公开(公告)号：US10243128B2

公开(公告)日：2019-03-26

申请号：US15451786

申请日：2017-03-07

Applicant: FUJIFILM Corporation

Inventor： Naoyuki Hayashi ,  Hiroki Sugiura ,  Toshiaki Aoai

IPC: H01L35/04 ,  H01L35/28 ,  H01L35/32 ,  H01L35/24 ,  B82Y30/00 ,  H01L35/30 ,  H01L35/34 ,  H01L35/02 ,  C01B32/158

Abstract: The present invention has a first substrate having a high thermal conduction portion which has a thermal conductivity higher than that of other regions in a plane direction, a thermoelectric conversion layer which is formed on the first substrate, consists of an organic material, and has a thermoelectric conversion material having a positive Seebeck coefficient, a second substrate which is formed on the thermoelectric conversion layer and has a high thermal conduction portion having a thermal conductivity higher than that of other regions in the plane direction and in which the high thermal conduction portion does not completely overlap the high thermal conduction portion of the first substrate in the plane direction, and a pair of electrodes which are connected to the thermoelectric conversion layer and consist of a metal material having a negative Seebeck coefficient. As a result, there are provided a thermoelectric conversion element and a thermoelectric conversion module which can generate heat with excellent efficiency by using a thermoelectric conversion material consisting of an organic material.

公开(公告)号：US10580953B2

公开(公告)日：2020-03-03

申请号：US15449032

申请日：2017-03-03

Applicant: FUJIFILM Corporation

Inventor： Hiroki Sugiura ,  Yuzo Nagata ,  Kimiatsu Nomura ,  Toshiaki Aoai

IPC: H01L35/24 ,  H01L35/26 ,  H01L35/22 ,  H01L35/32 ,  H01L35/34 ,  B82Y40/00 ,  B82Y30/00

Abstract: A thermoelectric conversion layer contains carbon nanotubes and a surfactant, and in an upper portion and a lower portion and/or a side face end surface and a center, a mass ratio obtained by dividing the carbon nanotubes by the surfactant is higher in the upper portion and/or the end surface than in the other portions. A layer which contains carbon nanotubes and a surfactant and will become a thermoelectric conversion element is formed, the layer is washed with a washing agent which dissolves the surfactant but does not dissolve the carbon nanotubes. Accordingly, provided is a thermoelectric conversion element and a thermoelectric conversion module, each having not only high adhesiveness between the substrate and the thermoelectric conversion layer but also excellent thermoelectric conversion performance; and methods for manufacturing the thermoelectric conversion element and the thermoelectric conversion module.

公开(公告)号：US09445501B2

公开(公告)日：2016-09-13

申请号：US14034676

申请日：2013-09-24

Applicant: FUJIFILM Corporation

Inventor： Ryo Nishio ,  Toshiaki Aoai ,  Naoyuki Hayashi

IPC: H01B1/00 ,  B05D5/12 ,  H05K1/09 ,  C08J5/18 ,  H01B1/12 ,  C08G61/02 ,  C08G61/10 ,  C08G61/12 ,  C09D165/00 ,  C08L65/00 ,  C08K5/03 ,  C08K5/19 ,  C08K5/375 ,  H01L51/00

CPC classification number: H05K1/09 ,  C08G61/02 ,  C08G61/10 ,  C08G61/126 ,  C08G2261/312 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/3422 ,  C08G2261/514 ,  C08G2261/76 ,  C08G2261/792 ,  C08J5/18 ,  C08J2300/12 ,  C08J2365/00 ,  C08K5/03 ,  C08K5/19 ,  C08K5/375 ,  C08L65/00 ,  C09D165/00 ,  H01B1/124 ,  H01B1/127 ,  H01L51/0036 ,  Y10T428/31533

Abstract: An electrically conductive composition, containing an electrically conductive polymer, and an onium salt compound as a dopant to the electrically conductive polymer, an electrically conductive film formed by shaping the composition and a method of producing the electrically conductive film.

