30 ,  F01N3/32 ,  F01N13/02 ,  B23P15/00

CPC分类号： B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/0207 ,  F01N13/0097 ,  F01N3/0814 ,  F01N3/206 ,  F01N3/28 ,  F01N3/2807 ,  F01N3/2814 ,  F01N3/2828 ,  F01N3/2832 ,  F01N3/2846 ,  F01N3/2896 ,  F01N3/30 ,  F01N2250/12 ,  F01N2330/321 ,  F01N2330/322 ,  F01N2430/04 ,  F01N2470/18 ,  F01N2610/01 ,  F01N3/32 ,  Y02T10/22 ,  Y10T29/49345 ,  Y10T428/24149

摘要： A catalytic vessel for adsorbing catalytic metals, such as from automotive exhaust gases, and carrying out three-way catalysis includes an inlet at an upstream end, a plurality of catalytic chambers located downstream of the inlet, and an outlet. At least one of the catalytic chambers contains a plurality of sheet members preferably made of steel and adapted for deposition of a metal selected from the group of noble and non-noble metals, and more particularly from the group consisting of platinum, rhodium, rhenium, palladium, and gold. The vessel may be used in a catalytic system which contains a liquid source of metal catalysts, such as a solution or a gasoline additive, means for adding metal catalysts to a combustion system, and the catalytic vessel, which collects the metal catalysts and is a site for three-way catalytic conversion of starting materials such as automotive emissions to final products.

摘要翻译： 用于吸附催化金属（例如来自汽车废气）和进行三元催化的催化容器包括在上游端的入口，位于入口下游的多个催化室和出口。 催化室中的至少一个包含多个优选由钢制成并适于沉积选自贵金属和非贵金属的金属，特别是由铂，铑，铼， 钯和金。 该容器可用于含有金属催化剂的液体源（例如溶液或汽油添加剂），用于向燃烧系统中添加金属催化剂的装置的催化体系以及收集金属催化剂的催化容器 将汽车排放物等原料三元催化转化成最终产品的现场。

公开(公告)号：US5525316A

公开(公告)日：1996-06-11

申请号：US334281

申请日：1994-11-04

申请人： Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Aleksandr Bragin ,  Nikolai Moiseev

发明人： Eugene Shustorovich ,  Richard Montano ,  Konstantin Solntsev ,  Yuri Buslaev ,  Veniamin Kalner ,  Aleksandr Bragin ,  Nikolai Moiseev

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/00 ,  B01J23/10 ,  B01J23/36 ,  B01J27/13 ,  B01J31/00 ,  B01J31/02 ,  B01J31/20 ,  B01J31/30 ,  B01D53/56 ,  B01D53/62 ,  B01D53/72

CPC分类号： B01J31/30 ,  B01D53/945 ,  B01J23/36 ,  B01J27/13 ,  B01J31/0204 ,  B01J31/0244 ,  Y02T10/22

摘要： A catalyst solution comprising one or more compounds of a metal catalyst and an organic solvent selected from the group consisting of a glycol derivative, an alkyl pyrrolidone, and an alkoxy ethyl ether, wherein no additional chloride-containing compounds are added to the solution. The metal can be selected from the group consisting of platinum, rhenium and rhodium. The compounds can be selected from the group consisting of H.sub.2 PtCl.sub.6.6H.sub.2 O, Re.sub.2 (CO).sub.10, Re.sub.2 O.sub.7, LiReO.sub.4 and RhCl.sub.3.4H.sub.2 O. The catalytic solutions are useful in conversion of pollutants from automotive engines and the like. In a particularly preferred embodiment, the solution contains three metals: platinum, rhenium, and rhodium.

摘要翻译： 一种催化剂溶液，其包含一种或多种金属催化剂和选自二醇衍生物，烷基吡咯烷酮和烷氧基乙基醚的有机溶剂的化合物，其中不向溶液中加入另外的含氯化合物。 金属可以选自铂，铼和铑。 该化合物可以选自H 2 PtCl 6·6H 2 O，Re 2（CO）10，Re 2 O 7，LiReO 4和RhCl 3·4H 2 O。 催化溶液可用于汽车发动机等污染物的转化。 在特别优选的实施方案中，溶液含有三种金属：铂，铼和铑。

公开(公告)号：US5387569A

公开(公告)日：1995-02-07

申请号：US841356

申请日：1992-02-25

申请人： Eugene Shustorovich ,  Richard Montano ,  Aleksandr Bragin ,  Veniamin Kalner ,  Konstantin Solntsev ,  Nikolai Moiseev ,  Yuri Buslaev

发明人： Eugene Shustorovich ,  Richard Montano ,  Aleksandr Bragin ,  Veniamin Kalner ,  Konstantin Solntsev ,  Nikolai Moiseev ,  Yuri Buslaev

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/00 ,  B01J23/10 ,  B01J23/36 ,  B01J27/13 ,  B01J31/00 ,  B01J31/02 ,  B01J31/20 ,  B01J31/30 ,  B01J31/28

CPC分类号： B01J31/30 ,  B01D53/945 ,  B01J23/36 ,  B01J27/13 ,  B01J31/0204 ,  B01J31/0244 ,  Y02T10/22

摘要： A catalyst solution comprising one or more compounds of a metal catalyst and an organic solvent selected from the group consisting of a glycol derivative, an alkyl pyrrolidone, and an alkoxy ethyl ether, wherein no additional chloride-containing compounds are added to the solution. The metal can be selected from the group consisting of platinum, rhenium and rhodium. The compounds can be selected from the group consisting of H.sub.2 PtCl.sub.6.6H.sub.2 O, Re.sub.2 (CO).sub.10, Re.sub.2 O.sub.7, LiReO.sub.4 and RhCl.sub.3.4H.sub.2 O. The catalytic solutions are useful in conversion of pollutants from automotive engines and the like. In a particularly preferred embodiment, the solution contains three metals: platinum, rhenium, and rhodium.

