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公开(公告)号：US20170305810A1
公开(公告)日：2017-10-26
申请号：US15646889
申请日：2017-07-11
发明人： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC分类号： C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
摘要： Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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公开(公告)号：US11951463B2
公开(公告)日：2024-04-09
申请号：US16497239
申请日：2018-03-19
发明人： Matthew S. Ide , Brett T. Loveless , Doron Levin , William W. Lonergan , Matthew J. Vincent , Wei-Ping Tai , Federico Barrai
CPC分类号： B01J29/7038 , B01J29/08 , B01J29/18 , B01J29/70 , B01J29/7007 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1071 , C07C2/66 , C07C2529/70
摘要： Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d50). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or cumene) which exhibit improved yield of the mono-alkylated aromatic compound using alkylation catalysts comprising one or more of these catalyst compositions.
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3.发明申请公开(公告)号：US20200377431A1
公开(公告)日：2020-12-03
申请号：US16497256
申请日：2018-03-19
摘要： Methods for removing impurities from a hydrocarbon stream using a guard bed material are disclosed. The guard bed material includes compositions which comprises a zeolite and a mesoporous support or binder. The zeolite has a Constraint Index of less than 3. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d50), a pore volume of less than 1 cc/g, and an alumina content of greater than 75%, by weight. Also disclosed are processes for producing mono-alkylated aromatic compounds (e.g., ethylbenzene or cumene) using impure feed streams that are treated by the disclosed methods to remove impurities which act as catalyst poisons to downstream alkylation and/or transalkylation catalysts.
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公开(公告)号：US20200179913A1
公开(公告)日：2020-06-11
申请号：US16479179
申请日：2018-02-07
发明人： Matthew S. Ide , Doron Levin , Wenyih F. Lai , Ivy D. Johnson , Scott J. Weigel , Brett T. Loveless
摘要： Catalyst composition which comprises a first zeolite having a BEA* framework type and a second zeolite having a MOR framework type and a mesopore surface area of greater than 30 m2/g is disclosed. These catalyst compositions are used to remove catalyst poisons from untreated feed streams having one or more impurities which cause deactivation of the downstream catalysts employed in hydrocarbon conversion processes, such as those that produce mono-alkylated aromatic compounds.
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公开(公告)号：US11654423B2
公开(公告)日：2023-05-23
申请号：US16479179
申请日：2018-02-07
发明人： Matthew S. Ide , Doron Levin , Wenyih F. Lai , Ivy D. Johnson , Scott J. Weigel , Brett T. Loveless
IPC分类号： B01J29/80 , B01J29/18 , C07C2/66 , B01J29/70 , B01J35/10 , B01J37/00 , C07C6/12 , C07C7/13 , B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/70 , B01J29/7007 , B01J35/1004 , B01J35/1061 , B01J37/0009 , C07C2/66 , C07C6/126 , C07C7/13 , B01J2029/062 , C07C2529/18 , C07C2529/70 , C07C2529/80
摘要： Catalyst composition which comprises a first zeolite having a BEA* framework type and a second zeolite having a MOR framework type and a mesopore surface area of greater than 30 m2/g is disclosed. These catalyst compositions are used to remove catalyst poisons from untreated feed streams having one or more impurities which cause deactivation of the downstream catalysts employed in hydrocarbon conversion processes, such as those that produce mono-alkylated aromatic compounds.
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公开(公告)号：US20190314794A1
公开(公告)日：2019-10-17
申请号：US16097666
申请日：2017-04-13
IPC分类号： B01J29/70 , B01J29/08 , B01J29/18 , B01J35/00 , B01J37/08 , B01J37/14 , B01J38/02 , B01J38/16 , C07C2/66
摘要： The present disclosure relates to a process for producing a mono-alkylated aromatic compound using a treated catalyst made by a method of this invention is disclosed. The method comprises the steps of heating an untreated catalyst in the presence of a gaseous stream having a dew point temperature less than about 5° C. to form a treated catalyst. The treatment is effective to improve the activity and selectivity of the catalyst.
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公开(公告)号：US09809505B1
公开(公告)日：2017-11-07
申请号：US15646889
申请日：2017-07-11
发明人： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC分类号： C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
摘要： Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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公开(公告)号：US11230515B2
公开(公告)日：2022-01-25
申请号：US16497256
申请日：2018-03-19
摘要： Methods for removing impurities from a hydrocarbon stream using a guard bed material are disclosed. The guard bed material includes compositions which comprises a zeolite and a mesoporous support or binder. The zeolite has a Constraint Index of less than 3. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 μm at 50% of the cumulative pore size distribution (d50), a pore volume of less than 1 cc/g, and an alumina content of greater than 75%, by weight. Also disclosed are processes for producing mono-alkylated aromatic compounds (e.g., ethylbenzene or cumene) using impure feed streams that are treated by the disclosed methods to remove impurities which act as catalyst poisons to downstream alkylation and/or transalkylation catalysts.
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公开(公告)号：US10821425B2
公开(公告)日：2020-11-03
申请号：US16097666
申请日：2017-04-13
IPC分类号： B01J29/00 , B01J29/70 , B01J29/08 , B01J29/18 , B01J35/00 , B01J37/08 , B01J37/14 , B01J38/02 , B01J38/16 , C07C2/66
摘要： The present disclosure relates to a process for producing a mono-alkylated aromatic compound using a treated catalyst made by a method of this invention is disclosed. The method comprises the steps of heating an untreated catalyst in the presence of a gaseous stream having a dew point temperature less than about 5° C. to form a treated catalyst. The treatment is effective to improve the activity and selectivity of the catalyst.
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公开(公告)号：US20180251413A1
公开(公告)日：2018-09-06
申请号：US15899096
申请日：2018-02-19
IPC分类号： C07C6/10 , B01J29/70 , B01J29/08 , C07C15/073 , C07C15/04
CPC分类号： C07C6/10 , B01J29/08 , B01J29/18 , B01J29/7007 , B01J29/7038 , C07C6/126 , C07C15/04 , C07C15/073 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , Y02P20/52
摘要： Disclosed are selectivated transalkylation catalyst compositions and methods of making the same. The selectivated transalkylation catalyst compositions have a zeolite framework structure of MWW, FAU, BEA*, or MOR, or mixtures thereof, and are selectivated with a selectivating solution. The selectivating solution includes a dissolved ion of at least one element in Group 1, Group 2, Group 15, Group 16, or Group 17 of the Periodic Table. Also disclosed are processes of producing ethylbenzene and cumene using the selectivated transalkylation catalyst compositions.
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