Process for stabilizing bismuth vanadate pigments against attack by
hydrochloric acid
    1.
    发明授权
    Process for stabilizing bismuth vanadate pigments against attack by hydrochloric acid 失效
    通过氢氯酸对双歧杆菌色素进行稳定化处理的方法

    公开(公告)号:US5123965A

    公开(公告)日:1992-06-23

    申请号:US616556

    申请日:1990-11-21

    摘要: A process for stabilizing bismuth vanadate pigments against attack by hydrochloric acid by treating said pigments with a metal phosphate, which process comprises treating an aqueous suspension of a bismuth vanadate pigment with 2-20% by weight, based on said pigment, of an orthophosphate selected from the group consisting of calcium, magnesium, aluminium, zirconium and titanium orthophosphate, of a mixture of such orthophosphates with one another or of such orthophosphates with zinc orthophosphate, with stirring, in the temperature range from 20.degree. to 100.degree. C. and in the pH range from 2 to 8, which orthophosphate is precipitated in situ from the appropriate metal salt of a strong mineral acid and orthophosphoric acid or from an alkali metal salt thereof, and isolating the resultant product by conventional methods.The pigments so obtained have excellent resistance to hydrochloric acid.

    摘要翻译: 一种通过用金属磷酸盐处理所述颜料来稳定钒酸铋颜料以防止盐酸侵蚀的方法,该方法包括用选自正磷酸盐的2-20重量%的基于所述颜料的2-20重量%的钒酸铋颜料颜料的水性悬浮液 由正磷酸钙,镁,铝,锆和钛组成的组,这些正磷酸盐彼此或这些正磷酸盐与正磷酸锌的混合物在搅拌下在20℃至100℃的温度范围内 pH范围为2至8,其中正磷酸盐由强无机酸和正磷酸的合适金属盐或其碱金属盐原位沉淀,并通过常规方法分离得到的产物。 如此获得的颜料具有优异的耐盐酸性。

    Process for warp-free pigmenting of polyolefins
    2.
    发明授权
    Process for warp-free pigmenting of polyolefins 失效
    聚烯烃无翘曲着色的方法

    公开(公告)号:US5274010A

    公开(公告)日:1993-12-28

    申请号:US726055

    申请日:1991-07-05

    摘要: A process for warp-free pigmenting of polyolefins comprising(A)(i) adsorbing a polyvinyl alcohol film onto the surface of an organic pigment particle,(ii) coating the surface of the polyvinyl alcohol coated organic pigment particle with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(B)(i) adsorbing a film of hydrolysed zirconium acetylacetonate onto the surface of an organic ##STR1## in which R is methyl or ethyl and m is a number from 1 to 6, onto the surface of the hydrolysed zirconium acetylacetonate coated organic pigment particle, (ii) coating the surface of organic pigment particle coated in accordance with step (B)(i) with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(C)(i) coating the surface of an organic pigment particle with one or more films or linear or branched homopolymers or copolymers of polyvinyl alcohols, and(ii) admixing said pigment particles with a polyolefin;said organic pigment particle being selected from the group consisting of azo, diketopyrrolopyrrole, perylene, quinacridone, phthalocyanine, perinone, quinophthalone, isoindolinone, isoindoline, benzimidazolone, dioxazine, anthraquinone, thioindigo, methine, azomethine and metal complex pigments.

    摘要翻译: 包括(A)(i)将聚乙烯醇膜吸附到有机颜料颗粒的表面上的方法,(ⅱ)将聚乙烯醇涂覆的有机颜料颗粒的表面用一种或多种 选自基于丙烯酸,甲基丙烯酸,丙烯酸或甲基丙烯酸的烷基酯及其混合物的丙烯酸聚合物的线性或支化均聚物或共聚物,和(iii)将所述颜料颗粒与聚烯烃混合; 或(B)(i)将水解的乙酰丙酮酸锆的膜吸附到有机“IMAGE”的表面上,其中R是甲基或乙基,m是1至6的数,在水解的乙酰丙酮酸锆包被的有机 颜料颗粒,(ii)将根据步骤(B)(i)涂布的有机颜料颗粒的表面用一种或多种线性或支化均聚物或共聚物涂布,所述共聚物或共聚物选自基于丙烯酸的丙烯酸聚合物,甲基丙烯酸 酸,丙烯酸或甲基丙烯酸的烷基酯及其混合物,和(iii)将所述颜料颗粒与聚烯烃混合; 或(C)(i)用一种或多种膜或聚乙烯醇的直链或支链均聚物或共聚物涂覆有机颜料颗粒的表面,和(ii)将所述颜料颗粒与聚烯烃混合; 所述有机颜料颗粒选自偶氮,二酮吡咯并吡咯,苝,喹吖啶酮,酞菁,紫环酮,喹酞酮,异吲哚啉酮,异二氢吲哚,苯并咪唑酮,二恶嗪,蒽醌,硫靛,次甲基,偶氮甲碱和金属络合物颜料。

    Inorganic compounds based on bismuth vanadate
    5.
    发明授权
    Inorganic compounds based on bismuth vanadate 失效
    基于钒酸铋的无机化合物

    公开(公告)号:US4752460A

    公开(公告)日:1988-06-21

    申请号:US16045

    申请日:1987-02-18

    申请人: Fritz Herren

    发明人: Fritz Herren

    摘要: Process for mass coloring high molecular weight organic material, which comprises using a compound of the general formula (I)(Bi,A)(V,D)O.sub.4 (I)in a tetragonal, scheelitelike crystal structure, in which A is an alkaline earth metal, Zn or a mixture thereof, D is Mo, W or a mixture thereof, and the molar ratios A:Bi and D:V are between 0.1 and 0.4 and 0 and 0.4 respectively.Processes for preparing the compounds of the formula (I) are likewise described.

    摘要翻译: 用于大量着色高分子量有机材料的方法,其包括使用通式(I)(Bi,A)(V,D)O 4(I)的化合物为四方晶格状晶体结构,其中A为碱 土壤金属,Zn或它们的混合物,D是Mo,W或它们的混合物,摩尔比A:Bi和D:V分别为0.1-0.4和0和0.4。 同样地描述了制备式(I)化合物的方法。

    Process for warp-free pigmenting of polyolefins
    10.
    发明授权
    Process for warp-free pigmenting of polyolefins 失效
    聚烯烃无翘曲着色的方法

    公开(公告)号:US06180694B2

    公开(公告)日:2001-01-30

    申请号:US08359710

    申请日:1994-12-20

    IPC分类号: C08J320

    摘要: The instant invention relates to a process for the warp-free pigmenting of polyolefins, which process comprises admixing coated pigment particles with a polyolefin, wherein said coated pigment particles are prepared by coating organic pigment particles with one or more films of a preformed polymer by adsorption thereon of from 1 to 10% by weight of the polymer, based on the pigment particles, at room temperature, the polymer being selected from the group consisting of polyvinylpyrrolidone homopolymers and copolymers.

    摘要翻译: 本发明涉及一种聚烯烃无翘曲着色的方法,该方法包括将涂覆的颜料颗粒与聚烯烃混合,其中所述涂覆颜料颗粒通过用一种或多种预成型聚合物膜通过吸附涂布有机颜料颗粒来制备 其中基于颜料颗粒的聚合物的1-10重量%,在室温下,该聚合物选自聚乙烯吡咯烷酮均聚物和共聚物。