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公开(公告)号：US09732013B2
公开(公告)日：2017-08-15
申请号：US14829399
申请日：2015-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC classification number: C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
Abstract: Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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公开(公告)号：US20160090332A1
公开(公告)日：2016-03-31
申请号：US14829399
申请日：2015-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC classification number: C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
Abstract: Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
Abstract translation: 提供了用于提高含氧化合物进料转化期间芳烃产率的方法。 含氧化合物进料可以含有含氧化合物的混合物，包括氢指数小于2的一种或多种化合物，使得含氧化合物混合物的有效氢指数在约1.4和1.9之间。 还提供了用热解油共同进料将含氧化合物的混合物与有效氢指数大于约1转化的方法。 通过将热解油引入反应体系中，可以减少或最小化共解热解油中的困难。 这可以允许不同的热解油和甲醇或另一种含氧化合物进料的混合物在各种进料入口处被引入反应体系中。
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公开(公告)号：US09809505B1
公开(公告)日：2017-11-07
申请号：US15646889
申请日：2017-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC classification number: C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
Abstract: Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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Patent Agency Ranking
公开(公告)号：US09783463B2
公开(公告)日：2017-10-10
申请号：US14829199
申请日：2015-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Frank Hershkowitz , Stephen H. Brown , Paul F. Keusenkothen , Tilman W. Beutel , Stephen J. McCarthy , Michel Daage , Rohit Vijay , Samia Ilias
CPC classification number: C07C2/864 , C07C5/35 , C07C2529/40 , C07C11/24 , C07C15/08
Abstract: Methods are provided for forming aromatic compounds from a highly unsaturated aliphatic feeds optionally in combination with methanol. The method can include dehydrogenating a feed containing at least about 50 vol % C1-C4 alkanes under dehydrogenation conditions to form a dehydrogenation effluent containing at least about 25 vol % alkynes. Alternatively, other sources of alkyne-containing feeds can be used. At least a portion of the alkyne-containing feed can then be converted under effective conversion conditions to form a conversion effluent comprising a hydrocarbon product containing aromatic compounds.
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公开(公告)号：US20170305810A1
公开(公告)日：2017-10-26
申请号：US15646889
申请日：2017-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC classification number: C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
Abstract: Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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公开(公告)号：US20160090334A1
公开(公告)日：2016-03-31
申请号：US14829199
申请日：2015-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Frank Hershkowitz , Stephen H. Brown , Paul F. Keusenkothen , Tilman W. Beutel , Stephen J. McCarthy , Michel Daage , Rohit Vijay , Samia IIias
IPC: C07C2/86 , C07C2/52 , C07C5/48 , C07C29/151
CPC classification number: C07C2/864 , C07C5/35 , C07C2529/40 , C07C11/24 , C07C15/08
Abstract: Methods are provided for forming aromatic compounds from a highly unsaturated aliphatic feeds optionally in combination with methanol. The method can include dehydrogenating a feed containing at least about 50 vol % C1-C4 alkanes under dehydrogenation conditions to form a dehydrogenation effluent containing at least about 25 vol % alkynes. Alternatively, other sources of alkyne-containing feeds can be used. At least a portion of the alkyne-containing feed can then be converted under effective conversion conditions to form a conversion effluent comprising a hydrocarbon product containing aromatic compounds.
Abstract translation: 提供了用于从任选与甲醇组合的高度不饱和脂族进料形成芳族化合物的方法。 该方法可以包括在脱氢条件下使包含至少约50体积％C 1 -C 4烷烃的进料脱氢以形成含有至少约25体积％炔的脱氢流出物。 或者，可以使用其它来源的含炔源的饲料。 然后可以在有效的转化条件下转化含炔烃的进料的至少一部分以形成包含含有芳族化合物的烃产物的转化流出物。
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公开(公告)号：US09327260B2
公开(公告)日：2016-05-03
申请号：US13768640
申请日：2013-02-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. Di Nicolantonio , John J. Waldrop
IPC: B01J8/18 , B01J10/00 , C10B55/10 , C10G9/00 , C10G9/36 , C10G51/02 , C10B55/00 , B01J19/00 , B01J19/24 , B04C7/00 , B01D21/26 , B01D45/12 , C10G9/34 , C10G51/00
CPC classification number: B01J10/005 , C10B55/00 , C10B55/10 , C10G9/005 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10G2400/30
Abstract: This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker™, visbreaker and catalytic hydrovisbreaker) where at least 30 wt % of the vacuum resid is converted to material boiling below 1050° F. (566° C.); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt % olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
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公开(公告)号：US08784743B2
公开(公告)日：2014-07-22
申请号：US14136245
申请日：2013-12-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul F. Keusenkothen , Stephen H. Brown
IPC: B01J14/00
CPC classification number: B01D3/009 , C10G9/007 , C10G9/14 , C10G9/36 , C10G45/00 , C10G45/44 , C10G69/00 , C10G69/06 , C10G2300/107 , C10G2400/20 , C10G2400/30
Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is treated by hydroprocessing and visbreaking and then passed to a steam cracker to obtain a product comprising olefins.
Abstract translation: 本发明涉及加氢处理和蒸汽裂化的整合。 通过加氢处理和减粘裂化处理包含粗制或残渣的馏分的进料，然后通入蒸汽裂化器得到包含烯烃的产物。
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