摘要:
The components of and a proton conducting membrane (PCM) produced from a host polymer and an attached or physically blended in hydrogen cyano fullerene proton-source agent, with the physical blending of the host polymer and hydrogen cyano fullerene further promoted by a poly(ethylene oxide) attached fullerene mixing agent.
摘要:
The components of and a proton conducting membrane (PCM) produced from a host polymer and an attached or physically blended in hydrogen cyano fullerene proton-source agent, with the physical blending of the host polymer and hydrogen cyano fullerene further promoted by a poly(ethylene oxide) attached fullerene mixing agent.
摘要:
A membrane/film casting method for fabricating composite membranes/films, and the produced composite membranes/films thereby fabricated, from a host polymer and a fullerene, often with the mixing of the host polymer and fullerene further promoted by a poly(ethylene oxide) attached fullerene mixing agent.
摘要:
Novel acidic hydrogen cyano fullerenes and cyano fullerenes are disclosed that may be utilized as components in a proton conducting membrane (PCM). In particular, C60H(CN)n, wherein n>1, and C60(CN)n, wherein n>2, species are provided.
摘要翻译:公开了可用作质子传导膜(PCM)中的组分的新型酸性氢氰基富勒烯和氰基富勒烯。 特别地,C 60 H(CN)n N,其中n> 1和C 60(CN)n SUB >,其中n> 2,提供物种。
摘要:
For use in a DMFC, a proton-conducting membrane containing a proton-conducting host polymer and a functionalized fullerene having one or more proton accepting or proton donating functional groups selected from: >C[PO(OH)2]2; —PO(OH)2; —OH; —SO3H; —NH2; —CN; —HOSO3H; —COOH; —OPO(OH)2; and —OSO3 or a combination of two or more of these groups attached to the fullerene.
摘要:
Pegylated fullerenes, for use with a lithium ion battery as a solvent-free electrolyte, having the formula {[CH3-(PEO)]m-LINKER}n-fullerene, with n≧1, m≧1 to 5, and the LINKER group comprising a moiety capable of attaching each of the CH3-(PEO)-chains to the fullerene.
摘要:
An electrical double layer capacitor (EDLC) energy storage device is provided that includes at least two electrodes and a redox-enhanced electrolyte including two redox couples such that there is a different one of the redox couples for each of the electrodes. When charged, the charge is stored in Faradaic reactions with the at least two redox couples in the electrolyte and in a double-layer capacitance of a porous carbon material that comprises at least one of the electrodes, and a self-discharge of the energy storage device is mitigated by at least one of electrostatic attraction, adsorption, physisorption, and chemisorption of a redox couple onto the porous carbon material.
摘要:
Disclosed is a microwave preparation method for producing polymeric nanoparticles in which a mixture is made that contains a monomer, an optional functionalize co-monomer, a polymerization initiator that is activated by microwave irradiation, a cross-linker that preferentially creates intra-particle cross-links during polymerization, and a water-based solvent which is then irradiated with microwave radiation to facilitate polymerization of the nanoparticles into sub-50 nm size range nanoparticles.
摘要:
An organic-inorganic hydrophilic polymer-oxide hybrid proton conducting membrane (PCM) is produced from a host organic polymer, a filler inorganic oxide, and a proton-source with a pKa less than about 5. Usually, the subject invention comprises PCMs containing host polymer-x-strong acid-y-filler oxide, wherein x is between about 1 and about 10 (with “x” as the molar ratio of acid anion to polymer repeat unit) and y≦ about 50% (with “y” the weight percentage of filler oxide in the composite).
摘要:
Novel cementitious contaminant barriers are formed by positioning a hydraulic cement composition into a predetermined configuration and then hydrating the cement composition. The contaminant barriers of the present invention include at least one liquid, gas, or ion getter capable of binding with or absorbing liquids, ions, or gases which may penetrate the barrier. The contaminant barriers of the present invention may be engineered to include mixtures of different getters, single and multiple layers of different getters, multiple layers of cement and getters, and a host of different getter, cement, mixture, and layer combinations.Novel waste containers are advantageously prepared utilizing contaminant barriers within the scope of the present invention. The waste containers may be prepared by surrounding waste material with at least one getter and with a powdered hydraulic cement composition and then compressing the cement and getter around the waste material. Preformed waste containers may also be prepared within the scope of the present invention. Use of reinforcing fibers and aggregates to improve the mechanical properties of the hazardous waste container is disclosed.