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公开(公告)号：US06465384B1
公开(公告)日：2002-10-15
申请号：US08481791
申请日：1995-06-07
申请人： Francis J. Timmers , James C. Stevens , David D. Devore , Robert K. Rosen , Jasson T. Patton , David R. Neithamer
发明人： Francis J. Timmers , James C. Stevens , David D. Devore , Robert K. Rosen , Jasson T. Patton , David R. Neithamer
IPC分类号： B01J3100
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F10/00 , Y10S526/943
摘要： Biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a &sgr;-complex or a &pgr;-complex in combination with strong Lewis acids, Bronsted acid salts, carbenium ion salts, salts containing a cationic oxidizing agent, or subjected to bulk electrolysis in the presence of compatible, inert non-coordinating anions form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
摘要翻译： 双环戊二烯基，与共轭二烯形成的第4族过渡金属络合物，其中二烯与形成σ-络合物或π-络合物的形式的结合到强路易斯酸，布朗斯台德酸盐，碳鎓离子盐，盐 含有阳离子氧化剂，或在相容的惰性非配位阴离子存在下进行本体电解形成用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。
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2.发明授权Polymerization process with biscyclopentadienyl diene complex containing catalysts 失效含有催化剂的双环戊二烯二烯络合物的聚合方法
公开(公告)号：US5616664A
公开(公告)日：1997-04-01
申请号：US474046
申请日：1995-06-07
IPC分类号： C07F17/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F36/02 , C08F38/00 , C08F210/08
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , Y10S526/901 , Y10S526/943
摘要： Olefins are polymerized by the use of catalysts comprising biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a .sigma.-complex or a .pi.-complex in combination with activating cocatalysts.
摘要翻译： 烯烃通过使用包含双环戊二烯基，由共轭二烯形成的第4族过渡金属络合物的催化剂聚合，其中二烯与Σ-复合物或π-复合物形式的过渡金属结合活化助催化剂结合。
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3.发明授权Group 4 metal diene complexes and addition polymerization catalysts therefrom 失效第4族金属二烯络合物及其加成聚合催化剂
公开(公告)号：US5486632A
公开(公告)日：1996-01-23
申请号：US267993
申请日：1994-06-28
CPC分类号： C07F17/00 , C08F10/00 , C08F10/02 , C08F4/65908 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
摘要翻译： 新型4族金属络合物，其含有一个且仅一个环状离域，阴离子，π键合基团，其中金属处于+4形式氧化态并具有桥连配体结构，也称为约束几何配合物和共轭二烯二价阴离子 配体基团 这种络合物的催化衍生物，包括新型的三嗪配合物; 以及其作为用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂的用途。
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4.发明授权Compatibilized blend of olefinic polymers and monovinylidene aromatic polymers 失效烯烃聚合物和单亚乙烯基芳族聚合物的相容共混物
公开(公告)号：US5460818A
公开(公告)日：1995-10-24
申请号：US226533
申请日：1994-04-12
IPC分类号： C08L23/00 , B65B5/00 , C08J5/18 , C08J9/00 , C08L23/02 , C08L23/04 , C08L23/06 , C08L25/02 , C08L25/04 , C08L25/06 , C08L23/10
摘要： A polymer blend composition comprising:(a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic .alpha.-olefin homopolymer or interpolymer, or an interpolymer of an .alpha.-olefin and a non-aromatic monomer interpolymerizable therewith;(b) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a homopolymer or interpolymer of monovinylidene aromatic monomers, or an interpolymer of monovinylidene aromatic monomer and a monomer interpolymerizable therewith other than an aliphatic .alpha.-olefin; and(c) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a substantially random interpolymer comprising an .alpha.-olefin and a vinylidene aromatic monomer. An expandable composition, comprising such polymer blend composition and an expanding agent; a foamed composition obtained by subjecting such an expandable composition to a foaming process; an article of manufacture molded from such a polymer blend composition; and a method of packaging using such a polymer blend composition.
摘要翻译： 一种聚合物共混组合物，其包含：（a）基于（a），（b）和（c）的脂肪族α-烯烃均聚物或互聚物的总重量的0.5〜99重量％ 可与其共聚的α-烯烃和非芳族单体; （b）基于单亚乙烯基芳族单体的均聚物或互聚物或单亚乙烯基芳族单体和单体的互聚物（a），（b）和（c））的总重量为0.5-99重量％ 除脂肪族α-烯烃以外可与其进行聚合; 和（c）基于包含α-烯烃和亚乙烯基芳族单体的基本上无规共聚体的（a），（b）和（c））的总重量的0.5至99重量％。 包含这种聚合物共混物组合物和膨胀剂的可发性组合物; 通过将这样的可发性组合物进行发泡处理获得的发泡组合物; 由这种聚合物共混组合物模制的制品; 以及使用这种聚合物共混组合物的包装方法。
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公开(公告)号：US5425872A
公开(公告)日：1995-06-20
申请号：US275579
申请日：1994-07-15
CPC分类号： C07F17/00 , B01J37/348 , C08F10/00 , C08F2420/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Group 4 metal complexes useful as addition polymerization catalysts are prepared by electrolysis of cyclopentadienyl metal complexes under inert electrolysis conditions.