摘要翻译： 一种催化剂溶液，其包含一种或多种金属催化剂和选自二醇衍生物，烷基吡咯烷酮和烷氧基乙基醚的有机溶剂的化合物，其中不向溶液中加入另外的含氯化合物。 金属可以选自铂，铼和铑。 该化合物可以选自H 2 PtCl 6·6H 2 O，Re 2（CO）10，Re 2 O 7，LiReO 4和RhCl 3·4H 2 O。 催化溶液可用于汽车发动机等污染物的转化。 在特别优选的实施方案中，溶液含有三种金属：铂，铼和铑。

公开(公告)号：US5322671A

公开(公告)日：1994-06-21

申请号：US840860

申请日：1992-02-25

申请人： Eugene Shustorovich ,  Richard Montano ,  Veniamin Kalner ,  Aleksandr Bragin ,  Nikolai Moiseev ,  Konstantin Solntsev ,  Yuri Buslayev

发明人： Eugene Shustorovich ,  Richard Montano ,  Veniamin Kalner ,  Aleksandr Bragin ,  Nikolai Moiseev ,  Konstantin Solntsev ,  Yuri Buslayev

IPC分类号： F01N3/22 ,  B01D53/86 ,  B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/02 ,  F01N3/08 ,  F01N3/20 ,  F01N3/24 ,  F01N3/28 ,  F01N3/30 ,  F01N3/32 ,  F01N13/02 ,  B01J8/08

CPC分类号： F01N3/2896 ,  B01J23/40 ,  B01J23/72 ,  B01J23/745 ,  B01J35/04 ,  B01J37/0207 ,  F01N13/0097 ,  F01N3/0814 ,  F01N3/206 ,  F01N3/28 ,  F01N3/2807 ,  F01N3/2814 ,  F01N3/2828 ,  F01N3/2832 ,  F01N3/2846 ,  F01N3/30 ,  F01N2250/12 ,  F01N2330/321 ,  F01N2330/322 ,  F01N2430/04 ,  F01N2470/18 ,  F01N2610/01 ,  F01N3/32 ,  Y02T10/22

摘要： A catalyst vessel including an inlet at an upstream end, a plurality of catalytic chambers located downstream of the conduit, wherein at least two chambers are connected by a plate having one or more orifices therein to permit gas flow through from the first chamber to the second chamber, and wherein at least one surface in the chamber is adapted for deposition of a metal selected from the group consisting of platinum, rhodium, and rhenium, and an outlet at its downstream end.

摘要翻译： 一种催化剂容器，包括位于上游端的入口，位于导管下游的多个催化室，其中至少两个室通过其中具有一个或多个孔的板连接以允许气体从第一室流入第二室 并且其中所述室中的至少一个表面适于沉积选自铂，铑和铼的金属以及在其下游端的出口。

公开(公告)号：US5386690A

公开(公告)日：1995-02-07

申请号：US118835

申请日：1993-09-08

申请人： Eugene Shustorovich ,  Veniamin Kalner ,  Konstantin Solntsev ,  Nikolai Moiseev ,  Yuri Buslayev ,  Richard Montano ,  Aleksandr Bragin

发明人： Eugene Shustorovich ,  Veniamin Kalner ,  Konstantin Solntsev ,  Nikolai Moiseev ,  Yuri Buslayev ,  Richard Montano ,  Aleksandr Bragin

IPC分类号： B01D53/86 ,  B01D53/94 ,  F01N3/20 ,  F01N3/28 ,  F02M27/02

CPC分类号： B01D53/9445 ,  B01D53/945 ,  B01D53/9454 ,  B01D53/9495 ,  F01N3/206 ,  F01N3/2896 ,  F02M27/02 ,  F01N2610/01 ,  Y02T10/22

摘要： A catalyst system comprising a metal catalyst in a liquid catalyst solution, means for adding metal catalyst from the solution to a combustion system, and a catalyst collector for collecting the metal catalyst which serves as a reaction vessel. A method for converting emissions from a combustion chamber comprising providing a source of metal catalyst in a liquid solution; adding the metal catalyst to a combustion system; carrying the metal catalyst to a catalyst collector: depositing the metal catalyst on a solid surface in the catalyst collector; and converting the emissions for the combustion chamber by contacting the emissions and the metal catalyst. Preferably, the metal catalyst solution contains a plurality of metals.

摘要翻译： 在液体催化剂溶液中含有金属催化剂的催化剂体系，将溶液中的金属催化剂添加到燃烧体系中的催化剂体系，以及收集用作反应容器的金属催化剂的催化剂收集体。 一种用于转换来自燃烧室的排放物的方法，包括在液体溶液中提供金属催化剂源; 将金属催化剂加入到燃烧系统中; 将金属催化剂携带到催化剂收集器上：将金属催化剂沉积在催化剂收集器的固体表面上; 以及通过使排放物和金属催化剂接触来转化燃烧室的排放物。 优选地，金属催化剂溶液含有多种金属。