Abstract translation: 包含导电聚合物的导电组合物和作为导电聚合物的掺杂剂的鎓盐化合物，通过使组合物成形而形成的导电膜和制备导电膜的方法。

公开(公告)号：US20140251407A1

公开(公告)日：2014-09-11

申请号：US14219703

申请日：2012-09-28

Applicant: FUJIFILM Corporation

Inventor： Ryo Nishio ,  Toshiaki Aoai ,  Naoyuki Hayashi

IPC: H01L35/24

CPC classification number: H01L35/24 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/3142 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/3229 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/3422 ,  C08G2261/55 ,  C08K3/041 ,  H01L35/32 ,  C08L65/00

Abstract: A thermoelectric conversion material containing an electrically conductive polymer and a thermal excitation assist agent, wherein the thermal excitation assist agent is a compound that does not form a doping level in the electrically conductive polymer, an energy level of LUMO (lowest unoccupied molecular orbital) of the thermal excitation assist agent and an energy level of HOMO (highest occupied molecular orbital) of the electrically conductive polymer satisfy following numerical expression (I): 0.1 eV≦|HOMO of an electrically conductive polymer|−|LUMO of a thermal excitation assistant agent|≦1.9 eV wherein, in numerical expression (I), |HOMO of an electrically conductive polymer| represents an absolute value of an energy level of HOMO of the electrically conductive polymer, and |LUMO of a thermal excitation assist agent| represents an absolute value of an energy level of LUMO of the thermal excitation assist agent, respectively.

Abstract translation: 一种含有导电聚合物和热激发助剂的热电转换材料，其中热激发辅助剂是在导电聚合物中不形成掺杂水平的化合物，LUMO（最低未占分子轨道的最低未占分子轨道）的能级 热激发辅助剂和导电聚合物的HOMO（最高占据分子轨道）的能级满足以下数值表达式（I）：导电聚合物的0.1eV＆lt; nIE | | HOMO | - 热激发助剂的LUMO |＆nlE; 1.9eV其中，在数字表达式（I）中，导电聚合物的| HOMO | 表示导电性聚合物的HOMO的能级的绝对值，热激励辅助剂的| LUMO | 分别表示热激励辅助剂的LUMO的能级的绝对值。

公开(公告)号：US09356217B2

公开(公告)日：2016-05-31

申请号：US14040086

申请日：2013-09-27

Applicant: FUJIFILM Corporation

Inventor： Toshiaki Aoai ,  Ryo Nishio ,  Naoyuki Hayashi

IPC: H01L35/12 ,  H01L51/44 ,  B82Y30/00 ,  H01B1/24 ,  C09D165/00 ,  C08K5/00 ,  C08K5/03 ,  C08K5/372 ,  C08K7/24 ,  C08G61/04 ,  C08G61/12 ,  C08K5/43 ,  C08K5/55

CPC classification number: H01L35/12 ,  B82Y30/00 ,  C08G61/04 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/135 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/3422 ,  C08G2261/51 ,  C08G2261/55 ,  C08G2261/76 ,  C08G2261/792 ,  C08G2261/90 ,  C08K3/041 ,  C08K5/0008 ,  C08K5/03 ,  C08K5/372 ,  C08K5/43 ,  C08K5/55 ,  C08K7/24 ,  C08K2201/011 ,  C09D165/00 ,  H01B1/24 ,  H01L51/444 ,  Y02E10/549 ,  Y02P20/129 ,  Y02P20/13 ,  Y02P70/521 ,  C08L65/00 ,  C08L101/12

Abstract: An electrically conductive composition, containing (A) a carbon nanotube, (B) an electrically conductive polymer, and (C) an onium salt compound, an electrically conductive film using the composition, and a method of producing the electrically conductive film.

Abstract translation: 包含（A）碳纳米管，（B）导电聚合物和（C）鎓盐化合物的导电组合物，使用该组合物的导电膜，以及制造导电膜的方法。