摘要翻译： 可用作加成聚合催化剂的第4族金属络合物通过在惰性电解条件下电解环戊二烯基金属络合物来制备。
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公开(公告)号：US07943546B2
公开(公告)日：2011-05-17
申请号：US12434436
申请日：2009-05-01
申请人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC分类号： C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要： A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要翻译： 用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法，所述催化剂组合物包含过渡金属化合物，助催化剂和聚合改性剂，以及由此产生的催化剂组合物和改进的烯烃聚合方法。
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公开(公告)号：US6075077A
公开(公告)日：2000-06-13
申请号：US958361
申请日：1997-10-27
CPC分类号： C08F2/34 , C08F4/602 , Y10S526/943
摘要： The subject invention is directed to a composition comprising a polymer, comprising in polymerized form ethylene and at least one additional polymerizable monomer, prepared by polymerizing ethylene and said at least one addition polymerizable monomer in the presence of a catalyst comprising a recited cyclopentadienyl group-containing metal coordination complex and an activating cocatalyst, wherein said composition is an asphalt, bitumen, or adhesive composition.
摘要翻译： 本发明涉及一种包含聚合物的组合物，该聚合物包含聚合形式的乙烯和至少一种另外的可聚合单体，其通过在包含所述含环戊二烯基的催化剂存在下聚合乙烯和所述至少一种可加聚单体而制备 金属配位络合物和活化助催化剂，其中所述组合物是沥青，沥青或粘合剂组合物。
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8.发明授权Biscyclopentadienyldiene complex containing addition polymerization catalysts 失效含有加成聚合催化剂的双环戊二烯二烯络合物
公开(公告)号：US5972822A
公开(公告)日：1999-10-26
申请号：US474224
申请日：1995-06-07
IPC分类号： C07F17/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F36/02 , C08F38/00 , C08F210/08 , B01J31/00 , B01J37/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , Y10S526/901 , Y10S526/943
摘要： Catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers comprising biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a .sigma.-complex or a .pi.-complex in combination with a cocatalyst or subjected to bulk electrolysis in the presence of compatible, inert non-coordinating anions.
摘要翻译： 用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂，其包含双环戊二烯基，由共轭二烯形成的第4族过渡金属络合物，其中二烯与σ-复合物或π-复合物形式的过渡金属结合， 助催化剂或在相容的惰性非配位阴离子存在下进行大量电解。
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9.发明授权Group 4, metal-conjugated diene metallocyclopentene complexes, and addition polymerization catalysts therefrom 失效第4族金属共轭二烯金属环戊烯络合物及其加成聚合催化剂
公开(公告)号：US5539068A
公开(公告)日：1996-07-23
申请号：US429974
申请日：1995-04-27
CPC分类号： C07F17/00 , C08F10/00 , C08F10/02 , C08F4/65908 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
摘要翻译： 新型4族金属络合物，其含有一个且仅一个环状离域，阴离子，π键合基团，其中金属处于+4形式氧化态并具有桥连配体结构，也称为约束几何配合物和共轭二烯二价阴离子 配体基团 这种络合物的催化衍生物，包括新型的三嗪配合物; 以及其作为用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂的用途。
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10.发明授权Sulfonated substantially random interpolymers, blends therewith and articles made therefrom 失效磺化的基本无规互聚物，与其混合并由其制成的制品公开(公告)号：US06844399B2
公开(公告)日：2005-01-18
申请号：US10265931
申请日：2002-10-07
申请人： Yunwa W. Cheung , Stephen F. Hahn , James C. Stevens , Francis J. Timmers , Gregory F. Schmidt , Thoi H. Ho , Robert H. Terbrueggen
发明人： Yunwa W. Cheung , Stephen F. Hahn , James C. Stevens , Francis J. Timmers , Gregory F. Schmidt , Thoi H. Ho , Robert H. Terbrueggen
IPC分类号： C08L23/00 , C08F8/36 , C08F210/00 , C08F212/00 , C08L23/02 , C08L23/08 , C08L23/32 , C08L23/34 , C08L25/00 , C08L25/18 , C08L77/00 , F16F9/02 , F16F9/48
CPC分类号： F16F9/48 , C08F8/36 , C08F8/44 , C08F212/00 , C08F2800/10 , C08F2800/20 , C08F2810/50 , C08L23/00 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/0876 , C08L23/32 , C08L23/34 , C08L25/18 , C08L77/00 , C08L2205/08 , F16F9/0209 , C08L2666/04 , C08L2666/20 , C08L2666/02 , C08F210/02 , C08F212/08
摘要： Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl or vinylidene aromatic monomer and at lest one hindered aliphatic or cycloaliphatic vinylidene monomer, and from 35 to 99 mole percent of at least one aliphatic α-olefin having from 2 to 20 carbon atoms; and optionally, from 0 to 20 mole percent of a diene containing from 4 to 20 carbon atoms; wherein the sulfonated interpolymer contains at least one mer (or moiety) of a group represented by the formula —SO3−M where M is hydrogen or a group 1, 7 or 12 metal in ionic form or combination thereof. Blends of these polymers with polyamides and polyolefins are made.
摘要翻译： 由单体组分制备的磺化的基本上无规的互聚物包含1至65摩尔％的（a）至少一种乙烯基或亚乙烯基芳族单体，或（b）至少一种受阻脂族或脂环族亚乙烯基单体，或（c） 至少一个乙烯基或亚乙烯基芳族单体和至少一个受阻的脂族或脂环族亚乙烯基单体，以及35至99摩尔％的至少一种具有2至20个碳原子的脂族α-烯烃; 和任选的0至20摩尔％的含有4至20个碳原子的二烯; 其中所述磺化互聚物包含至少一个由式-SO 3 M表示的基团的聚合物（或部分），其中M是氢或1-7或12族离子形式或其组合的金属。 制备这些聚合物与聚酰胺和聚烯烃的共混物。
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