摘要:
An impregnation sealant composition comprises a low viscosity vulcanizable silicone. The silicone is selected from the group consisting of (i) a heat curable silicone composition formed as the reaction product in the presence of a platinum catalyst of a first silicon containing material containing at least two SiH functionalities and having a molecular weight less than 2000 with a second silicon containing material containing at least two ethylenically unsaturated functionalities and having a molecular weight less than 2000, said silicone composition having a ratio of SiH to Si-ethylenically unsaturated functionalities of from about 0.8 to about 1.2; and (ii) a room temperature vulcanizing silicone composition formed as the reaction product of a silicone fluid containing at least two SiOH functionalities and having a molecular weight less than 2000 with a silane cross-linker of formula (I):R.sub.n Si(X).sub.4-n (I),wherein the R groups are the same or different and selected from the group consisting of hydrogen, C1-C12 alkyl, C6-C12 aryl, C7-C18 arylalkyl, C7-C18 alkylaryl, haloalkyl, haloaryl, and monovalent ethylenically unsaturated radicals, X is a hydrolyzable functionality selected from the group consisting of alkoxy, oximino, enoloxy, acetoxy, amino, and amido, and n is an integer of from 0 to 1, with the proviso that when X is alkoxy, the reaction is in the presence of an organolithium, titanium or tin catalyst, said silicone composition having at least 1 silane per SiOH functionality.
摘要:
The present invention provides anaerobic adhesive compositions, reaction products of which demonstrate controlled-strength at ambient temperature conditions and enhanced resistance to thermal degradation at elevated temperature conditions. The compositions are (meth)acrylate- and/or polyorganosiloxane-based and may include one or more of a variety of other components, such as certain coreactants, a maleimide component, a diluent component reactive at elevated temperature conditions, mono- or poly-hydroxyalkane components, and other components.
摘要:
Anaerobic adhesive compositions, the reaction products of which demonstrate improved cure speed and bond strength are disclosed. A high percentage of ultimate bond strength is reached within the first hour of room temperature cure. Higher ultimate bond strengths as compared to conventional compositions are achieved. The anaerobic adhesive compositions incorporate an adhesion promoter which contributes to these properties.
摘要:
A curable impregnation sealant composition comprising a curable monomer, e.g., a (meth)acrylic acid ester monomer, of a type adapted for curing by heat and/or substantial absence of oxygen, and a curable monomer-soluble reactive bismaleimide of a type and in a solubilized amount providing enhanced high temperature resistance in the impregnation sealant composition when cured.
摘要:
Anaerobic and heat curing polymerizable impregnation compositions for sealing pourous articles are disclosed. The compositions contain glycerol, oxygenated glycerol or (meth)acrylate glycerol to improve the washability of the compositions in aqueous solutions. The compositions may contain other compounds to effect the curing characteristics of the sealants.
摘要:
The present invention provides compositions and methods for removing water from a sealant composition. This includes the addition of a particularly selected anhydride to a sealant composition and further addition of an acrylic acid, in order to remove water from a sealant composition.
摘要:
A method of treating wastewater including a heat-curable (meth)acrylic monomer-containing composition, at temperature below that necessary to effect heat-curing of the composition. The wastewater may be produced by aqueous washing of porous parts impregnated with a sealant composition containing such monomer. The monomer-containing wastewater is (1) adjusted in pH to a value in the range of from about 8 to about 10, and (2) contacted with an effective amount of a reducing agent which is polymerizingly effective for the monomer, to yield corresponding polymer from the monomer. The wastewater is mixed with a cationic flocculating agent in sufficient quantity to flocculate the polymer in the wastewater, and the resulting wastewater is physically separated to recover a monomer- and polymer-reduced wastewater effluent which may be discharged to receiving waters.
摘要:
A method of treating wastewater containing (meth)acrylic monomer, such as is produced by aqueous washing of porous parts impregnated with a sealant composition containing such monomer. The monomer-containing wastewater is (1) adjusted in pH to a value in the range of from about 8 to about 10, and (2) contacted with an effective amount of a reducing agent which is polymerizingly effective for the monomer, to yield corresponding polymer from the monomer. The wastewater is mixed with a cationic flocculating agent in sufficient quantity to flocculate the polymer in the wastewater, and the resulting wastewater is physically separated to recover a monomer- and polymer-reduced wastewater effluent which may be discharged to receiving waters.