摘要:
The invention relates to an electrode for an electrochemical cell, wherein an electrode is flatly applied onto a surface of a solid oxide electrolyte, and a cathode is flatly applied onto the solid oxide electrolyte surface opposite the electrode. The base material of the electrode is a composite whose catalytically active metal component contains a nickel phase which is made of NiO as part of the electrode starting material by reducing the NiO in a hydrogen-containing atmosphere. The ceramic component is made with a doped cerium oxide and a spinel made of at least one transition metal selected from Ni, Mn, Fe, and Cr.
摘要:
The invention relates to an arrangement of electrochemical cells and also to the uses thereof. The electrochemical cells are arranged one above another and are in electrically conducting communication with one another. In this arrangement they form repeating units which in each case are formed of at least one interconnector, in which apertures for gas passage are formed, an electrochemical cell, which is formed of a cathode, an electrolyte and an anode, and contact elements on the anode side and on the cathode side, and are arranged one above another. The area of the individual planar electrochemical cells is in each case smaller than the area of the individual interconnectors, and the electrolytes finish flush in each case with a plane of a surface of the respective interconnector. Mounted on this surface of the interconnector in each case is a single sealing ply of a glass solder with constant thickness, for sealing the gap between electrolyte and interconnector (internal joining) and the gaps between apertures for gas passage of two adjacent interconnectors (external joining).
摘要:
An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.
摘要:
An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.
摘要:
The invention relates to solid-state electrolytes for use in lithium-air batteries or in lithium-water batteries. It is the object of the invention to provide solid electrolyte for use in lithium-air batteries or lithium-water batteries, with the solid electrolyte having sufficient strength, good conductivity for lithium ions, imperviousness for gas and water resistance and being inexpensive in manufacture. The solid-state electrolyte in accordance with the invention has an open-pore ceramic carrier substrate. In this respect, at least one layer which is conductive for lithium ions, which has an electrical conductivity of at least 10−5 Scm−1 and which is gas-impervious is formed on the surface facing the cathode. In this respect, the carrier substrate has greater mechanical strength and a larger layer thickness than the at least one layer.
摘要:
A composition is for the manufacture of glass solders for high-temperature applications up to temperatures of approximately 1000° C., which composition, having no ZrO2, has SiO2 at a proportion in the range from 48 mol-% to 62 mol %, Al2O3 at a proportion in the range from 0.5 mol % to 6 mol %, B2O3 at a proportion in the range 4 mol % to 12 mol %, BaO at a proportion in the range 12 mol % to 30 mol %, and either CaO at a proportion in the range from 2.5 mol % to 15 mol %, or an R2O3 at a proportion in the range 0.5 mol % to 20 mol % where the R2O3 is selected from La2O3, Y2O3, Sc2O3, and from a further oxide of a chemical element from the series of lanthanoids, wherein the SiO2:BaO ratio is in the range from 1.9 to 4.
摘要:
A pasty composition for the manufacture of three-dimensional structures or structural elements on the surface of a substrate is formed together with a polymer as an organic component B1, and a powdery material that makes up a proportion of solid in the range of 60 mass % to 95 mass % in the composition, and at least two mutually different solvents C1 and C2 that form a solvent mixture. A first solvent C1 has a boiling temperature here that is lower than the boiling temperature of the further solvent or solvents C2.
摘要:
An electrochemical assembly can include an electrochemical device and a heat exchanger disposed within a housing. In an embodiment, the heat exchanger can be disposed in a gas outlet chamber. In another embodiment, the heat exchanger can be at least partially embedded in a wall of the gas outlet chamber. The heat exchanger can be configured to transfer a heat from an outlet gas to an inlet gas.
摘要:
The invention relates to compositions for the manufacture of glass solders for high-temperature applications up to temperatures of approx. 1000° C. and to their use. SiO2 having a proportion in the range from 48 mol-% to 62 mol %, Al2O3 having a proportion in the range from 0.5 mol % to 6 mol %, B2O3 having a proportion in the range 4 mol % to 12 mol % and BaO having a proportion in the range 12 mol % to 30 mol % as well as CaO having a proportion in the range from 2.5 mol % to 15 mol %, or an R2O3 having a proportion in the range 0.5 mol % to 20 mol % are contained in the composition in accordance with the invention, where the R2O3 is selected from La2O3, Y2O3, Sc2O3 and from a further oxide of a chemical element from the series of lanthanoids. In this respect, an SiO2:BaO ratio in the range from 1.9 to 4 is observed and no ZrO2 is contained.
摘要翻译:本发明涉及用于制造高温应用的玻璃焊料的组合物, 1000°C和它们的使用。 具有48摩尔%至62摩尔%范围内的比例的SiO 2,比例为0.5摩尔%至6摩尔%的Al 2 O 3,比例为4摩尔%至12摩尔%的B 2 O 3和具有 12摩尔%〜30摩尔%范围的比例以及比例在2.5摩尔%〜15摩尔%范围内的CaO或0.5摩尔%〜20摩尔%的比例的R 2 O 3的比例含有 根据本发明的组合物,其中R 2 O 3选自La 2 O 3,Y 2 O 3,Sc 2 O 3和来自该系列镧系元素的化学元素的另外的氧化物。 在这方面,观察到在1.9〜4的范围内的SiO 2:BaO比,不含有ZrO 2。
摘要:
The invention relates to solid-state electrolytes for use in lithium-air batteries or in lithium-water batteries. It is the object of the invention to provide solid electrolyte for use in lithium-air batteries or lithium-water batteries, with the solid electrolyte having sufficient strength, good conductivity for lithium ions, imperviousness for gas and water resistance and being inexpensive in manufacture. The solid-state electrolyte in accordance with the invention has an open-pore ceramic carrier substrate. In this respect, at least one layer which is conductive for lithium ions, which has an electrical conductivity of at least 10−5 Scm−1 and which is gas-impervious is formed on the surface facing the cathode. In this respect, the carrier substrate has greater mechanical strength and a larger layer thickness than the at least one layer.