摘要:
Selective hydrogenation of a polyunsaturated hydrocarbon feed containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting said feed with a catalyst having an active phase of at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process involving at least: i) contacting said support with at least one solution containing at least one precursor of metal from group VIII; ii) contacting said support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) calcining to obtain metal from group VIII in oxide form; i) and ii) possibly being carried out separately, in any order, or simultaneously.
摘要:
A process is described for preparing a catalyst comprising at least one porous support and at least one metallic phase containing nickel and at least one metal M from group IB in a proportion such that the molar ratio M/Ni is in the range 0.005 to 0.5, said process comprising at least the following steps in succession: a1) depositing nickel on at least said support in order to obtain a supported nickel-based monometallic catalyst; b1) depositing, in the presence of at least one reducing gas and in the absence of any aqueous solvent, at least one organometallic compound of at least said metal M onto said monometallic catalyst.
摘要:
The invention concerns a catalyst comprising nickel on an aluminum oxide support. The aluminum oxide support has, in the calcined state, a diffractogram obtained by X ray diffractometry comprising peaks which correspond to the following interplanar spacings and relative intensities: Interplanar spacingsRelative intensities d (10−10 m )I/I0 (%) 5.03 to 5.221-5 4.56 to 4.60 1-10 4.06 to 4.101-5 2.80 to 2.85 5-20 2.7315-35 2.60 5-10 2.4335-40 2.2930-40 1.9960-95 1.9525-50 1.79 1-10 1.53 5-10 1.51 5-10 1.4140-60 1.39100 1.23 to 1.261-5 1.14 5-10 1.111-5 1.041-5 1.00 5-10 0.97 1-5.
摘要:
The invention concerns a catalyst comprising nickel on an aluminium oxide support. The aluminium oxide support has, in the calcined state, a diffractogram obtained by X ray diffractometry comprising peaks which correspond to the following interplanar spacings and relative intensities: Interplanar spacingsRelative intensities d (10−10 m )I/I0 (%) 5.03 to 5.22 1-5 4.56 to 4.60 1-10 4.06 to 4.10 1-5 2.80 to 2.85 5-20 2.7315-35 2.60 5-10 2.4335-40 2.2930-40 1.9960-95 1.9525-50 1.79 1-10 1.53 5-10 1.51 5-10 1.4140-60 1.39100 1.23 to 1.26 1-5 1.14 5-10 1.11 1-5 1.04 1-5 1.00 5-10 0.97 1-5